Photochemistry of the SO2, 2-pentene system at 3660 Å

The photolysis of SO₂ in the presence of cis- and trans-2-pentene has been investigated at 3660 Å and 22°C. Quantum yield measurements of the SO₂ photosensitized conversion of one isomer into the other are consistent with a mechanism in which the only participating excited electronic state of SO₂ is the SO₂(³B₁) state. Quantum yield measurements were made for a variation in P_SO2/P_isomer reactant ratios of 4.01–283 and 57.5–351 for the cis and trans isomers, respectively. The data are consistent with a mechanism in which a (SO₂-olefin)³ collision intermediate is the precursor to the photosensitized isomeric products. The intermediate undergoes unimolecular decay to yield the cis and trans isomers with probabilities of 0.26 ± 0.05 and 0.69 ± 0.04, respectively. Estimates of the quenching rate constants at 22°C for removal of SO₂(³B₁) molecules by cis- and trans-2-pentene are (0.633 ± 0.125) × 10¹¹ l./mole/sec and (1.00 ± 0.27) × 10¹¹ l./mole/sec, respectively. An experimentally determined photostationary composition, [trans-2-pentene]/[cis-2-pentene] = 2.3 ± 0.1 was in fair agreement with that of 1.7 ± 0.7 as predicted from kinetic data derived in this study.     

On generating regular elements in the semigroup of binary relations

We prove the semigroup generated by four binary relations contains all regular binary relations.     

Neutron-proton radius differences and isovector deformations from π+ and π− inelastic scattering from 18O

π⁺ and π^? elastic and inelastic scattering from ¹⁸O have been measured at T(π)=164 MeV. Consistent with the results at 230 MeV, it is found that the ratio $\text{σ(π}{}^{\mathrm{?}}\text{)}\text{σ(π}{}^{\mathrm{+}}\text{)}$ for the 2₁⁺ state is 1.86(16), while for the 3₁^? state it is 0.89(6). These results are interpreted as indicating differences in neutron and proton deformations characterizing the 2₁⁺ transition and partial neutron blocking for the 3₁^? transition. Optical model analysis of elastic scattering leads to the conclusion that $\text{〈r}{}_{\mathrm{<mtext>n</mtext>}}{}^2\text{〉}{}^{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{?〈r}{}_{\mathrm{<mtext>p</mtext>}}{}^2\text{〉}{}^{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{=0.03(3)}\text{fm}$.     

Necessary conditions for normed convergence of critical multitype Bienaymé-Galton-Watson processes without variance

The condition on the offspring distribution in the critical multitype Bienaymé-Galton-Watson process without variance, which was previously shown to be sufficient for the existence of the analogue of the exponential limit law, is now shown also to be necessary. This completely extends previous one-type work of R. S. Slack.     

HARVESTING IN POPULATION MODELS WITH DELAYED RECRUITMENT AND AGE-DEPENDENT MORTALITY

We formulate a Volterra equation model to describe the effect of harvesting on populations with delayed recruitment and age-dependent mortality. This model is more complicated mathematically than the unharvested model, and we describe some numerical simulations which indicate the possible qualitative behaviours.     

Valuation theory: A constructive view

The theory of valuations on fields is developed in the constructive spirit of Errett Bishop. As a consequence of the general theory we are able to construct all nonarchimedean valuations on algebraic number fields and compute their ramification indices and residue class degrees. The notion of a field with a valuation for which the infimum of the values of any polynomial function can be computed plays an important role. Numerous limiting counterexamples are provided.     

Modulation spectroscopy under uniaxial stress

During the past several years the combination of modulation spectroscopy and static uniaxial stress has been developed into a powerful tool for the investigation of the relationship between the optical properties of semiconductors and their electronic energy bands. Studies of the stress-induced splittings and shifts of energy levels and oscillator strengths as well as the dependence of the induced fine structure on polarization direction and strain configuration have produced a wealth of information concerning the intrinsic properties of the undeformed crystal such as symmetries of interband optical transitions, deformation potentials, spin-exchange interaction of excitons, etc. Symmetry assignments are of considerable value for comparison with band structure calculations while the latter parameters are of significance for comparison with theories based on model calculations and systematic trends such as ionicity. This paper will review experiments and theories dealing with the effects of static uniaxial stress on those optical properties of semiconductors related to the intrinsic properties of the material with special emphasis on the modulated optical spectra.