全文获取类型
收费全文 | 3180篇 |
免费 | 58篇 |
国内免费 | 7篇 |
专业分类
化学 | 2082篇 |
晶体学 | 17篇 |
力学 | 37篇 |
数学 | 538篇 |
物理学 | 571篇 |
出版年
2016年 | 56篇 |
2015年 | 46篇 |
2014年 | 48篇 |
2013年 | 76篇 |
2012年 | 87篇 |
2011年 | 118篇 |
2010年 | 63篇 |
2009年 | 77篇 |
2008年 | 107篇 |
2007年 | 106篇 |
2006年 | 101篇 |
2005年 | 92篇 |
2004年 | 86篇 |
2003年 | 84篇 |
2002年 | 78篇 |
2001年 | 54篇 |
2000年 | 51篇 |
1999年 | 27篇 |
1998年 | 37篇 |
1997年 | 24篇 |
1996年 | 37篇 |
1995年 | 47篇 |
1994年 | 41篇 |
1993年 | 45篇 |
1992年 | 37篇 |
1991年 | 29篇 |
1990年 | 38篇 |
1989年 | 47篇 |
1988年 | 57篇 |
1987年 | 44篇 |
1986年 | 39篇 |
1985年 | 51篇 |
1984年 | 31篇 |
1983年 | 26篇 |
1982年 | 24篇 |
1981年 | 47篇 |
1980年 | 42篇 |
1979年 | 50篇 |
1978年 | 47篇 |
1977年 | 32篇 |
1976年 | 29篇 |
1975年 | 41篇 |
1974年 | 27篇 |
1973年 | 37篇 |
1972年 | 31篇 |
1971年 | 38篇 |
1934年 | 27篇 |
1933年 | 24篇 |
1931年 | 19篇 |
1912年 | 25篇 |
排序方式: 共有3245条查询结果,搜索用时 15 毫秒
161.
Three carrageenans derived from red algae and three partially modified carrageenans were tested for their ability to inhibit the formation of new blood capillaries on the chorionallantois membrane of the hen egg. It could be clearly demonstrated that they were better angiogenesis inhibitors than the standard compound suramin. 相似文献
162.
Alfred Schmidpeter Franz Steinmüller Konstantin Karaghiosoff 《Heteroatom Chemistry》1994,5(4):385-390
The triazaphosphole 1 adds sulfur along with HCl or H2S to yield, respectively, the dihydrotriazaphosphole thiochloride 4 and sesquisulfide 5 (two diastereomers). In pyridine solution, 1 adds sulfur alone to yield the trimer of a triazaphosphole monosulfide 7 . Its central cyclotriphosphazane trisulfide ring has a trans structure and a boat conformation. 相似文献
163.
1,1-Difluorodecamethyl- and 1,1,4,4-tetrafluorooctamethylcyclohexasilane were synthesized by the reaction of LiF with the corresponding trifluoromethanesulfonic derivatives and were characterized by spectroscopic methods, mainly by modern NMR techniques. The stability of the fluorinated cyclosilanes decreases with an increase of fluorine substituents. This seems to be the reason for the instability of perfluorinated cyclosilanes. 相似文献
164.
Egils Avots Klvs Jermakovs Maie Bachmann Laura Peske Cagri Ozcinar Gholamreza Anbarjafari 《Entropy (Basel, Switzerland)》2022,24(2)
Depression is a public health issue that severely affects one’s well being and can cause negative social and economic effects to society. To raise awareness of these problems, this research aims at determining whether the long-lasting effects of depression can be determined from electroencephalographic (EEG) signals. The article contains an accuracy comparison for SVM, LDA, NB, kNN, and D3 binary classifiers, which were trained using linear (relative band power, alpha power variability, spectral asymmetry index) and nonlinear (Higuchi fractal dimension, Lempel–Ziv complexity, detrended fluctuation analysis) EEG features. The age- and gender-matched dataset consisted of 10 healthy subjects and 10 subjects diagnosed with depression at some point in their lifetime. Most of the proposed feature selection and classifier combinations achieved accuracy in the range of 80% to 95%, and all the models were evaluated using a 10-fold cross-validation. The results showed that the motioned EEG features used in classifying ongoing depression also work for classifying the long-lasting effects of depression. 相似文献
165.
The crystal structure of the title compound has been determined by single crystal X-ray diffraction methods at 98 K. Zinc azide · 2-methyl pyridine crystallizes in the space group P1 with a = 6.028(2) Å, b = 7.610(3) Å, c = 10.052(4) Å, α = 92.81(3)°, β = 101.08(2)·, γ = 94.64(3)° and Z = 2. Least-squares refinement gave an R value of Rw = 0.039 for 2096 observed reflections. Each zinc atom is surrounded by four nitrogen atoms of different azide groups and one nitrogen atom of the pyridine adduct in a distorted trigonal bipyramidal fashion. The ZnN5-polyhedra share common edges to form chains along the crystallographic a-axis. 相似文献
166.
167.
Benedikt Nowak Oskar Karlström Peter Backman Anders Brink Maria Zevenhoven Severin Voglsam Franz Winter Mikko Hupa 《Journal of Thermal Analysis and Calorimetry》2013,111(1):183-192
In order to determine the intrinsic reactivity behavior from thermogravimetry studies, the experimental conditions should be such that the reactions are not mass transfer limited. Biomass char usually has a higher reactivity than coal chars. Therefore, mass transfer limitations may be more problematic when studying biomass char reactivity. Chemical reaction kinetics and mass transfer processes present in thermogravimetry are used for modeling the overall reaction rate for spruce bark CO2 gasification. Thermogravimetric experiments are carried out between 700 and 900 °C, and the CO2 concentration is varied between 10 and 90 vol%. The intrinsic activation energy is found to be 120 kJ mol?1. The transition temperature between regimes I and II is here defined when the fraction apparent to true activation energy equals 0.75. Higher external mass transfer (e.g., by decreasing the diffusion path through the crucible’s freeboard), decreasing the sample amounts, and higher CO2 partial pressures for the Langmuir–Hinshelwood reaction type increase the transition temperature. The results show that the transition temperature between regimes I and II conditions is approx. 1,030 °C for 90 vol% CO2. 相似文献
168.
169.
170.
Synthesis of Structurally Varied 1,3‐Disiloxanediols and Their Activity as Anion‐Binding Catalysts
下载免费PDF全文
![点击此处可从《Chemistry (Weinheim an der Bergstrasse, Germany)》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Kayla M. Diemoz Sean O. Wilson Prof. Dr. Annaliese K. Franz 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(51):18349-18353
A series of new 1,3‐disiloxanediols has been synthesized, including naphthyl‐substituted and unsymmetrical siloxanes, and demonstrated as a new class of anion‐binding catalysts. In the absence of anions, diffusion‐ordered spectroscopy (DOSY) displays self‐association of 1,3‐disiloxanediols through hydrogen‐bonding interactions. Binding constants determined for 1,3‐disiloxanediol catalysts indicate strong hydrogen‐bonding and anion‐binding abilities with unsymmetrical siloxanes displaying different hydrogen‐bonding abilities for each silanol group. 相似文献