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1.
Biodistribution study of free and microencapsulated 6‐methylcoumarin in Wistar rats by HPLC 下载免费PDF全文
Aura Rocío Hernández Luis Fernando Ospina Diana Marcela Aragón 《Biomedical chromatography : BMC》2015,29(2):176-181
A sensitive, specific and reproducible HPLC method has been developed and validated for the quantitative determination of 6‐methylcoumarin (6MC) in plasma and other tissues in Wistar rats. A C18 column was used with UV detection at 321 nm and a gradient system consisting of methanol‐deionized water was used as mobile phase. The retention time for 6MC was 14.921 min and no interfering peaks were observed for any of the matrices. Linear relationships (r2 > 0.997) were obtained between the peak height ratios and the corresponding biological sample concentrations over the range 0.4–12.8 µg/mL. Precision and accuracy were evaluated; the coefficient of variation and the relative error for all of the organs were <2 and 7%, respectively. The limit of quantitation was 0.20 µg/mL for the heart and 0.30 µg/mL for the other tissues evaluated. This HPLC method was successfully used in the determination of 6MC in the biodistribution study after administration of 200 mg/kg of both 6MC‐free and 6MC‐loaded polymeric microparticles. In this study, extensive 6MC was found, in both free and microencapsulated forms, in all the organs tested. The 6MC‐free showed a range of between 1.7 and 11.5 µg/g, while the microencapsulated 6MC showed concentrations of between 6.35 and 17.7 µg/g, suggesting that 6MC improved absorption rate. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
2.
The main object of this note is to prove the following generalisation of a theorem of Serre. A simply connected space of finite
type whose mod. 2 cohomology is nilpotent (and non-trivial) has infinitely many homotopy groups which are not of odd torsion.
Incidentally we show that for every fibrationF(
→
ί
)E (
→
p
)B, satisfying certain mild conditions, the following holds. If a classx in the mod. 2 cohomology ofE belongs to the kernel ofi*, then some power ofx belongs to the ideal generated by the image underp* of the mod. 2 reduced cohomology ofB.
相似文献
3.
We give a small functorial algebraic model for the 2-stage Postnikov section of the K-theory spectrum of a Waldhausen category and use our presentation to describe the multiplicative structure with respect to biexact functors. 相似文献
4.
5.
Fernando M. Lanas Janete H. Y. Vilegas Srgio Martins Elaine A. F. Gobato 《Journal of separation science》1994,17(4):237-244
An overview is presented of the analytical approaches developed by our research group over the last ten years for analysis of alternative fuel, both biomass and fossil. The alternative fuels are analyzed successively by PLC-8 (preparative liquid chromatography–group-type) fractionation and high resolution gas chromatography. Some of the possibilities for fractionation and characterization of alternative fuels are herein exemplified with sugar cane bagasse pyrolysis products. 相似文献
6.
Angla Schwartz Lszl Szab Katalin Pusztay-Szab Istvn Hermecz Zoltn Mszros 《Journal of heterocyclic chemistry》1987,24(3):655-660
Ultraviolet-visible spectra of 4-oxo 1 and 4-imino 2 quinolizines or their monocyclic tautomers 3, 4 have been studied in neutral, acidic and basic ethanolic solution as well as in dimethyl sulfoxide and chloroform. Ring B of 4-oxo and 6-unsubstituted 4-imino compounds can be cleaved by sodium ethanolate more or less easily. Ring B of 6-methyl-4-iminoquinolizines is very unstable and they are present mainly in the monocyclic form which are partly dissociated in ethanol and dimethyl sulfoxide especially in higher dilution or in the presence of sodium ethanolate. In dilute acidic ethanol or chloroform, the dissociation is suppressed and in the latter solvent and in some cases, absorption bands can be observed due to a small amount of the 4-imino-6-methylquinolizines. In acidic solution of compounds 3B=C, 3D, 4E, 4F=G having simultaneously cyano and ethoxycarbonyl groups in 1 and 3 position, not simple reprotonation occurs but irreversible changes can be observed. 相似文献
7.
M. Trinidad Menarguez Fernando Soria 《Rendiconti del Circolo Matematico di Palermo》1992,41(3):342-352
In this paper we study the behavior of the constants which appear in the weak type (1, 1) inequalities for maximal convolution
operators by means of discrete methods.
One of the first applications of these techniques will give us a very simple proof of the ergodic theorem. We also present
partial results in order to investigate the best constant in the weak type (1, 1) inequality for the Hardy-Littlewood centered
maximal operator in dimension one. In dimension bigger than one we also obtain some lower bounds for that constant. 相似文献
8.
9.
Eleonora Catsigeras Jean-Marc Gambaudo Fernando Moreira 《Proceedings of the American Mathematical Society》1998,126(1):297-304
We show that, among area contracting embeddings of the 2-disk, infinitely renormalizable maps with a bounded geometry either have positive topological entropy or correspond to a cascade of period doubling.
10.
In this paper we address a two-dimensional (2D) orthogonal packing problem, where a fixed set of small rectangles has to be placed on a larger stock rectangle in such a way that the amount of trim loss is minimized. The algorithm we propose hybridizes a placement procedure with a genetic algorithm based on random keys. The approach is tested on a set of instances taken from the literature and compared with other approaches. The computation results validate the quality of the solutions and the effectiveness of the proposed algorithm. 相似文献