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Chalcones may be cyclised to the corresponding flavanones by stirring with KF-celite suspended in methanol at reflux. This method gives consistently higher conversion than other reported procedures and its utility is illustrated by the synthesis of the linear prenylated flavanone bavachinin. 相似文献
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Mathematical deconvolution methods can separate co-eluting peaks in samples for which (chromatographic) separation fail. However, these methods often heavily rely on manual user-input and interpretation. This is not only time-consuming but also error-prone and automation is needed if such methods are to be applied in a routine manner. 相似文献
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In this paper we show that the quasi-symmetric coupling of finite and boundary elements of Bielak and MacCamy can be freed
of two very restricting hypotheses that appeared in the original paper: the coupling boundary can be taken polygonal/polyhedral
and coupling can be done using the normal stress instead of the pseudostress. We will do this by first considering a model
problem associated to the Yukawa equation, where we prove how compactness arguments can be avoided to show stability of Galerkin
discretizations of a coupled system in the style of Bielak–MacCamy’s. We also show how discretization properties are robust
in the continuation parameter that appears in the formulation. This analysis is carried out using a new and very simplified
proof of the ellipticity of the Johnson–Nédélec BEM–FEM coupling operator. Finally, we show how to apply the techniques that
we have fully developed in the model problem to the linear elasticity system. 相似文献
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Baptiste Schindler Agathe Depraz Depland Gina Renois-Predelus Gabriel Karras Bruno Concina Gulabi Celep Jacques Maurelli Vincent Loriot Eric Constant Richard Bredy Christian Bordas Franck Lépine Isabelle Compagnon 《International Journal for Ion Mobility Spectrometry》2017,20(3-4):119-124
An original workflow allowing inline FAIMS separation, electrospray ionization, mass analysis and ion spectroscopy (IRMPD: InfraRed Multiple Photon Dissociation) is presented for multidimensional molecular analysis. This new instrument consists of an ultraFAIMS (Owlstone) device interfaced to a linear ion trap (LTQ XL Thermo Scientific) which was modified for IRMPD spectroscopy. Two modes of operation are demonstrated on an isomeric mixture of paracetamol and 2-phenylglycine. In the first mode a FAIMS (high-Field Asymmetric waveform Ion Mobility Spectrometry) separation of the isomers is performed with a static compensation field for mass- and isomer- selective ion spectroscopy. In the second mode, the compensation field is scanned while the ions are irradiated at a fixed wavenumber. The advantages of this workflow as compared to traditional FAIMS-MS and IRMPD spectroscopy are described. The potential of the two modes for molecular spectroscopy and analytical applications, in particular the new “omics” are discussed. 相似文献