用光学相关识别方法测量单模光纤的折射率分布和色散

介绍了一种测量单模光纤剖面折射率分布和色散的新方法－－光学相关识别方法。应用计算全息制作高斯－拉盖尔模的匹配滤波器，根据光学相关识别原理测出单模光纤场分布的展开系数，由此推得剖面折射率分布和色散，给出了实际测量结果。     

大功率GaAs光导开关寿命实验研究

设计并制作了18 mm间隙的半绝缘GaAs光导开关,开关芯片采用标准半导体工艺制作并封装在陶瓷基板上。测试了光导开关在20 kV工作电压、1 kA工作电流时,不同重复频率工作的开关寿命,结果表明,开关寿命4 000次~7 000次,且随着重复频率的提高,开关寿命有所降低。初步分析了导致开关失效的原因为热损伤,包括局部发热导致的连接损伤和材料损伤以及整体发热导致的暗态电阻下降。     

不同形状的光斑触发砷化镓光导开关

为研究使用不同形状光斑触发光导开关对光电导特性的影响,研制了12 mm间隙的半绝缘砷化镓光导开关,在不同的偏置电压下,使用波长为1 064 nm的不同能量的激光触发光导开关并进行了光电导测试。使用了不同形状的光斑(包括面状、线状和点状光斑)触发光导开关并进行了光电导特性的比较,讨论了触发光参数对光导开关特性的影响。对处于开关电极间不同位置的线状光斑触发特性进行了比较,结果显示,本征光电导和非本征光电导情况下光斑位置对光电流的影响正好相反。     

激光脉冲波形对烧蚀Si靶表面温度的影响

利用双温方程对激光烧蚀Si靶的过程进行了数值模拟,并结合合适的初始条件和边界条件,研究了在飞秒、皮秒激光作用下,脉冲波形(矩形、梯形、三角形和高斯形)对Si靶表面载流子和晶格温度分布的影响。结果表明:激光功率密度是影响载流子温升的主要因素,矩形脉冲激光烧蚀Si靶表面载流子的峰值温度最高,而高斯分布的脉冲引起靶面载流子峰值温度最低。可见,激光脉冲波形对Si靶表面载流子的温度分布具有重要影响。所得结果可为制备高质量的薄膜提供理论依据。     

掺杂型有机电致发光二极管的研究进展

有机电致发光具有结构简单、成本低、平面光源、节省能源等优点,其中掺杂型电致发光二极管因可以同时利用单重态和三重态的激子来发光和理论上能使器件内量子效率达到100%而倍受关注。从掺杂型电致发光二极管发光机理、主体材料、掺杂剂材料、白光器件几个方面阐述了该领域的研究进展。     

The impact of carbon shell on a Sn–C composite anode for lithium-ion batteries

Spherical Sn–carbon core-shell powders (CSCM/Sn) were synthesized through a resorcinol–formaldehyde microemulsion polymerization performed in the presence of SnO₂ powders, followed by carbonization in an inert atmosphere. Scanning electron microscope and X-ray diffractometry analyses showed that the Sn powders were thoroughly encapsulated within the carbon microspheres. The CSCM/Sn presented much better cyclability than the conventional Sn–carbon microsphere composite. In core-shell-structured composite, most of the Sn particles were encased inside carbon microspheres and not easy to aggregate or fall off from the microspheres. The carbon shell suppressed the aggregation of tin particles and alleviated the volume change of tin, and the conductive carbon shell effectively decreased the polarization during cycling, giving rise to better high rate performance and excellent capacity retention ability. It is shown that surface structure plays an important role in alloy/C composite anode materials for lithium-ion battery.     

Density functional theory studies on the B-containing lithium salts

Three B-containing lithium salts, lithium bis(oxalato)borate, lithium (malonatooxalato)borate, and lithium bis(malonato)borate, are studied by density functional theory. The relationships between the structure of lithium salts and their physical chemistry characteristics are investigated. A linear correlation is observed between the highest occupied molecular orbital energy of lithium salts and their oxidation potentials. The correlation between ionic conductivity and binding energy of lithium salt is also studied. The physical chemistry characteristics of a novel lithium salt, lithium oxalyldifluoroborate, are predicted according to the rules concluded from other B-containing lithium salts.     

Adaptive varying-coefficient linear quantile model: a profiled estimating equations approach

We consider an estimating equations approach to parameter estimation in adaptive varying-coefficient linear quantile model. We propose estimating equations for the index vector of the model in which the unknown nonparametric functions are estimated by minimizing the check loss function, resulting in a profiled approach. The estimating equations have a bias-corrected form that makes undersmoothing of the nonparametric part unnecessary. The estimating equations approach makes it possible to obtain the estimates using a simple fixed-point algorithm. We establish asymptotic properties of the estimator using empirical process theory, with additional complication due to the nuisance nonparametric part. The finite sample performance of the new model is illustrated using simulation studies and a forest fire dataset.     

弹性介质中受轴向冲击载荷作用的圆柱壳的屈曲临界载荷计算分析

建立并求解了弹性介质中圆柱壳的径向位移控制方程,考虑边界条件及相容条件,得到了应力波传播及反射过程中圆柱壳的动力屈曲分叉条件.通过计算得到了不同时间段屈曲临界载荷与应力波波阵面到达圆柱壳的位置、弹性介质的刚度、壳体未嵌入弹性介质部分的长度与总长之比的关系.数值计算结果表明,弹性介质中的圆柱壳发生轴对称屈曲和非轴对称屈曲趋势一致;嵌入弹性介质部分越深、弹性介质刚度越大圆柱壳越难屈曲;屈曲临界载荷随着弹性介质刚度的增大经历了增长缓慢、增长迅速以及增长较慢3个阶段;应力波反射前波阵面通过分界面后,屈曲仅发生在应力波传播区域,反射波波阵面通过分界面前,临界载荷较小时屈曲先发生在反射端部,随着轴向阶数增大,屈曲覆盖整个圆柱壳区域,反射波波阵面通过分界面后,壳体发生的屈曲始终覆盖整个圆柱壳区域.