全文获取类型
收费全文 | 728篇 |
免费 | 17篇 |
国内免费 | 4篇 |
专业分类
化学 | 442篇 |
晶体学 | 3篇 |
力学 | 27篇 |
数学 | 161篇 |
物理学 | 116篇 |
出版年
2023年 | 6篇 |
2022年 | 17篇 |
2021年 | 26篇 |
2020年 | 21篇 |
2019年 | 15篇 |
2018年 | 13篇 |
2017年 | 14篇 |
2016年 | 30篇 |
2015年 | 23篇 |
2014年 | 26篇 |
2013年 | 43篇 |
2012年 | 51篇 |
2011年 | 50篇 |
2010年 | 36篇 |
2009年 | 23篇 |
2008年 | 42篇 |
2007年 | 44篇 |
2006年 | 37篇 |
2005年 | 39篇 |
2004年 | 28篇 |
2003年 | 19篇 |
2002年 | 19篇 |
2001年 | 10篇 |
1999年 | 9篇 |
1998年 | 4篇 |
1997年 | 2篇 |
1996年 | 10篇 |
1995年 | 6篇 |
1994年 | 7篇 |
1993年 | 5篇 |
1992年 | 5篇 |
1991年 | 2篇 |
1989年 | 2篇 |
1988年 | 2篇 |
1985年 | 6篇 |
1984年 | 6篇 |
1982年 | 2篇 |
1981年 | 3篇 |
1979年 | 4篇 |
1978年 | 4篇 |
1976年 | 3篇 |
1975年 | 2篇 |
1973年 | 2篇 |
1921年 | 2篇 |
1919年 | 2篇 |
1915年 | 4篇 |
1909年 | 2篇 |
1901年 | 2篇 |
1875年 | 1篇 |
1868年 | 2篇 |
排序方式: 共有749条查询结果,搜索用时 15 毫秒
711.
Ernest?IliscaEmail author Filippo?Ghiglieno 《The European Physical Journal B - Condensed Matter and Complex Systems》2014,87(10):235
Models are provided and discussed to interpret new experiments on the ortho-paraconversion of hydrogen “physisorbed” on dielectric and diamagnetic surfaces.Electro-static and dynamical molecule-surface interactions complemented by hyperfinecontacts are shown to be generally more effective than the magnetic ones. Coulombrepulsion induces exchanges of molecular and surface electrons and excites triplet spinstates which are effective in the angular momenta transfers to the catalyst. Theconversion time is obtained as the square of a ratio of two energies: the exchange andexcitation ones. The main channel is found composed of triplet excitations of the order ofthe eV, induced by molecule-surface exchanges of about a hundred of meV. It explains thezinc and oxygen rates of about one minute observed on the MOF samples as well as the aboutten times slower ones on the ASW. The same mechanism is also shown to occur in thetransient regime, but faster. Finally it explains also the conversion of a few hoursobserved for interstitial hydrogen in silicium by transitions to the conduction bandinduced by about 10 meVelectron exchanges. The molecule-surface orbital geometries of the MOF and ASWconfigurations are displayed and the quantum path when unfolded exhibits the successivebroken symmetries. 相似文献
712.
Combining Topological and Steric Constraints for the Preparation of Heteroleptic Copper(I) Complexes
下载免费PDF全文
![点击此处可从《Chemistry (Weinheim an der Bergstrasse, Germany)》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Dr. Meera Mohankumar Dr. Filippo Monti Dr. Michel Holler Dr. Frédéric Niess Dr. Béatrice Delavaux‐Nicot Dr. Nicola Armaroli Dr. Jean‐Pierre Sauvage Dr. Jean‐François Nierengarten 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(38):12083-12090
Heteroleptic copper(I) complexes have been prepared from a macrocyclic ligand incorporating a 2,9‐diphenyl‐1,10‐phenanthroline subunit ( M30 ) and two bis‐phosphines, namely bis[(2‐diphenylphosphino)phenyl] ether (POP) and 1,3‐bis(diphenylphosphino)propane (dppp). In both cases, the diphenylphosphino moieties of the PP ligand are too bulky to pass through the 30‐membered ring of M30 during the coordination process, hence the formation of C2v‐symmetrical pseudo‐rotaxanes is prevented. When POP is used, X‐ray crystal structure analysis shows the formation of a highly distorted [Cu( M30 )(POP)]+ complex in which the POP ligand is only partially threaded through the M30 unit. This compound is poorly stable as the CuI cation is not in a favorable coordination environment due to steric constraints. By contrast, in the case of dppp, the bis‐phosphine ligand undergoes both steric and topological constraints and adopts a nonchelating coordination mode to generate [Cu2( M30 )2(μ‐dppp)](BF4)2. This compound exhibits metal‐to‐ligand charge transfer (MLCT) emission characterized by a very large Stokes’ shift (≈200 nm) that is not attributed to a dramatic structural distortion between the ground and the emitting states but to very weak MLCT absorption transitions at longer wavelengths. Accordingly, [Cu2( M30 )2(μ‐dppp)](BF4)2 shows unusually high luminescence quantum yields for CuI complexes, both in solution and in the solid state (0.5 and 7 %, respectively). 相似文献
713.
