Etude de l''addition des organomagnesiens satures et benzyliques aux enynes conjugues, simples et fonctionnels

Saturated and benzylic organomagnesium compounds are shown to readily undergo addition reactions with the conjugated enynes H$\text{C}\text{4}$$\text{C}\text{3}$C$\text{H}\text{2}$$\text{C}\text{1}$HCH₂R′, with R′ = alkyl, OH, OC₄H₉, NHC₂₅, N(C₂H₅)₂, by refluxing for several hours in benzene or toluene.This reaction leads to both υ-acetylenic compounds (1,2-addition) and β-allenic compounds (1,4-addition).     

Synthesis of 1,7-bis(4′-aminophenylamido)-m-carborane and 1,7-bis(4′-aminophenylcarboxy)-m-carborane

Conclusion 1,7-Bis(4-aminophenylamido)- and l,7-bis(4-aminophenylcarboxy)-m-carboranes were prepared and characterized.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2786–2787, December, 1986.     

Mechanisms of antioxidant action: The effect of thermal processing on the antioxidant activity of sulphur compounds

The nickel dithiophosphates and their corresponding disulphides are shown to be more effective uv stabilisers for LDPE than the closely related nickel xanthates and disulphides (dixanthogens). In general, the nickel complexes in both series are more effective uv stabilisers than the disulphides.Evidence is presented to show that the better performance of the dithiophosphates than the xanthates is associated with their higher solubility in the polymer. For the same reason, nickel dithiolates containing long alkyl substituents are more effective uv stabilisers than those containing shorter alkyl substituents.Thermal processing adversely affects the photo-stabilising performance of nickel dithiolates whereas the performance of the less efficient disulphides is enhanced under the same conditions. In the former case, the uv stability of the polymer is shown to be directly proportional to the amount of the nickel complex left after processing. In the case of the disulphides, on the other hand, the evidence suggests that increasing the severity of their processing increases the extent of oxidation to products which are more effective uv stabilisers than the parent disulphides.     

Lactam and acid amide acetals. 71. New synthesis of 3-nitro-6-hydroxyindole derivatives

Previously unknown 3-nitro-6-hydroxyindole derivatives were synthesized by condensation of p-benzoquinone with secondary -nitro enamines.See [1] for Communication 70.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 1, pp. 40–45, January, 1992.     

Acetals of amides and lactams in the synthesis of heterocyclic compounds

The review collects the results of investigations on the synthesis of heterocyclic compounds, mainly azaheterocycles, from amide and lactam acetals. The reasons for the high reactivity of these compounds with respect to nucleophilic and electrophilic reagents are considered, as are the principal pathways of heterocyclization of amidine and enamine systems synthesized via amide and lactam acetals.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 6, pp. 762–780, June, 1992.     

Photoreduction de la benzophenone par des phtalimidines et des dihydro isoquinolones: Etude chimique par RMN PNIC

Benzophenone is photoreduced by pthalimidines and dihydro isoquinolones. The hydrogen atom α to the nitrogen atom is abstracted and radical coupling leads to adducts. CIDNP studies of these adducts show inversion of polarisation for the adduct on the N-alkyl chain when the nitrogen is bound to a benzylic methylene. This inversion is explained by considering that the radical on the N-alkyl chain derives from the radical on the ring.