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141.
142.
G. Valensi R. H. Crist F. B. Brown L. Williams A. H. Wilson Busby L. S. Echols Jr M. A. Smith F. L. Hayes C. H. Townes H. K. Alber A. Knoll J. Schukal E. P. Barrett W. E. Holbrook J. S. Blair A. V. Grosse W. N. Ipatjew H. J. Hall G. B. Bachman A. Klemenc A. Stock H. Kühne A. Bellmann J. Haller W. H. Albrecht K. P. GRohr H. Hillemann H. A. Wilhelm W. MacNevin H. S. Clark K. R. More R. F. Humphreys W. W. Watson P. A. Anderson G. Atchison D. O. Holland H. Sieben T. Langer 《Analytical and bioanalytical chemistry》1944,127(1):197-202
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Micellar electrokinetic capillary chromatography (MECC) is applied to the high-speed analysis of aflatoxins. Baseline separation of the four common aflatoxins G(1), G(2), B(1) and B(2), is accomplished in less than 30 sec. Small (25 mum) internal diameter capillaries are found to be critical in maintaining high efficiency under rapid MECC separation conditions. Van Deemter-like plots are generated in order to study the effects of capillary diameter and organic solvent on efficiency under high electric field conditions. Other experimental parameters affecting efficiency are investigated, including buffer concentration, surfactant concentration, and detector time constant. Simple on-column laser-based fluorescence detection, employing helium-cadmium laser radiation at 325 nm for excitation, allows for limits of detection in the range of 0.05-0.9 femtomoles injected for underivatized aflatoxins. Considerations important in the analysis of aflatoxins in real matrices are presented. 相似文献
145.
This report outlines a rapid, reproducible method for the determination of beta-asarone, a known carcinogen, using micellar electrokinetic capillary chromatography (MEKC)-UV-vis absorbance and a simple alcohol extraction. The MEKC method is based on a running buffer comprised of 100 mM sodium dodecyl sulfate (SDS), pH 10. The method is reproducible and provides baseline separation of alpha-asarone and beta-asarone. This protocol was used to determine the beta-asarone content of Acorus calamus rhizome of a diploid variety harvested from the wetlands of the United States and the triploid variety from India obtained commercially. The results indicate raw product that originated from India contained 4.4% w/w beta-asarone, while that from the United States contained 0.2% w/w beta-asarone. Neither sample contained detectable concentrations of alpha-asarone. This is the first report of the use of MEKC to determine asarone in a natural source. 相似文献
146.
Vela J Stoian S Flaschenriem CJ Münck E Holland PL 《Journal of the American Chemical Society》2004,126(14):4522-4523
The active site iron-molybdenum cofactor of nitrogenase has sulfide-bridged pairs of redox-active, trigonal pyramidal iron atoms that are postulated to be the site of N2 transformation. A synthetic compound is described in which two three-coordinate iron(II) ions are bridged similarly by sulfide. The compound binds nitrogen donors to become trigonal pyramidal and cleaves the N-N bond of phenylhydrazine with oxidation of iron(II) to iron(III). 相似文献
147.
R. Baer asked whether the group operation of every (totally) ordered group can be redefined, keeping the same ordered set, so that the resulting structure is an Abelian ordered group. The answer is no. We construct an ordered set (G, ) which carries an ordered group (G, , ) but which islawless in the following sense. If (G, *, ) is an ordered group on the same carrier (G, ), then the group (G, *) satisfies no nontrivial equational law.Research partially supported by NSERC of Canada Grants #A4044 and A3040.Research partially supported by NSERC of Canada Grant #U0075.Research partially supported by a grant from the BSF. 相似文献
148.
Summary The synthesis and characterization of disodium 3-hydroxy-4-[(6-methyl-2-pyridyl)azo]-2, 7-naphthalenedisulfonateN-oxide and its application to the spectrophotometric determination of trace amounts of copper are described. The effects due to pH, time, reagent concentration and diverse ions are reported. The reagent exhibits good specificity for copper. Beer's law is obeyed and the molar absorbance coefficient at 536 nm is 1.8×104.
Die spektrophotometrische Bestimmung von Kupfer mit Dinatrium-3-hydroxy-4-[(6-methyl-2-pyridyl)azo]-2, 7-napbthalindisulfonat-N-oxid
Zusammenfassung Die Synthese und die Eigenschaften von Dinatrium-3-hydroxy-4-[(6-methyl-2-pyridyl)azo]-2, 7-naphthalindisulfonat-N-oxid sowie dessen Anwendung zur spektrophotometrischen Bestimmung von Kupferspuren wurden beschrieben. Die Einflüsse von pH, Zeit, Reagenskonzentration und von verschiedenen Ionen wurden angegeben. Das Reagens zeigt gute Spezifität gegenüber Kupfer. Das Beersche Gesetz wird befolgt. Der molare Extinktionskoeffizient bei 536 nm beträgt 1,8·104.相似文献
149.
150.
Daniel R. Drodge Beth Mortimer Chris Holland Clive R. Siviour 《Journal of the mechanics and physics of solids》2012,60(10):1710-1721
A revision of a classic transverse fibre impact technique is presented, as applied to the problem of obtaining the high strain-rate constitutive behaviour of commercial Bombyx mori silk. Medium tenacity nylon was also studied. Two approaches are presented: firstly a fixed pre-stress, varied impact velocity method that derives stress–strain behaviour by inverse fit; and secondly a fixed impact velocity, varied pre-stress approach, assuming basic elastic jump conditions to obtain a locus of post-impact states. The post-impact stress–strain states obtained using the two approaches converge for silk but diverge for nylon. This we attribute to silk's fine structure being able to homogenise energy dissipation at static and dynamic deformation rates. However, the coarser microstructure of nylon results in a different loading path dependence, thus divergence in the two approaches. It was also noted that silk exhibited a comparatively stable level of impact energy absorption under varying pre-stress, when compared to nylon. 相似文献