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51.
52.
Anne Sophie Voisin-Chiret Grégory Burzicki Filomena Corbo Carlo Franchini 《Tetrahedron》2010,66(40):8000-8005
One-pot reaction for the synthesis of novel phenylpyridyl derivatives and mixed quater phenylpyridyl compounds is described by using the Garlanding approach. The reactions proceed with moderate to good yields in mild conditions and good reaction times. This work represents a second application of the simplicity and versatility of Garlanding concept for the construction of new phenylpyridyl scaffolds, which can be considered as non-peptidic foldamer α-helix mimetics. 相似文献
53.
Isabeau?Birindelli Giulio?Galise Fabiana?LeoniEmail author Filomena?Pacella 《Calculus of Variations and Partial Differential Equations》2018,57(6):158
We study the asymptotic behavior of positive solutions of fully nonlinear elliptic equations in a ball, as the exponent of the power nonlinearity approaches a critical value. We show that solutions concentrate and blow up at the center of the ball, while a suitable associated energy remains invariant. 相似文献
54.
55.
R. J. N. Bettencourt da Silva M. Filomena G. F. C. Camões João Seabra e Barros 《Accreditation and quality assurance》1998,3(4):155-160
Every analytical result should be expressed with some indication of its quality. The uncertainty as defined by Eurachem ("parameter
associated with the result of a measurement that characterises the dispersion of the values that could reasonably be attributed
to the, . . ., quantity subjected to measurement") is a good tool to accomplish this goal in quantitative analysis. Eurachem
has produced a guide to the estimation of the uncertainty attached to an analytical result. Indeed, the estimation of the
total uncertainty by using uncertainty propagation laws is components-dependent. The estimation of some of those components
is based on subjective criteria. The identification of the uncertainty sources and of their importance, for the same method,
can vary from analyst to analyst. It is important to develop tools which will support each choice and approximation. In this
work, the comparison of an estimated uncertainty with an experimentally assessed one, through a variance test, is performed.
This approach is applied to the determination by atomic absorption of manganese in digested samples of lettuce leaves. The
total uncertainty estimation is calculated assuming 100% digestion efficiency with negligible uncertainty. This assumption
was tested.
Received: 3 November 1997 · Accepted: 2 January 1998 相似文献
56.
Giuseppina Castronuovo Vittorio Elia Filomena Velleca 《Journal of solution chemistry》1996,25(10):971-982
Calorimetric measurements were carried out at 25°C on binary aqueous solutions containing N-acetyl derivatives of the following -amino acids: glycine, alanine, valine, leucine, norleucine, aspartic acid, glutamic acid, phenylalanine, methionine, asparagine, glutamine, cysteine, histidine, serine. The N-acetyl derivative of the -amino acid proline was also studied. The results obtained have been used to calculate the pairwise enthalpic interaction coefficients and these are compared with results reported in the literature concerning free -amino acids, and their acetylamide derivatives. The coefficients largely increase passing from free amino acids to N-acetyl derivatives. The derivatives of -amino acids bearing unsubstituted alkyl chains present an increased cooperativity of hydrophobic interactions. 相似文献
57.
M. J. Guiomar H. M. Lito M. Filomena G. F. C. Camões Arthur K. Covington 《Journal of solution chemistry》1998,27(10):925-933
A new computer program has been developed for the calculation of pH, pOH, hydroxide ion concentration m
OH, species distribution coefficients i, ionic activity coefficients i ionic strength I, buffer capacity , solubility product K
s0, and the two dissociation constants, K
b1 and K
b2, corresponding, respectively, to first and second dissociation steps of Ca(OH)2 in aqueous solution. Previously developed methodology, for the calculation of pH, i, i
I, and parameters of pH buffer solutions, starting from the corresponding acidity constants, has been adapted for the case of aqueous Ca(OH)2 solutions, for which the pertinent stoichiometric relationships are different from those applicable to mixtures of acids and their salts. The results show that, contrary to what is currently assumed, the first dissociation is far from complete. Values are given for the concentrations and activities of species Ca(OH)2(aq), Ca(OH)+(aq), and Ca2+ (aq) in saturated calcium hydroxide solutions at 25°C. 相似文献
58.
Using the filament model developed in the previous paper, the elastostatic interaction problem between a penny-shaped crack and a slender inclusion or filament in an elastic matrix is formulated. For a single filament as well as multiple identical filaments located symmetrically around the crack the problem is shown to reduce to a singular integral equation. The solution of the problem is obtained for various geometries and filament to-matrix stiffness ratios, and the results relating to the angular variation of the stress intensity factor and the maximum filament stress are presented. 相似文献
59.
Flavia Barone Adalberto Bonincontro Filomena Mazzei Anna Minoprio Francesco Pedone 《Photochemistry and photobiology》1995,61(1):61-67
Abstract— It is well known that the pyrimidine dimers are the main damage produced by UV radiation on the DNA structure. However, while studies on the photoproduct structure have been carried out extensively, uncertainties still exist on the implication that a single damaging event has on the overall conformation. In particular, the extension of the damage influence on the polynucleotide chain is a matter of debate. This problem is especially important to understanding some steps of the repair mechanisms. In this study we performed a chemical-physical characterization of 21 base pair oligonucleotides containing a single thymine dimer in one strand. Thermodynamic parameters were determined by means of thermal denaturation experiments, and static fluorescence measurements were performed to unequivocally define the primary structure-conformation relationship in this specific case. We used hydroxyl radicals, produced by means of γ-irradiation of the sample solution, to detect fine structure changes. Our data show that the introduction of a single thymine dimer might cause only a slight distortion of the helix geometry, as judged by the evaluation of the enthalpic and the entropic terms and by the small changes observed in the binding of ethidium bromide to DNA. The modifications in the sugar phosphate backbone subsequent to the damaging event are especially evident, near the thymine dimer, toward the 5'-end direction in the strand containing the dimer. 相似文献
60.
Potentiometric cells from which the pH values of standard buffer solutions are computed rely on the silver–silver chloride
reference electrode which has proved to be convenient, reproducible and reliable.
Of the various methods of preparation of silver-silver chloride electrodes only one concerns us here: the thermal–electrolytic
type that has been used more extensively than any other form. Once prepared, the electrodes need to be equilibrated before
use and between experiments. The equilibration technique must ensure voltage stability and inter-electrode, or bias, potential
below 0.1 mV. In potentiometry the stability of a reference electrode is of utmost importance since an offset of 1 mV is equivalent
to a deviation of about 0.02 in the pH value. 相似文献