Synthesis and Self-assembling of Coumarin-based Low-molecular Weight Organogelators

Four coumarin derivatives(4a―4d) with different alkoxy chains were synthesized. It was found that compound 4d showed a better gelation ability than the other compounds, for example, it could self-assemble into organogels in various organic fluids via ultrasound treatment or heating-cooling process, whereas compound 4c could only gel in a few mixed solvents and compounds 4a, 4b could not form organogel. The results from fluorescent and FT-IR spectra indicate that π-π interaction had an effect on the formatio...     

Synthesis of Poly（aryl ether ketone） Copolymers Containing Adamantyl-substituted Naphthalene Rings

1 Introduction High performance polymers have received con-siderable attention over the past decade owing to their increased demands as replacements for metals or     

Refolding and Purification of Yeast Acetyl-CoA Carboxylases CT Domain Expressed as Inclusion Bodies in Escherichia coli

Acetyl-CoA carboxylase(ACCase) is a crucial enzyme in fatty acid synthesis, by regulating the first committed step in the process. Therefore, it is a potential target for the development of new compounds against obesity or as herbicides. The cDNA encoding yeast ACCase CT domains(YCTs) from Saccharomyces cerevisiae was amplified by RT-PCR and inserted into the vector PET28a(+) for bacterial expression of YCT fused to N-terminal His-tag(YCT-his6). YCTs-his6 was expressed in Escherichia coli BL21(DE3) PLys as ...     

High Sensitive Long Period Fiber Grating Sensor for Detection of Nitrite

A high sensitive long period fiber grating(LPFG) sensor for the detection of nitrite is proposed, which is realized by coating multiple poly(sodium 4-styrensulfonate)(PSS) and poly(diallyldimethylammonium) chloride (PDDA) layers on the fiber grating surface. The sensitivity of this LPFG sensor is maximum when the number of assembled layers is 70. Under this condition, a nitrite concentration of 3×10-3 mol/L, which is lower than the National Food Additive Standard, 4.2×10-3 mol/L, can be distinguished. The s...     

Adsorption of Benzene and Propylene in Zeolite ZSM-5： Grand Canonical Monte Carlo Simulations

The adsorption behavior of benzene and propylene in zeolite ZSM-5 was studied by Grand Canonical Monte Carlo(GCMC) simulations. It could be found that benzene and propylene molecules showed different adsorption behavior in the zeolite cavities. The loadings of propylene were significantly larger than those of benzene at 100 kPa. From the figures of potential energy distribution,the potential energy of benzene/zeolite was more negative than that of propylene/zeolite,so benzene could be adsorbed more stably t...     

Detection of Trace Heavy Metals Ions by Arrays of Titania Nanotubes Annealed in Nitrogen

Redox response of trace heavy metals ions(THMIs) has better performance on highly ordered vertically oriented titania nanotube arrays(TNA) annealed in nitrogen. Experimental data showed that different THMIs possess different reaction peak shapes and charge and discharge capacities. Therefore, the TNA will become an important tool used for environmental protection and facilitating the rapid determination of THMIs. THMIs of 5×10-4 mol/L concentration were measured at a scan rate of 100 mV/s. The analytical ut...     

Synthesis and Characterization of Model Complexes of Catechol Dioxygenases Supported by the Anionic Hydrotris-3,5-dimethyl-pyrazolylborate Ligand

An iron(Ⅲ) complex [FeIII(TpzMe2)(HpzMe2)Cl2](1) has been synthesized at a low temperature,which contains tripodal ligand,namely,the anionic hydrotris-3,5-dimethyl-pyrazolylborate(TpzMe2). A series of iron(Ⅲ) catecholate complexes 2―5 has been obtained via the reaction of compound 1 with catecholate or substituted catecho-lates. These complexes were characterized by X-ray crystallographic analysis,mass spectrometry and elemental analysis,and the results show that TpzMe2 ligand has the beneficial effect on t...     

反相液相色谱中离子抑制剂的有机调节剂作用

系统地研究了在反相液相色谱（RPLC）流动相中作为离子抑制剂的酸、碱及缓冲溶液对中性化合物保留行为的影响,着重探讨了有机酸、有机碱离子抑制剂的有机调节剂作用,定量地考察了甲醇和乙腈、甲醇和乙酸、甲醇和三乙胺、乙腈和乙酸、乙腈和三乙胺在十八烷基硅烷键合相上洗脱强度之间的关系,为RPLC中有机调节剂的洗脱强度排序提供一种评判方法．另外,讨论了乙酸和三乙胺作为有机调节剂时不同的作用机理．本实验结果对于RPLC分离方法的快速建立和准确优化都具有一定的借鉴意义．     

Screening and docking studies of natural phenolic inhibitors of carbonic anhydrase Ⅱ

Carbonic anhydrase Ⅱ (CAⅡ) is an important enzyme complex with Zn2+,which is involved in many physiological and pathological processes, such as calcification, glaucoma and tumorigenicity. In order to search for novel inhibitors of CAⅡ, inhibition assay of carbonic anhydrase Ⅱ was performed, by which seven natural phenolic compounds, including four phenolics (grifolin, 4-O-methyl-grifolic acid, grifolic acid, and isovanillic acid) and three flavones (eriodictyol, quercetin and puerin A), showed in-hibitory a...     

A new tripodal rhodamine B derivative as a highly selective and sensitive fluorescence chemosensor for copper(Ⅱ)

A new tripodal rhodamine B derivative 2 was designed and synthesized by tripodal trialdehyde and rhodamine B hydrazide for the first time. This derivative could be used as a fluorescent chemosensor for the selective and sensitive determination of copper(II) in Tris-HCl buffer and ethanol aqueous mixed media. Under the optimum conditions described herein,fluorescence enhancement at 557/577 nm was linearly related to the concentration of copper(II) in the range of 0.10 to 10.00×10-5 mol·L-1,with a corre-latio...