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61.
Grein F 《The Journal of chemical physics》2005,122(12):124504
For Ne(n)-AlO (n=2, 4, 6, 8, 10) and Ar(n)-AlO clusters (n=2, 4, 6, 8), the perpendicular (relative to AlO) component of the g tensor was calculated by second-order perturbation theory, using multireference configuration-interaction wave functions. The rare-gas (Rg) atoms were placed axially and/or off axially (one or two rings of four Rg atoms each), and the distance of the Rg atoms from the Al and O atoms, or from the AlO axis, was varied from 4 to 12 bohrs. Rg atoms placed axially mostly increase g(perpendicular), whereas off-axially placed ones lower it below the gas-phase value of AlO. The largest deviations from g(perpendicular) of isolated AlO occur at Ne-Al,O distances of 5-6 bohrs, and Ar-Al,O distances of 6-9 bohrs, with maximal lowerings of about 1600 ppm for Ne and about 2200 ppm (estimated) for Ar in the case of two axial and eight off-axial Rg atoms. Electron spin resonance studies by Knight and Weltner found large matrix effects for AlO, with downshifts of g(perpendicular) observed to be about 450 and 1150 ppm in Ne and Ar matrices, respectively. 相似文献
62.
G. Miksch E. Liebermann Friedrich Kohler 《Monatshefte für Chemie / Chemical Monthly》1969,100(5):1574-1582
Zusammenfassung Totaldampfdrucke des Systems 1,2-Dichloräthan + Cyclohexan wurden bei 13°, 20° und 32° C über den gesamten Konzentrationsbereich gemessen. Für Cyclohexan-reiche Mischungen des Systems wurde ferner die Schmelzkurve bestimmt. Aus diesen Meßgrößen wurde die zusätzliche freie Mischungsenthalpie G
E des Systems für verschiedene Temperaturen berechnet. Bei 20°C beträgt G
E für die äquimolare Mischung 773 J/mol. Ein Vergleich mit Literaturangaben über die Mischungswärme (H=1611 J/mol für äquimolare Mischung bei 20°C) ergibt, daß die zusätzliche Mischungsentropie S
E des Systems stark positiv ist. Eine Interpretation der Ergebnisse wird in einer anderen Arbeit gegeben, wo auch Ergebnisse an anderen Dihalogenäthan + Kohlenwassersoff-Systemen berücksichtigt werden.
Mit 5 Abbildungen 相似文献
Free enthalpy of mixing for the system 1,2-dichloroethne-cyclohexane
Total vapour pressures of the system 1,2-dichloroethane + cyclohexane were measured at 13°, 20° and 32°C over the total concentration interval. For mixtures rich in cyclohexane the
Mit 5 Abbildungen 相似文献
63.
Christian C. Van de Sande Syed Zahoor Ahmad Friedrich Borchers Karsten Levsen 《Journal of mass spectrometry : JMS》1978,13(11):666-670
Gaseous protonated aziridine ions are produced at the threshold from β-phenoxyethylamine molecular ions. The evidence for this is collisional activation spectra, using various precursors (including labelled analogues) under electron impact and field ionization conditions. Partial conversion to the acyclic \documentclass{article}\pagestyle{empty}\begin{document}$ {\rm CH}_{\rm 3} {\rm CH = }\mathop {\rm N}\limits^ + {\rm H}_{\rm 2} $\end{document} isomer occurs at higher electron energies and is rationalized by means of a potential energy surface constructed from energetic data. 相似文献
64.
Friedrich Boberg Maria Ruhr Karl-Heinz Garburg Alfons Garming 《Journal of heterocyclic chemistry》1986,23(3):759-766
Dihydro-1,2-oxazines 8 and 12-oxazines 12 are formed by the reaction of the nitronic acids of the adducts of α-nitroolefins and β-dicarbonyl compounds ( 6 ) by two ways: A ) The nitronic acids 6 are heated in a boiling solution of urea in ethanol or methanol. B ) The nitronic acids 6 are reduced with an aqueous solution of ammoniachloride and sodium sulfide. 1H-nmr and 13C-nmr investigations prove the constitutions. The mechanism is discussed. 相似文献
65.
