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31.
Comas E Gimeno RA Ferré J Marcé RM Borrull F Rius FX 《Journal of chromatography. A》2003,988(2):277-284
We used the Generalized Rank Annihilation Method (GRAM), a second-order calibration method, to quantify aromatic sulfonates in water with high-performance liquid chromatography (HPLC) when interferences coeluted with the analytes of interest. With GRAM, we can quantify in only two chromatographic analyses, one for a calibration sample and one for the unknown sample. The calculated concentrations were not statistically different to those obtained when the chromatographic separation of the unknown sample was modified in order to completely separate the analyte from the interferences before univariate calibration. With GRAM, the concentrations are determined much more quickly because a complete resolution is not required. 相似文献
32.
Rojo I Teixidor F Viñas C Kivekäs R Sillanpää R 《Chemistry (Weinheim an der Bergstrasse, Germany)》2004,10(21):5376-5385
The anionic chelating ligand [1,1'-(PPh2)2-3,3'-Co(1,2-C2B9H10)2]- has been synthesized from [3,3'-Co(1,2-C2B9H11)2]- in very good yield in a one-pot process with an easy work-up procedure. The coordinating ability of this ligand has been studied with Group 11 metal ions (Ag, Au) and with transition-metal ions (Pd, Rh). The two dicarbollide halves of the [1,1'-(PPh2)2-3,3'-Co(1,2-C2B9H10)2]- ligand can swing about one axis in a manner analogous to the constituent parts of BINAP and ferrocenyl phosphine derivatives. All these ligands function as hinges, with the most important property in relation to the coordination requirements of the metal being the PP distance. [1,1'-(PPh2)2-3,3'-Co(1,2-C2B9H10)2]-, BINAP, ferrocenyl phosphine derivatives, and other hinge ligands present a range of different PP separations, and consequently different coordination spheres and dispositions around metal cations. To account for these differences, the equation Dphi2 = D02 + 4 R2cos2(90-phi/2) has been developed. It relates the PP distance (Dphi) in a complex with the minimum PP distance (D0) that is characteristic of the hinge-type ligand. 相似文献
33.
Rojo I Teixidor F Kivekäs R Sillanpää R Viñas C 《Journal of the American Chemical Society》2003,125(48):14720-14721
The unprecedented metal-mediated transformation of an alkyne into a B,B' bridging alkene is reported. Also, the unprecedented synthesis of a conjugated dialkene derivative of [3,3'-Co(1,2-C2B9H11)2]- generated only from an alkyne, contrary to the usual case where an alkyne and an alkene are needed, is described. This has been possible through the singular capacity of a B-H to produce hydroboration. 相似文献
34.
Esteve-Turrillas FA Armenta S Moros J Garrigues S Pastor A de la Guardia M 《Journal of chromatography. A》2005,1065(2):321-325
A non-destructive, fast and environmentally friendly procedure has been developed for cocaine determination in euro bank notes. Cocaine was extracted with 15 ml methanol by vortex agitation during 5 min. The extract was evaporated and reconstituted in 0.5 ml methanol. GC-MS-MS analysis was performed using as precursor ion m/z 182.2, with an excitation energy voltage of 1.60 eV, being the product ions measured m/z 150.2 and 82.0. A limit of detection of 0.15 ng per note and a repeatability of 6%, established from the relative standard deviation, of a 1 ng ml(-1) level, were achieved. Recoveries of 101+/-2 and 98+/-3% were obtained for samples spiked with 100 and 10 microg respectively. Results show that all the euro bank notes measured (16 samples) were contaminated with cocaine in the range between 1.25 and 889 microg. Two different contamination levels, high level (150-889 microg) and low one (1.25-77 microg) were found and it could be related with the direct or indirect contact with the drug. 相似文献
35.
Torres D Lopez N Illas F Lambert RM 《Journal of the American Chemical Society》2005,127(31):10774-10775
The heterogeneously catalyzed epoxidation of alkenes is experimentally challenging, theoretically interesting, and technologically important. Although large-scale ethylene epoxidation is universally carried out with Ag catalysts, recent laboratory studies on single crystal surfaces show that Cu is intrinsically much more selective than Ag in the epoxidation of a variety of terminal alkenes. The reasons for this striking difference between Ag and Cu have been investigated by means of density functional theory. It is found that the fundamental cause is the inversion in the ordering of activation barriers for the competing pathways to epoxide formation versus acetaldehyde formation (the latter being the first step on the route to combustion). On Cu, epoxide formation is less activated than aldehyde formation; the opposite is true on Ag. This behavior is associated with a late transition state to epoxidation on Cu (i.e., product-like) compared to an early (reactant-like) transition state to epoxidation on Ag. 相似文献
36.
37.
