Circular dichroism spectra in mordant azo dyes

The photogyrotropic properties of several mordant yellow azo dyes in gelatin and polymer matrices that are in the normal state or exposed to circularly polarized light are investigated. A model explanation for the experimental data is given.     

Production and properties of metal-carbon composite coatings with a nanocrystalline structure

It is suggested to produce metal-carbon composite coatings by magnetron sputtering of mosaic cathodes, which are Group IV, V, and VI metals. The mosaic structure of the cathode elements are computer-optimized for each of the metals. Reflection electron diffraction studies show that the coatings have the amorphous or nanocrystalline structures, which are thermally stable. The coatings offer specific physical properties, in particular, low friction factor and high hardness.     

Revisiting Gouy phase

The aim of this paper is to highlight the added value of the generalized Gouy phase shift introduced by Siegman. Although suited for optical systems study, including those more complex than free space, we note that it did not meet the use that it deserves so far. The analysis of the whole of the ideas and analytical approaches associated to the important concept of the Gouy phase proves its effectiveness.

Usually, the resonance condition is systematically built on the basis of the equivalent empty cavity. Unfortunately, this approach does not cover some of the useful parameters of the real resonator. By means of the generalized Gouy phase and the self-consistent complex parameter q, we derive here a new approach for the calculation of the resonance condition for the real cavity. Moreover, the use of the generalized Gouy phase clearly simplifies the study of resonators, while making it possible to avoid the use of the Huygens’ Fresnel integral.     

Interpretation of the polyelectrolyte and antipolyelectrolyte effects of poly(N‐vinylimidazole‐co‐sodium styrenesulfonate) hydrogels

Hydrogels of N‐vinylimidazole (VI) and sodium styrenesulfonate (SSS) were synthesized in aqueous solution by radical crosslinking copolymerization with N,N′‐methylene‐bis(acrylamide) as crosslinker. Swelling in several saline solutions was measured for hydrogel samples synthesized with different comonomer concentrations (C_T = 10, 25, or 40%) and with SSS mole fractions covering a broad range (f_SSS = 0–0.7), while the crosslinker ratio was 2 wt % in all cases. The degree of swelling in aqueous solution with a specific ionic strength (μ), plotted versus the SSS composition of the feed, shows a minimum for any set of samples synthesized with a fixed C_T. The dependence of swelling on μ shows both polyelectrolyte (f_SSS beyond the minimum) and antipolyelectrolyte behaviors (in the low f_SSS limit). It was found that the nonGaussian factor of the crosslinking density and the polymer‐solvent interaction parameter increase with f_SSS for any C_T. Moreover, in the low f_SSS limit, the osmotic swelling pressure is governed not only by the ionic contribution, but also by the polymer‐solvent mixing and, the concentration of mobile counterions inside the gel is not proportional to the net fixed charge but to the addition of cationic and anionic side groups, what discards the formation of ionic pairs. The antipolyelectrolyte effect is interpreted as due to the increasing protonation of VI as μ goes up. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 1683–1693, 2007     

CAS based approach for discussing subset construction

This paper continues the discussion of teaching nondeterminism (see [6]) where we presented a didactic approach introducing the notion of nondeterministic automata. Although in this paper we use the same methodology we have to face up to new didactic challenges. Namely, teaching the subset construction requires answers to the question how can CAS be used in teaching the different phases of mathematical problem solving so that we can reach higher cognitive efficiency.     

Growth and study of single crystals of (Na,K)NbO<Subscript>3</Subscript> solid solutions

(Na, K)NbO₃ crystals with a perovskite structure and a KNbO₃ content up to 40 mol % were grown from flux with the use of the solvent NaBO₂. The dielectric measurements of the crystals grown revealed phase transitions that had never been observed before in ceramic samples.     

Multistep numerical methods for functional-differential-algebraic equations

This paper deals with constructing multistep numerical methods for differential delay equations under additional algebraic constraints. Theorems on the orders of convergence of these methods are proved both for functional-differential equations with algebraic constraints and for singular functional-differential equations.     

A local search approach to a circle cutting problem arising in the motor cycle industry

This paper is concerned with the development of a customized circle packing algorithm for a manufacturer of sprockets for the motor cycle industry. Practical constraints mean that the problem differs somewhat from those tackled elsewhere in the literature. In particular, the layouts need to conform to a given structure. This is achieved by using a local search algorithm with an appropriate starting solution and a series of neighbourhoods designed to preserve the layout structure. Empirical evidence based on real data shows that the quality of the resulting solutions closely matches that of cutting patterns currently produced by human experts. Computation times average around 20–30?s per order as compared to several hours for an equivalent manual solution.