Water-Soluble Organometallic Compounds. 8[1]. Synthesis, Spectral Properties, and Crystal Structures of 1,3,5-Triaza-7-phosphaadamantane (PTA) Derivatives of Metal Carbonyl Clusters: Ru3(CO)9(PTA)3 and Ir4(CO)7(PTA)5

The syntheses of Ru₃(CO)₉(PTA)₃ and Ir₄(CO)₇(PTA)₅ were accomplished through the thermal reactions of Ru₃(CO)₁₂ or Ir₄(CO)₁₂ with the water-soluble phosphine, PTA(1,3,5-triaza-7-phosphaadamantane). The ruthenium derivative was shown by X-ray crystallography to consist of a triangular Ru₃ core with three nearly equal Ru–Ru bonds, with each ruthenium atom bearing an equatorially positioned PTA ligand. In Ir₄(CO)₇(PTA)₅ the iridium atoms define a tetrahedron which is bridged on three edges by CO ligands. One basal iridium atom contains two PTA ligands, while the other two basal and the apical iridium atoms each possess one PTA ligand in their coordination spheres. Although, Ru₃(CO)₉(PTA)₃ is only sparingly soluble in pure water, it is very soluble in aqueous solution of pH<4. Indeed the triruthenium cluster can be extracted reversibly between an aqueous and an organic phase (e.g., CH₂Cl₂) by changing the pH of the aqueous phase. On the other hand the more highly PTA substituted cluster, Ir₄(CO)₇(PTA)₅, exhibits good solubility in aqueous solution (pH 7 and below) and a variety of organic solvents. Both cluster derivatives are stable in deoxygenated, aqueous solutions for extended period of time (>24 h).     

Restricted Percolation Critical Exponents in High Dimensions

Despite great progress in the study of critical percolation on ℤ^d for d large, properties of critical clusters in high-dimensional fractional spaces and boxes remain poorly understood, unlike the situation in two dimensions. Closely related models such as critical branching random walk give natural conjectures for the value of the relevant high-dimensional critical exponents; see in particular the conjecture by Kozma-Nachmias that the probability that 0 and (n, n, n, …) are connected within [−n, n]^d scales as n^{−2 − 2d} . In this paper, we study the properties of critical clusters in high-dimensional half-spaces and boxes. In half-spaces, we show that the probability of an open connection (“arm”) from 0 to the boundary of a sidelength n box scales as n⁻³ . We also find the scaling of the half-space two-point function (the probability of an open connection between two vertices) and the tail of the cluster size distribution. In boxes, we obtain the scaling of the two-point function between vertices which are any macroscopic distance away from the boundary. Our argument involves a new application of the “mass transport" principle which we expect will be useful to obtain quantitative estimates for a range of other problems. © 2020 Wiley Periodicals LLC     

Ion coupling efficiency for an extraction applied-B ion diode onthe HELIA linear-induction adder in positive polarity

Initial experiments to investigate coupling of the four-stage HELIA linear-induction accelerator to a uniformly insulated applied-B ion diode in planar extraction geometry are reported. Results describing the efficient operation of an applied-B extraction ion diode coupled to the HELIA linear induction accelerator operated in positive polarity are reported. Operation of a close-coupled, undermatched, applied-B diode on HELIA was consistent with magnetically insulated transmission line (MITL) electron flow intermediate between locally emitted flow and generalized flow, rather than with full-gap flow. Peak ion coupling efficiencies of 60-70% and peak ion power levels of 0.3-0.4 TW have been achieved     

An NMR Investigation of the Conformational Effect of Nitroxide Spin Labels on Ala-Rich Helical Peptides

Nitroxide spin labels, in conjunction with electron spin resonance (ESR) experiments, are extensively employed to probe the structure and dynamics of biomolecules. One of the most ubiquitous spin labeling reagents is the methanethiosulfonate spin label which attaches a spin label selectively to Cys residues via a disulfide bond (Cys-SL). However, the actual effect of the nitroxide spin label upon the conformation of the peptide or protein cannot be unambiguously determined by ESR. In this study, a series of 16-residue Ala-rich helical peptides was characterized by nuclear magnetic resonance techniques. The C_αH chemical shift analysis, NOEs, and³J_NHαcoupling constants for peptides with no Cys, free Cys, and Cys-SL (with the N–O group reduced) were compared. These results indicate that while replacement of an Ala with a Cys residue causes a loss of overall helical structure, the Cys-SL residue is helix supporting, as would be expected for a non-β-branched aliphatic amino acid. Thus, the Cys-SL residue does not perturb helical structure and, instead, exhibits helix-stabilizing characteristics similar to that found for Ala, Met, and Leu.     

Progress in a trajectory interpretation of the Klein-Gordon equation

A trajectory interpretation is developed for the Klein-Gordon equation in one dimension. The development is couched in a Hamilton-Jacobi representation. Equations of motion are developed. Different trajectories for a given eigenvalue energy are shown to manifest different microstates of the eigenfunction of that particular energy.     

A Multiple-criteria Approach to Dynamic Cold-ingot Substitution

Bethlehem Steel's plant at Bethlehem, Pennsylvania uses a computer-based mill-providing procedure to plan ingot requirements for the production of structural shapes and pilings. When not enough hot steel is available to meet all the ingot requirements, cold steel ingots from inventory must be substituted in order to meet the production plan. A computer system was developed that dynamically selects cold ingots to use when hot steel is not available. This system selects cold ingots based first on ingot-selection priorities, and secondly, within priorities, on several criteria. An approach was developed that assigns a penalty to each feasible cold ingot such that the priorities and multiple criteria are addressed by simply ranking the ingots based on their penalty values. Ingots are selected from the top of the ranked list, and the results are consistently acceptable to the steel-providers at the Bethlehem plant. The system improves yield and reduces material-handling costs.     

Polarization dependency of enhanced multipath radar backscattering from an ocean-like surface

Previous analyses of electromagnetic scattering from a two-scale ocean surface assumed the tilts on a large-scale surface to be small. This means that multiple scattering between large-scale roughnesses is insignificant. If the tilts are not small, multipath-enhanced backscattering may occur due to quasi-specular reflections between the opposite slopes of a large-scale surface component. We have considered the simplest situation; this involves one reflection from the large-scale component and one single-scattering from the small-scale component. The coherent addition of this process to the reciprocally reverse one creates multipath-enhanced backscattering. The relative gain in the HH backscattering cross section up to the level of the VV signal was obtained for surface-wave slopes of about 30° and for large incidence angles. This gain occurs because the VV signal experiences an extinction during reflection at incident angles close to the pseudo-Brewster angle. The presented model provides insight into one scattering mechanism that is possibly responsible for the departure of radar sea experimental data from predictions by the conventional two-scale model.