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101.
102.
We study the ergodic theory of non-conservative C 1-generic diffeomorphisms. First, we show that homoclinic classes of arbitrary diffeomorphisms exhibit ergodic measures whose supports coincide with the homoclinic class. Second, we show that generic (for the weak topology) ergodic measures of C 1-generic diffeomorphisms are non-uniformly hyperbolic: they exhibit no zero Lyapunov exponents. Third, we extend a theorem by Sigmund on hyperbolic basic sets: every isolated transitive set Λ of any C 1-generic diffeomorphism f exhibits many ergodic hyperbolic measures whose supports coincide with the whole set Λ.  相似文献   
103.
Inspired by statistical physics, we present a probabilistic approach to portfolio selection. Instead of seeking the global extremum of some chosen utility function, we reinterpret the latter as a probability distribution of ‘optimal’ portfolios, and select the portfolio that is given by the mean value with respect to that distribution. Compared to the standard maximization of expected utility, this approach has several attractive features. First, it significantly reduces the excessive sensitivity to external parameters that often plague optimization procedures. Second, it mitigates the commonly observed concentration on too few assets; and third, it provides a natural and consistent way to account for the incompleteness of information and the aversion to uncertainty. Supportive empirical evidence is derived by using artificial data to simulate finite-sample behavior and out-of-sample performance.  相似文献   
104.
With reference to the evaluation of the speed–precision efficiency of pricing and hedging of American Put options, we present and discuss numerical results obtained on the basis of four different large enough random samples according to the relevance of the American quality (relative importance of the early exercise opportunity) of the options. Here we provide a comparison of the best methods (lattice based numerical methods and an approximation of the American Premium analytical procedure) known in literature along with some key methodological remarks.  相似文献   
105.
    
The different possible sources of the intraannular hydrogens in the dehydroxylated calixarenes obtained by reductive cleavage of the calix [4] arene diethyl phosphate esters 2 and 6 are analysed. Two calixarene diethyl phosphate esters (4 and 5) full deuterated in the ethyl groups were synthesized. Reductive cleavage of 4 and 5 (potassium-ammonia) resulted in the formation of the OH-depleted calixarenes 3 and 7, respectively, which did not incorporate any deuterium at the intraannular positions, as judged by integration of the NMR signals. Quenching with D2O of the reaction mixture of either 2 or 6 and potassium-ammonia did not result in any deuterium incorporation in the products. The labelling experiments rule out the possibility that the source of the intraannular hydrogens is the diethyl phosphate ester groups or the quencher. It is concluded that the most probable sources of the hydrogen atoms in the OH-depleted calixarenes is the ammonia molecule.  相似文献   
106.
This article describes the synthesis of new peptomers through a simple and efficient route using a one-pot Ugi four-component reaction. The synthesis started from either carboxylic acids or protected amino acids, primary amines, aldehydes, and isocyanides in anhydrous methanol and proceeded under stirring at room temperature. The reaction produced several functionalized peptomers in good yields (67–80%). These compounds are versatile multifunctional intermediates that can be further unprotected or functionalized to generate new molecules with numerous applications in the field of biomedicine.  相似文献   
107.
    
A novel label-free photoelectrochemical immunosensor was developed for the determination of prostate-specific antigen (PSA) based on fluorine-doped tin oxide (FTO) electrode modified with barium titanate and cadmium sulfide (BaTiO3−CdS/FTO). The photoelectrochemical current density of the BaTiO3 platform sensitized with CdS for the ascorbic acid (AA) donor molecule was higher than that observed in the absence of CdS. The BaTiO3−CdS/FTO platform was modified with PSA antibodies to produce the anti-PSA/BaTiO3−CdS/FTO immunosensor, which was incubated in solutions of PSA to inhibit the photocurrent density of the immunosensor for AA. The photocurrent density of the anti-PSA/BaTiO3−CdS/FTO immunosensor presented a linear relationship with the logarithm of the PSA concentration ranging from 1 pg mL−1 to 1 μg mL−1 with good sensitivity. The proposed method presented an experimental detection limit of 1 pg mL−1 (S/N=3). The immunosensor was successfully employed for the determination of PSA in blood serum samples, with recoveries between 98.7 %–104.4 %.  相似文献   
108.
    
A preconditioned scheme for solving sparse symmetric eigenproblems is proposed. The solution strategy relies upon the DACG algorithm, which is a Preconditioned Conjugate Gradient algorithm for minimizing the Rayleigh Quotient. A comparison with the well established ARPACK code shows that when a small number of the leftmost eigenpairs is to be computed, DACG is more efficient than ARPACK. Effective convergence acceleration of DACG is shown to be performed by a suitable approximate inverse preconditioner (AINV). The performance of such a preconditioner is shown to be safe, i.e. not highly dependent on a drop tolerance parameter. On sequential machines, AINV preconditioning proves a practicable alternative to the effective incomplete Cholesky factorization, and is more efficient than Block Jacobi. Owing to its parallelizability, the AINV preconditioner is exploited for a parallel implementation of the DACG algorithm. Numerical tests account for the high degree of parallelization attainable on a Cray T3E machine and confirm the satisfactory scalability properties of the algorithm. A final comparison with PARPACK shows the (relative) higher efficiency of AINV‐DACG. Copyright © 2000 John Wiley & Sons, Ltd.  相似文献   
109.
    
A large series of 1,2‐diaryl‐benzimidazole and 2‐aryl‐1H‐benzimidazole derivatives were synthesized with slight differences using both microwave irradiation and conventional heating methods. Usually higher yields and time reactions reduction were obtained with the former method. All compounds were assayed for their in vitro ability to inhibit human cyclooxygenases, and most of them showed an encouraging inhibitory activity and isoform selectivity in the micromolar range.  相似文献   
110.
    
A new approach for the fabrication of disposable electrochemical surfaces is presented. Conducting fibers have been produced by a two‐step process. Firstly, a fine web mat composed of nylon‐6 and ferric chloride fibers (with diameters of about 200 nm) were electrospun on a flat collector. Afterwards, the electrospun mat was exposed to pyrrole vapor under controlled dry atmosphere until each nylon thread was fully coated with a conducting polypyrrole layer. The conducting fiber mat was finally integrated within an electrochemical cell and used as a disposable sensor device. The suitability of the sensor was tested using phosphate and carbonate organic anions. The large scale fabrication of conducting tissue, in the form of a fine web of spun nanofibers, is relatively fast and inexpensive, and it paves the way to the build up of new disposable electrodes.  相似文献   
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