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Dr. Tao Liu Dr. Aline Nonat Dr. Maryline Beyler Dr. Martín Regueiro‐Figueroa Dr. Katia Nchimi Nono Dr. Olivier Jeannin Dr. Franck Camerel Dr. François Debaene Dr. Sarah Cianférani‐Sanglier Prof. Raphaël Tripier Dr. Carlos Platas‐Iglesias Dr. Loïc J. Charbonnière 《Angewandte Chemie (International ed. in English)》2014,53(28):7259-7263
Lanthanide complexes (Ln=Eu, Tb, and Yb) that are based on a C2‐symmetric cyclen scaffold were prepared and characterized. The addition of fluoride anions to aqueous solutions of the complexes resulted in the formation of dinuclear supramolecular compounds in which the anion is confined into the cavity that is formed by the two complexes. The supramolecular assembly process was monitored by UV/Vis absorption, luminescence, and NMR spectroscopy and high‐resolution mass spectrometry. The X‐ray crystal structure of the europium dimer revealed that the architecture of the scaffold is stabilized by synergistic effects of the Eu? F? Eu bridging motive, π stacking interactions, and a four‐component hydrogen‐bonding network, which control the assembly of the two [EuL] entities around the fluoride ion. The strong association in water allowed for the luminescence sensing of fluoride down to a detection limit of 24 nM . 相似文献
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In this study, through the method of rapid controlled precipitation (RCP), the influence of temperature and dissolved CO2 on the scaling capacity of mineral water in the presence of copper and zinc ions was studied in laboratory experiments. The
results indicated that with a rise in temperature or concentration of dissolved CO2, the scaling time of Salvetat water greatly decreased and the rate of precipitation considerably increased; therefore, the
minimum dosage of copper or zinc ion for achieving total inhibition of scaling needed to be increased, which would provide
better guidance for practical use of metal ions in inhibiting the scaling of drinking water. 相似文献
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Here we describe the synthesis of a mesoporous composite material using the self-assembly of well defined tubular building blocks obtained from the exfoliation of [Nb6O17(4-)]n sheets. 相似文献
38.
A unified analytic solution to the Busemann-Petty problem was recently found by Gardner, Koldobsky and Schlumprecht. We give an elementary proof of their formulas for the inverse Radon transform of the radial function
of an origin-symmetric star body
. 相似文献
39.
Franck Leprévost 《manuscripta mathematica》1992,75(1):303-326
We construct here, forl=2g
2
+2g+1 or2g
2
+3g+1, a family with one parameter of hyperelliptic curves of genusg overQ such that its jacobian has a point of orderl rational overQ(t). Wheng=2 the method allows to construct, forl=17, 19 or 21 a family with one parameter of hyperelliptic curves of genus 2 overQ such that its jacobian has a point of orderl rational overQ(t).
相似文献
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