The energy dependence of 18O(π+, π−)18Ne(gs)

Eight angular distributions measured for ¹⁸(π⁺, π^?)¹⁸Ne(gs) across the Δ₃₃ resonance show the details of the energy dependence of the reaction. At higher energies, the maximum is at q ? 0.85 fm^?1, in agreement with simple sequential scattering models, but a lower energies it is at q ? 0.5 fm^?1, with the transition occuring over a narrow energy range.     

Use of enzymes in peptide synthesis

Recent experiments in several laboratories have emphasized the benefits of proteolytic enzymes as effective catalysts for the formation of peptide bonds for synthesis and semisynthesis. This review summarizes successful applications in both stepwise synthesis for small peptides and fragment condensation to produce large polypeptides and proteins.     

Enumeration of acyclic and unicyclic nets with four types of self-duality

A net is a graph in which each point and line is given a sign. The point, line, and simple duals of a net are obtained by reversing the signs of the points, lines, or both. If a net possesses two of the three types of self-duality, it possesses all three and is said to be doubly self-dual. Enumeration formulas are derived for nets and point, line, simply, and doubly self-dual nets, whose underlying graphs are acyclic and unicyclic. The numbers are tabulated up to 12 points (24 for doubly self-dual nets) in each case.     

Pressure saturation of SO2(3B1 0,0,0) lifetimes

Lifetime data have been obtained for the decay of SO₂(³B₁ 0,0,0) at 25°C over the pressure range of 1–762 torr. The ³B₁ state was populated by direct absorption to eliminate any possible complications in interpretation due to the participation of excited-singlet manifolds. At pressures greater than about 10 torr, the measured lifetimes are longer than predicted from low-pressure Stern–Volmer parameters. This deviation can be interpreted in terms of Freed's theory on collisionally induced intersystem crossing and provides unequivocal evidence to support earlier speculations that the lengthening of the lifetimes at high pressures is due to saturation in depopulation of the ³B₁ state.     

Experiments with Enhanced Mode Thermionic Converters

Reduction of the ionization and scattering losses associated with ignited mode cesium diodes is essential for high thermal-to-electrical conversion efficiency. Use of an auxiliary electrode in conjuction with a noble gas in the interelectrode space should permit more efficient ion generation for space charge neutralization. The characteristics of a thermionic triode utilizing a ring electrode and a dispenser cathode emitter have been studied as a function of xenon pressure, cesium reservoir temperature, spacing, electrode temperature and pulse parameters (i.e., potential, duration and repetition rate) applied to the auxiliary electrode. Pulsed operation significantly enhanced output power with uniform discharges appearing to be sustained at emitter-collector spacings as low as 0.5 mm.     

Raman investigation of rutile RuO2

We report the first Raman investigation of the rutile material RuO₂. The four allowed first-order Raman-active phonon modes have been observed and classified. Comparison is made with other rutile materials.     

Analysis of the lattice,strong coupling series for g0φ4 field theory in d dimensions

We analyze the renormalized strong coupling series for lattice g₀φ⁴ field theory which is a double series in x = M⁴a⁴/g₀a_4?dandy = 1/M²a², where M is the renormalized mass, a the lattice spacing, g₀ the bare coupling constant and d the dimension of space-time. We extrapolate to large y for fixed x by using a Padé-like extrapolation technique. We study the dimensionless renormalized coupling constant G/M^4?d and find that as we approach the continuum(x → 0, y → ∞) the entire spectrum of g₀ from zero to infinity can be studied. Our results for d = 1,2,3,4 based on a series in y up to y⁵ and in x up to x³ show that for fixed lattice spacing a, G/M^4?d is a monotonic function of g₀ ranging from zero at g₀ = 0 to a maximum at g₀ = ∞. Using the high temperature expansion results, we have also derived 9 terms in y on 8 lattices of dimension 1,2,3 and 4 for the linear term in x, and studied this series to see if one can see a breakdown in this monotonic behavior of G for large y. The analysis of this latter series is inconclusive.     

Reactant adsorption in differential pulse polarography: Effects of adsorptive depletion of reactant,non-linear adsorption isotherms and uncompensated resistance

Digital simulation techniques are applied to the diagnosis of the ways in which the peak currents and wave shapes of differential pulse polarograms are affected by the adsorption of reactants or products. The changes in the polarograms introduced by the items mentioned in the title are examined and their magnitudes calculated and compared with experimental polarograms. Some implications of the results in analytical applications of differential pulse polarography are described.