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71.
Wolstenholme DJ Titah JT Che FN Traboulsee KT Flogeras J McGrady GS 《Journal of the American Chemical Society》2011,133(41):16598-16604
The solid-state structures of LiNH(2)BH(3) and NaNH(2)BH(3) have been shown recently to exhibit intricate M(δ+)···(δ-)H-B and N-H(δ+)···(δ-)H-B interactions. However, closer inspection of these structures reveals additional homopolar H···H interactions, viz., B-H(δ-)···(δ-)H-B and N-H(δ+)···(δ+)H-N, which contribute to the relative stability of the extended structures of these crystalline materials. In addition, an NMR study of the isotopomer LiND(2)BH(3) shows that a significant quantity of H(2) is desorbed thermally along with HD, which can only arise from hydride-hydride interactions, either directly from B-H(δ-)···(δ-)H-B moieties or indirectly through the participation of Li-H intermediates. 相似文献
72.
Buell AK Esbjörner EK Riss PJ White DA Aigbirhio FI Toth G Welland ME Dobson CM Knowles TP 《Physical chemistry chemical physics : PCCP》2011,13(45):20044-20052
Much effort has focussed in recent years on probing the interactions of small molecules with amyloid fibrils and other protein aggregates. Understanding and control of such interactions are important for the development of diagnostic and therapeutic strategies in situations where protein aggregation is associated with disease. In this perspective article we give an overview over the toolbox of biophysical methods for the study of such amyloid-small molecule interactions. We discuss in detail two recently developed techniques within this framework: linear dichroism, a promising extension of the more traditional spectroscopic techniques, and biosensing methods, where surface-bound amyloid fibrils are exposed to solutions of small molecules. Both techniques rely on the measurement of physical properties that are very directly linked to the binding of small molecules to amyloid aggregates and therefore provide an attractive route to probe these important interactions. 相似文献
73.
M. I. Mendivil B. Krishnan F. A. Sanchez S. Martinez J. A. Aguilar-Martinez G. A. Castillo D. I. Garcia-Gutierrez S. Shaji 《Applied Physics A: Materials Science & Processing》2013,110(4):809-816
Pulsed laser ablation in liquid media (PLALM) is a prominent technique for the controlled fabrication of nanomaterials via rapid reactive quenching of ablated species at the interface between the plasma and liquid. Results on nanoparticles and nanocrystals formed by PLALM of silver (Ag) and antimony (Sb) solid targets in different liquid environments (Sodium Dodecyl Sulfate, distilled water) are presented. These experiments were done by irradiating solid targets of Ag and Sb with a nanosecond pulsed Nd:YAG laser output of wavelength 532 nm. Nanoparticles of silver and nanocrystals of antimony oxide (Sb2O3) obtained were characterized using UV-Vis spectrometry, Scanning Electron Microscopy (SEM), transmission electron microscopy (TEM), X-ray Energy Dispersion Analysis (EDAX) and X-ray diffractometry (XRD). The morphology of nanomaterials formed is studied as a function of surfactant environment. The silver nanoparticles obtained were spherical of size in the order of 10–35 nm in solution of SDS having different concentrations. In case of the Sb target, ablation was performed in two different molarities of SDS solution and distilled water. Nanocrystals of Sb2O3 in powder form having cubic and orthorhombic phases were formed in SDS solution and as fibers of nanocrystals of cubic Sb2O3 in distilled water. 相似文献
74.
Franklin R.N. 《IEEE transactions on plasma science. IEEE Nuclear and Plasma Sciences Society》2003,31(2):304
Godyak and Sternberg (2003) reassert their contention that one can obtain a satisfactory physical solution to the active plasma-collisionless sheath by patching together plasma and sheath. They choose to do it at an arbitrary point where the sheath electric field is kT/sub e/ /e/spl lambda//sub D/. If one tacks their sheath solution to the full plasma solution, then the field is infinity on the plasma side and finite on the sheath side. Alternatively, if one terminates the plasma solution where the plasma field is kT/sub e//e/spl lambda//sub D/, then one has continuity of electric field, but not of its gradient, since on the sheath side it is zero and on the plasma side of order L//spl lambda//sub D/, where L is the size of the plasma. Furthermore, in achieving continuity of the field, one has introduced discontinuities in the ion speed and in the particle densities. Thus, in no sense is a joining which denies the existence of a transition layer, smooth. J. Ockendon and H. Ockendon, my colleagues in the production of our paper describing the transition layer (Franklin et al., 1970), privately expressed disappointment in not finding a proof of the existence and uniqueness of our solution. Such a formal mathematical proof has been given recently by Slemrod (2002). Smooth joining of active plasma and collisionless sheath within the context of a fluid model or free fall model of the ion motion, does require a transition layer and of length scale intermediate between L and /spl lambda//sub D/. 相似文献
75.
Polysubstituted 2-carboxylate and 2-phosphonate pyrroles are prepared by aromatization of the corresponding 3-oxo 2-carboxylate and 2-phosphonate NH-pyrrolidines using air. Reaction of electrophiles with 3-oxo pyrrolidine dianions readily introduces substituents, regioselectively at C-4 in these pyrrolidines. 相似文献
76.
The appearance potentials for loss of H2O and DOH from the constitutional isomers 3,5-dideuterocyclohexanol and 4,4- dideuterocyclohexannol show, in agreement with proposals based on stereoselectivites, that 1,3 loss of water is energetically more costly than 1,4 loss of water. 相似文献
77.
Jahar L. Mukherjee Chandra P. Khattak Kedar P. Gupta Franklin F.Y. Wang 《Journal of solid state chemistry》1978,24(2):163-167
Ba2NaNb5O15 (BSN) exhibits a large thermal contraction in its c-axis between 350° and 750°C. This behaviour contributes to a serious cracking problem during its crystal growth. The substitutions of Gd for Ba and/or Na in BSN can be made with either anion or cation compensation. The former, namely, type A, compositions were found to eliminate the thermal contraction behaviors, and had small variations in their linear thermal expansion coefficients, α, between 50° and 650°C. With good ferroelectric and dielectric properties, they showed potentials to replace the BSN crystal in electro-optic devices. 相似文献
78.
79.
80.
W.R. Franklin 《Nuclear Physics B》1975,91(1):160-178
Decay modes and lifetimes of quarks, vector mesons and protons are determined for the unified model of leptons and hadrons recently proposed by Pati and Salam. It is found that while both the quarks and gauge mesons decay too rapidly to be observed, protons will be comfortably stable against decay into leptons, consistent with earlier estimates and existing experimental evidence. It is of special interest that while quarks may not be directly observable, their presence may be verified owing to the uniqueness of their preferred decay into quite a large number of pions. We also discuss an anomalous lepton-hadron scattering process whose occurrence would imply the presence of exotic SU(4) gluons carrying both baryon and lepton number. 相似文献