Hagberg DP Yum JH Lee H De Angelis F Marinado T Karlsson KM Humphry-Baker R Sun L Hagfeldt A Grätzel M Nazeeruddin MK 《Journal of the American Chemical Society》2008,130(19):6259-6266
Novel unsymmetrical organic sensitizers comprising donor, electron-conducting, and anchoring groups were engineered at a molecular level and synthesized for sensitization of mesoscopic titanium dioxide injection solar cells. The unsymmetrical organic sensitizers 3-(5-(4-(diphenylamino)styryl)thiophen-2-yl)-2-cyanoacrylic acid (D5), 3-(5-bis(4-(diphenylamino)styryl)thiophen-2-yl)-2-cyanoacrylic acid (D7), 5-(4-(bis(4-methoxyphenylamino)styryl)thiophen-2-yl)-2-cyanoacrylic acid (D9), and 3-(5-bis(4,4'-dimethoxydiphenylamino)styryl)thiophen-2-yl)-2-cyanoacrylic acid (D11) anchored onto TiO2 and were tested in dye-sensitized solar cell with a volatile electrolyte. The monochromatic incident photon-to-current conversion efficiency of these sensitizers is above 80%, and D11-sensitized solar cells yield a short-circuit photocurrent density of 13.90 +/- 0.2 mA/cm(2), an open-circuit voltage of 740 +/- 10 mV, and a fill factor of 0.70 +/- 0.02, corresponding to an overall conversion efficiency of 7.20% under standard AM 1.5 sun light. Detailed investigations of these sensitizers reveal that the long electron lifetime is responsible for differences in observed open-circuit potential of the cell. As an alternative to liquid electrolyte cells, a solid-state organic hole transporter is used in combination with the D9 sensitizer, which exhibited an efficiency of 3.25%. Density functional theory/time-dependent density functional theory calculations have been employed to gain insight into the electronic structure and excited states of the investigated species. 相似文献
714.
Thomas G. F. Marsh Alessia Santambrogio Dr. Ben J. Murray Dr. Lee T. Boulton Dr. Juan A. Aguilar Dr. Dmitry S. Yufit Prof. Graham Sandford Dr. William D. G. Brittain 《European journal of organic chemistry》2023,26(11):e202300058
Trifluoromethyl ynones derived from the refrigerant gas HFO-1234yf (2,3,3,3-tetrafluoropropene) react with nucleophiles via a Michael-type addition process and the allenolate intermediate formed reacts intramolecularly with a carbonyl group to form heterocyclic derivatives. Thus, reaction of 2-amino and 2-hydroxyl benzaldehyde or ketone substrates with trifluoromethyl ynone derivatives gives trifluoromethyl quinoline and chromene products by a one-pot tandem ring closing sequence, forming pharmaceutically relevant structures from an inexpensive starting material without the need for transition metals or column chromatography. The 2-trifluoromethylquinoline products also show unusual fluxional behaviour, which was explored through 2-D NMR and X-ray crystallographic studies. 相似文献
715.
We consider an abstract system of Timoshenko typewhere the operator \({A}\) is strictly positive selfadjoint. For any fixed \({\gamma \in {\mathbb{R}}}\), the stability properties of the related solution semigroup \({S(t)}\) are discussed. In particular, a general technique is introduced in order to prove the lack of exponential decay of \({S(t)}\) when the spectrum of the leading operator \({A}\) does not consist of eigenvalues only.
相似文献
$$\begin{aligned} \left\{ {\begin{array}{l} \rho_1{{\ddot \varphi}} + a A^{\frac12}(A^{\frac12}\varphi + \psi) =0\\\rho_2{{\ddot \psi}} + b A \psi + a (A^{\frac12}\varphi + \psi) -\delta A^\gamma {\theta} = 0\\\rho_3{{\dot \theta}} + c A\theta + \delta A^\gamma {{\dot \psi}} =0 \end{array}} \right. \end{aligned}$$
716.
