Thermal relaxation of charm in hadronic matter

The thermal relaxation rate of open-charm (D) mesons in hot and dense hadronic matter is calculated using empirical elastic scattering amplitudes. D-meson interactions with thermal pions are approximated by D^? resonances, while scattering off other hadrons (K, η, ρ, ω, K^?, N, Δ) is evaluated using vacuum scattering amplitudes as available in the literature based on effective Lagrangians and constrained by realistic spectroscopy. The thermal relaxation time of D-mesons in a hot π gas is found to be around 25-50 fm/c for temperatures T=150-180 MeV, which reduces to 10-25 fm/c in a hadron-resonance gas. The latter values, argued to be conservative estimates, imply significant modifications of D-meson spectra in heavy-ion collisions. Close to the critical temperature (Tc), the spatial diffusion coefficient (Ds) is surprisingly similar to recent calculations for charm quarks in the Quark-Gluon Plasma using non-perturbative T-matrix interactions. This suggests a possibly continuous minimum structure of Ds around Tc.     

17O Hyperfine Spectroscopy Reveals Hydration Structure of Nitroxide Radicals in Aqueous Solutions

The hydration structure of nitroxide radicals in aqueous solutions is elucidated by advanced ¹⁷O hyperfine (hf) spectroscopy with support of quantum chemical calculations and MD simulations. A piperidine and a pyrrolidine-based nitroxide radical are compared and show clear differences in the preferred directionality of H-bond formation. We demonstrate that these scenarios are best represented in ¹⁷O hf spectra, where in-plane coordination over -type H-bonding leads to little spin density transfer on the water oxygen and small hf couplings, whereas -type perpendicular coordination generates much larger hf couplings. Quantitative analysis of the spectra based on MD simulations and DFT predicted hf parameters is consistent with a distribution of close solvating water molecules, in which directionality is influenced by subtle steric effects of the ring and the methyl group substituents.