Heterometallic Complexes with E6 Ligands (E = P, As) The reaction of [Cp*Co(μ-CO)]2 1 with the sandwich complexes [Cp*Fe(η5-E5)] 2 a: E = P, 2 b: E = As in decalin at 190°C affords besides [CpCo2E4] 4: E = P, 7: E = As and [CpFe2P4] 5 the trinuclear complexes [(Cp*Fe)2(Cp*Co)(μ-η2-P2)(μ3-η1:2:1-P2)2] 3 as well as [(Cp*Fe)2(Cp*Co)(μ3-η2:2:2-As3)2] 6 . With [Mo(CO)5(thf)] 3 and 6 form in a build-up reaction the tetranuclear clusters [(Cp*Fe)2(Cp*Co)E6{Mo(CO)3}] 10: E = P, 11: E = As. 3, 6 and 11 have been further characterized by an X-ray crystal structure determination. 相似文献
66.
Doz. Dr. Friedrich Höfler Ernst Brandstätter 《Monatshefte für Chemie / Chemical Monthly》1975,106(4):893-904
The reactions of Ge2(C6H5)6 with HCl and HBr lead in nearly quantitative yields to the 1,1,2,2-tetrahalo derivatives Cl2(C6H5)GeGe(C6H5)Cl2 (I) and Br2(C6H5)GeGe(C6H5)Br2 (II), resp. The Si?Ge bond of (C6H5)3SiGe(C6H5)3 is cleaved under the conditions of hydrohalogenation. The vibrational spectra of Ge2Br6, Ge2(C6H5)6, I, and II are reported. The influence of vibrational coupling on ν GeGe in these compounds is discussed in detail, including vibrational calculations. 相似文献
67.
Preparation and Crystal Structure of Cadmium Azide Cd(N3)2 Solvent free, binary cadmium azide was synthesized by the reaction of cadmium carbonate and a 24 weight% solution of HN3 in water. Cadmium azide is a colorless, crystalline powder which is highly sensitive to percussion and heat. Caution, the manipulation of Cd(N3)2 is very dangerous! The crystal structure was solved by single‐crystal methods and the phase purity was verified by a Rietveld refinement (Cd(N3)2, Pbca, no. 61; a = 7.820(2), b = 6.440(2), c = 16.073(3) Å; Z = 8, 1174 independent reflections, 64 parameters, R1 = 0.022). Cadmium azide crystallizes in a new structure type. In the crystal there are edge‐sharing Cd2(N3)10 double octahedrons which are further connected to other units by azide bridges. Vibrational spectroscopic investigations (Raman an IR) are discussed with respect to the crystal structure data. 相似文献
68.
Equilibrium Measurements by the Transport Method. Determination of the Enthalpie of Formation ΔH°(NbOCl2,f) by Chemical Transport in the Diffusion Tube By means of chemical transport in an ampoule with a well defined diffusion path the equilibrium NbOCl2,s + NbCl5,g ? NbOCl3,g + NbCl4,g has been investigated. Introducing a reaction entropy ΔS = 45 cl one gets ΔH = 38(±2) kcal/formula weight and ΔH0(NbOCl2,s)= ?187,6 kcal/mol. 相似文献
69.
Hiltrud Breitenfelder-Manske Friedrich Kohler 《Monatshefte für Chemie / Chemical Monthly》1985,116(11):1247-1261
The second virial coefficients of homonuclear three-centerLennard-Jones molecules are calculated with various parameters of the isosceles triangle connecting the three sites. A special effort is made to establish the reducedBoyle temperaturesT
B and the values of the second virial coefficients atT/T
B=0.3 for the sake of comparison with one- and two-centerLennard-Jones molecules. It is shown that it is possible to find parameter values of the interaction potential of one- and two-centerLennard-Jones molecules which give very similar values of second virial coefficients forT/T
B0.3, and the equivalence conditions are established. These conditions might not only give a basis for a microscopic scaling of state variables, but also some restrictions for the validity of the group contribution concept.Presented in part at the DFG-Colloquium at Paderborn, 19th April 1982, and at the 5th Conference on Mixtures of Nonelectrolytes and Intermolecular Interactions, April 18–22, 1983, at Halle (GDR). 相似文献
70.
Westmacott G Zhong F Frank M Friedrich S Labov SE Benner WH 《Rapid communications in mass spectrometry : RCM》2000,14(7):600-607
The performance of an energy sensitive, niobium superconducting tunnel junction (STJ) detector is investigated by measuring the pulse height produced by impacting molecular and atomic ions at different kinetic energies. Ions are produced by laser desorption and matrix-assisted laser desorption in a time-of-flight mass spectrometer. Our results show that the STJ detector pulse height decreases for increasing molecular ion mass, passes through a minimum at around 2000 Da, and then increases with increasing mass of molecular ions above 2000 Da. The detector does not show a decline in sensitivity for high mass ions as is observed with microchannel plate ion detectors. These detector plus height measurements are discussed in terms of several physical mechanisms involved in an ion-surface collision. 相似文献