Time shift correction in second-order liquid chromatographic data with iterative target transformation factor analysis 总被引:4,自引:0,他引:4
Enric Comas R. Ana Gimeno Joan Ferr Rosa M. Marc Francesc Borrull F. Xavier Rius 《Analytica chimica acta》2002,470(2):607-173
When the generalized rank annihilation method (GRAM) is applied to liquid chromatographic data with diode-array detection, an important problem is the time shift of the peak of the analyte in the test sample. This problem leads to erroneous predictions. This time shift can be corrected if a time window is selected so that the chromatographic profile of the analyte in the test sample is trilinear with the peak of the analyte in the calibration sample. In this paper we present a new method to determine when this condition is met. This method is based on the curve resolution with iterative target transformation factor analysis (ITTFA). The calibration and test matrices are independently decomposed into profiles and spectra, and aligned before GRAM is applied. Here we study two situations: first, when the calibration matrix has one analyte and second, when it has two analytes. When the calibration matrix has two analytes, we selectively determine the time window for the analyte to be quantified. There were considerably fewer prediction errors after correction. 相似文献
38.
The ab initio two-state model for electron transfer induced by an external electric field has been applied to the chloride oxidation on Cu, Rh, Pd, Ag, Pt and Au (001) surface models. The two electronic states involved in the model represent physical situations where the electron transferred from the chloride anion to the metal surface lies either on the halide or on the metal substrate. The model assumes that electron transfer takes place when these two states become degenerate and this is achieved by applying an external electric field. Two different situations representing either ultrahigh vacuum or electrochemical conditions have been considered. For the former the present study shows that electric field necessary to achieve degeneracy of the two electronic states is directly related to the metal surface work function whereas for the latter, it is found to be rather insensitive to the metal surface. 相似文献
39.
The preparation and crystal structure determination of the iron(III) compound of formula [(NH(4))(2)[Fe(2)O(ox)(2)Cl(2)].2H(2)O](n) (1) (ox = oxalate dianion) are reported here. Complex 1 crystallizes in the orthorhombic system, space group Fdd2, with a = 14.956(7) A, b = 23.671(9) A, c = 9.026(4) A, and Z = 8. The structure of complex 1 consists of the chiral anionic three-dimensional network [Fe(2)O(ox)(2)Cl(2)](2-) where the iron(III) ions are connected by single oxo and bisbidentate oxalato groups. The metal-metal separations through these bridging ligands are 3.384(2) and 5.496(2) A, respectively. Ammonium cations and crystallization water molecules are located in the helical pseudohexagonal tunnels defined by iron atoms. The longest iron-iron distance in the pseudohexagonal tunnel is 15.778(2) A whereas the shortest one is 8.734(2) A. The iron atoms are hexacoordinated: a terminal chloro ligand and five oxygen atoms, that of the oxo group and four from two cis coordinated oxalate ligands, build a distorted octahedral environment around the metal atom. The Fe-O(oxo) bond distance [1.825(2) A] is significantly shorter than the Fe(III)-O(ox) [average value 2.103(4) A] and Fe(III)-Cl bond distances [2.314(2) A]. Magnetic susceptibility measurements of 1 in the temperature range 2.0-300 K reveal the occurrence of a susceptibility maximum at 195 K and a transition toward a magnetically ordered state in the lower temperature region with T(c) = 40 K. The strong antiferromagnetic coupling through the oxo bridge (J = -46.4 cm(-1), the Hamiltonian being H = -JS(A).S(B)) accounts for the susceptibility maximum whereas a weak spin canting of approximately 0.3 degrees due to the antisymmetric magnetic exchange within the chiral three-dimensional network is responsible for the magnetic ordering. The values of coercive field (H(c)) and remnant magnetization (M(r)) obtained from the hysteresis loop of 1 at 5 K are 4000 G and 0.016 micro(B). 相似文献
40.
Colacio E Lloret F Kivekäs R Suárez-Varela J Sundberg MR Uggla R 《Inorganic chemistry》2003,42(2):560-565
Two polymorphic cyano-bridged Au(I)-Ni(II) bimetallic complexes of formulas [Ni(en)2Au(CN)2][Au(CN)2] (1) and [Ni(en)2[Au(CN)2]2] (2) have been prepared from the 1:2 reaction between [Au(CN)2]- and either [Ni(en)2Cl2]Cl or [Ni(en)3]Cl2.2H2O, respectively. The structure of 1 consists of polymeric cationic chains of alternating [Au(CN)2]- and [Ni(en)2]2+ units running along the a axis and [Au(CN)2]- anions lying between the chains. The noncoordinated dicyanoaurate anions are aligned perpendicular to the ac plane and involved in aurophilic interactions with the bridging dicyanoaurate groups, ultimately leading to a 2D bimetallic grid. The structure of 2 consists of trinuclear molecules made of two [Au(CN)2]- anions linked to [Ni(en)2]2+ unit in trans configuration. Trinuclear units are joined by aurophilic interactions to form 1D zigzag chains. The magnetic properties of these compounds are strongly dominated by the local anisotropy of the octahedral Ni(II) ions, thus indicating that the magnetic exchange interaction mediated by dicyanoaurate bridging groups, if it exists, is very weak. To get insight into the electronic properties of the inter- and intramolecular interactions of the [Au(CN)2]- building blocks, the structures of different aggregates of dicyanogold units were optimized and then analyzed by making use of atoms-in-molecules (AIM) theory. Moreover, bond indices were calculated by methods based upon nonlinear population analysis. 相似文献