The coproporphyrin-I (CPI) behaves as a reducing agent for silver and gold metal ions and as stabilizing agent for the formed colloidal metallic nanoparticles. The peculiarity of silver and gold nanoparticles obtained in the reactions of monomeric form of CPI with their metal ions has been studied. The optical properties of the colloidal forms of these metals have been investigated by UV–Vis spectrophotometry, and their morphology by TEM and SEM measurements. The structures and the size distributions of Ag and Au particles have been characterized and determined by computerized TEM images. 相似文献
717.
Abbotto A Barolo C Bellotto L De Angelis F Grätzel M Manfredi N Marinzi C Fantacci S Yum JH Nazeeruddin MK 《Chemical communications (Cambridge, England)》2008,(42):5318-5320
A novel heteroleptic ruthenium complex carrying a heteroaromatic-4,4'-pi-conjugated 2,2'-bipyridine [Ru(II)LL'(NCS)(2)] (L = 4,4'-bis[(E)-2-(3,4-ethylenedioxythien-2-yl)vinyl]-2,2'-bipyridine, L' = 4,4'-(dicarboxylic acid)-2,2'-bipyridine) was synthesized and used in dye-sensitized solar cells, yielding photovoltaic efficiencies of 9.1% under standard global AM 1.5 sunlight. 相似文献
718.
Donati F Pucci A Cappelli C Mennucci B Ruggeri G 《The journal of physical chemistry. B》2008,112(12):3668-3679
In this work, two perylene derivatives containing different peripheral alkyl chains (i.e., N,N'-bis-(hexyl)perylene-3,4,9,10-tetracarboxyldiimide (ES-PTCDI) and N,N'-bis-(2'-ethylhexyl)perylene-3,4,9,10-tetracarboxyldiimide (EE-PTCDI)) were synthesized and efficiently dispersed at low loadings (from 0.01 to 0.1 wt %) into linear low-density polyethylene (LLDPE) by processing in the melt. Spectroscopic investigations (UV-vis and fluorescence) combined with quantum-mechanical studies demonstrated the ability of both chromophores to generate aggregates among the planar structure of dyes when dissolved in solution or dispersed into LLDPE above a certain concentration. The data acquired for dyes' dispersions into the polymer matrix reveal that the optical properties and responsiveness to mechanical stimuli are strongly dependent on the compactness of perylene aggregates provided by the different molecular structure of dyes. In particular, the strong intermolecular aggregates of ES-PTCDI resulted in being more resistant toward mechanical stress and less orientable by uniaxial drawing along the drawing direction of the film, whereas the less compact and distorted supramolecular architecture of EE-PTCDI chromophores provided composite films with a remarkable optical response to mechanical solicitations. 相似文献
719.
De Angelis F Santoro F Nazeruddin MK Barone V 《The journal of physical chemistry. B》2008,112(42):13181-13183
We performed fully first principles quantum mechanical calculations of the ground and excited state geometries and harmonic vibrational frequencies of two prototype cationic Ir(III) complexes showing high emission quantum efficiencies. Thanks to recent theoretical advances, we have been able for the first time to simulate their vibrationally resolved emission spectra. Our results, in good agreement with the experiment, allow us to calculate the CIE coordinates and therefore the emission color of this important class of emitters for OLEDs and LECs. 相似文献
720.
Morini F Hajgató B Deleuze MS Ning CG Deng JK 《The journal of physical chemistry. A》2008,112(38):9083-9096
An extensive study, throughout the valence region, of the electronic structure, ionization spectrum, and electron momentum distributions of ethanol is presented, on the ground of a model that focuses on a mixture of the gauche and anti conformers in their energy minimum form, using weight coefficients obtained from thermostatistical calculations that account for the influence of hindered rotations. The analysis is based on accurate calculations of valence one-electron and shakeup ionization energies and of the related Dyson orbitals, using one-particle Green's Function (1p-GF) theory in conjunction with the so-called third-order Algebraic Diagrammatic Construction scheme [ADC(3)]. The confrontation against available UPS (HeI) measurements indicates the presence in the spectral bands of significant conformational fingerprints at outer-valence ionization energies ranging from approximately 14 to approximately 18 eV. The shakeup onset is located at approximately 24 eV, and a shoulder at approximately 14.5 eV in the He I spectrum can be specifically ascribed to the minor anti (C(s)) conformer fraction. Thermally and spherically averaged Dyson orbital momentum distributions are computed for seven resolvable bands in model (e, 2e) ionization spectra at an electron impact energy of 1.2 keV. A comparison is made with results obtained from standard (B3LYP) Kohn-Sham orbitals and EMS measurements employing a high-resolution spectrometer of the third generation. The analysis is qualitatively in line with experiment and reveals a tremendously strong influence of the molecular conformation on the outermost electron momentum distributions. Quantitatively significant discrepancies with experiment can nonetheless be tentatively ascribed to strong dynamical disorder in the gas phase molecular structure. 相似文献