全文获取类型
收费全文 | 272篇 |
免费 | 3篇 |
国内免费 | 2篇 |
专业分类
化学 | 186篇 |
晶体学 | 6篇 |
力学 | 6篇 |
数学 | 39篇 |
物理学 | 40篇 |
出版年
2022年 | 8篇 |
2021年 | 8篇 |
2020年 | 11篇 |
2019年 | 12篇 |
2018年 | 4篇 |
2017年 | 4篇 |
2016年 | 7篇 |
2015年 | 12篇 |
2014年 | 14篇 |
2013年 | 29篇 |
2012年 | 16篇 |
2011年 | 20篇 |
2010年 | 25篇 |
2009年 | 16篇 |
2008年 | 21篇 |
2007年 | 15篇 |
2006年 | 10篇 |
2005年 | 10篇 |
2004年 | 6篇 |
2003年 | 7篇 |
2002年 | 3篇 |
2001年 | 1篇 |
2000年 | 4篇 |
1999年 | 2篇 |
1996年 | 1篇 |
1995年 | 2篇 |
1993年 | 1篇 |
1990年 | 1篇 |
1984年 | 1篇 |
1983年 | 1篇 |
1980年 | 1篇 |
1979年 | 2篇 |
1976年 | 2篇 |
排序方式: 共有277条查询结果,搜索用时 171 毫秒
51.
Güleç Özcan Türkeş Cüneyt Arslan Mustafa Demir Yeliz Yeni Yeşim Hacımüftüoğlu Ahmet Ereminsoy Ergün Küfrevioğlu Ömer İrfan Beydemir Şükrü 《Molecular diversity》2022,26(5):2825-2845
Molecular Diversity - The acetylcholinesterase and carbonic anhydrase inhibitors (AChEIs and hCAIs) remain key therapeutic agents for many bioactivities such as anti-Alzheimer and antiobesity... 相似文献
52.
In this study, steady-state forced convection heat transfer and pressure drop characteristics in a horizontal rectangular cross-sectioned duct, baffles mounted on the bottom surface with different inclination angles were investigated experimentally in the Reynolds number range from 1 × 103 to 1 × 104. The study was performed under turbulent flow conditions. Effects of different baffle inclination angles on flow and heat transfer were studied. Results are also presented in terms of thermal enhancement factor. It is observed that increasing in baffle inclination angle enhances the heat transfer and causes an increase in pressure drop in the duct. 相似文献
53.
S. V. Stetsyura S. A. Klimova S. B. Wenig I. V. Malyar M. Arslan I. Dincer Y. Elerman 《Applied Physics A: Materials Science & Processing》2012,109(3):571-578
We aim to reveal the influence of?pH values of the working solution on spatial arrangement of metal-containing inclusions in the monolayer coatings prepared by Langmuir?CBlodgett (LB) technology and transferred to solid substrates with consequent modification of surface electrical properties. Consequently, films with inclusions in the form of dendrites and cluster shapes have been obtained. Submicron and micron lead-containing formations in Langmuir?CBlodgett films have been characterized by using the atomic force microscopy, Kelvin probe microscopy, and scanning electron microscopy methods. The results show that increasing?pH value of the subphase has caused the significant changes in the shape and composition of the inclusions in Langmuir?CBlodgett films. The synthesized inclusions on the solid substrate surface resulted in formation of the regions with the local electric fields and, as consequence, to significant modification of the structure and electrical properties. The location and length of the regions with surface potential disturbance depend on the shape of inclusions, and consequently, on?pH value of the subphase used in LB technology. 相似文献
54.
The Sn substituted Bi1.75Pb0.25Sr2Ca2Cu3-xSnxOδ glass ceramic (where x = 0, 0.1, 0.3, and 0.5) samples were prepared by the melt-quenching method. Crystallization kinetic studies of the samples were conducted using the differential thermal analysis (DTA). The oxidation behavior of the samples was also analyzed using the thermogravimetry analysis (TG). The DTA curves were registered with different heating rates (5, 10, 15, and 20 Kmin? 1) up to 1200 ± 0.5 K. The crystallization results were analyzed, and activation energy of crystallization process as well as the crystallization mechanisms and the effect of Sn substitution on powder glass ceramic were characterized. The glass transition temperature (Tg), the first crystallization peak temperature (Tx1) and the second crystallization peak temperature (Tx2) values were obtained as 713.0 ± 0.5–746.6 ± 0.5, 731.0 ± 0.5–760.8 ± 0.5 and 789.0 ± 0.5–820.1 ± 0.5 K, respectively. The activation energy (Ea) of crystallization was estimated from DTA results to be about 332.8 ± 0.1, 358.0 ± 0.1, 353.1 ± 0.1 and 348.9 ± 0.1 kJ/mol for x = 0, 0.1, 0.3 and 0.5, respectively, by using the Kissinger method. The Avrami parameter (n) values calculated at different Sn ratio from DTA results were found to be between 1.70 ± 0.01 and 2.57 ± 0.01, results reflect the growth of small particle with a decreasing nucleation rate. 相似文献
55.
Analytical solution of an elastic-partially plastic two-layer curved bar subjected to couples at both ends is obtained. The solution is based on Tresca's yield criterion and its associated flow rule. Numerical results for real engineering materials in partially plastic stress state are presented in graphical form. (© 2012 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
56.
Based on Tresca's yield criterion and the flow rule associated with it, the behaviour of a linearly strain-hardening elastic-plastic hollow shaft subject to a positive radial temperature gradient and monotonously increasing angular speed is studied. (© 2008 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
57.
This paper presents a chemometrics-assisted optimization study to improve the separation of tocopherol (-T) and tocotrienol (-TT) homologues on a C30 stationary phase in reversed-phase HPLC. The HPLC settings were optimized using a central composite design and the response surface methodology. Flow rate, column temperature, and mobile phase composition were chosen as independent variables. Peak resolution (Rs), analysis time (tR), and peak symmetries of the tocopherol isomers were chosen as response variables. Optimum performance in terms of Rs was obtained at a flow rate of 0.31 mL min?1, a temperature of 8.70 °C, and % B content (methyl tert-butyl ether: methanol: water, 80:18:2, v/v/v) in the mobile phase of 38.12%. The analysis of variance and regression analysis gave adjusted R2 values of 0.9841 for Rs, 0.9850 for tR-(α-T), 0.9853 for tR-(β-T), and 0.9204 for the peak symmetry of β-T. This confirms the good agreement of experimental data with predicted values. The close eluting peaks of β-/γ-tocol could be baseline separated at the optimized conditions at a minimized analysis time. Empirical second-order polynomial models were derived that gave statistically high significances (P?<?0.0001). Hence, the models can be successfully employed to predict the optimum separation conditions of co-eluting peaks of β-/γ-tocols. The optimized method was successfully applied to determine the individual tocol homologues in various cold pressed edible oils. Total contents ranged from 15 to almost 2600 mg tocol kg?1 oil. 相似文献
58.
59.
Structural Chemistry - A cluster of 10 vanadium (5+) atoms bridged by 22 oxygen atoms and having six of the vanadiums around the periphery each bound to a single bidentate acetylacetone is... 相似文献
60.
Şenol Zeynep Mine Şenol Arslan Dilek Şimşek Selçuk 《Journal of Radioanalytical and Nuclear Chemistry》2019,319(3):791-803
Journal of Radioanalytical and Nuclear Chemistry - The thiol-functional hydrotalcite (Mg/Al-LDO-SH) composite materials were prepared and characterized by EDS, SEM, FT-IR and XRD. The variables... 相似文献