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41.
Isolda C. Mendes Fernanda B. Costa Geraldo M. de Lima José D. Ardisson Isabel Garcia-Santos Alfonso Castiñeiras Heloisa Beraldo 《Polyhedron》2009,28(6):1179-1185
Reaction of tin tetrachloride with 2-pyridineformamide thiosemicarbazone (H2Am4DH) and its N(4)-methyl (H2Am4Me), N(4)-ethyl (H2Am4Et) and N(4)-phenyl (H2Am4Ph) derivatives gave [Sn(2Am4DH)Cl3] (1), [Sn(2Am4Me)Cl3] (2), [Sn(2Am4Et)Cl3] (3) and [Sn(2Am4Ph)Cl3] (4) as products, in which an anionic thiosemicarbazone coordinates to the metal centre along with three chloride ions. The crystal structures of 1 and 2 were determined. The thiosemicarbazones were moderately active against Candida albicans and Pseudomonas aeruginosa. Upon coordination to tin(IV) the antimicrobial activity of the thiosemicarbazones increases. The studied compounds proved to be toxic to Artemia salina, suggesting that they could present cytotoxic activity against solid tumors. 相似文献
42.
2-Iodoxybenzoic acid (IBX), a mild and efficient hypervalent iodine oxidant, has been utilised in different reaction conditions to perform several efficient oxidative modifications of flavonoids. Fine-tuning of the reaction conditions allowed remarkably selective modifications of these compounds. At room temperature, IBX proved to be an excellent reagent for a highly regioselective aromatic hydroxylation of monohydroxylated flavanones and flavones, generating the corresponding catecholic derivatives showing high antioxidant activity. At 90 °C, IBX efficiently dehydrogenated a large panel of methoxylated flavanones to their corresponding flavones exhibiting anticancer activity. IBX polystyrene has also been utilised to increase the recovery of highly polar compounds. Following the first oxidation, the reagent was recovered and reused in several runs without loss of efficiency and selectivity. The first example of an application of IBX polystyrene in a dehydrogenation reaction has been described. 相似文献
43.
Daniele Bartoli Stefano Marcugini Fernanda Pambianco 《Designs, Codes and Cryptography》2014,72(1):129-134
The non-existence of $[29+h,3+h,26]_{16}$ and $[29+h,4+h,25]_{16}$ -codes, $h\ge 0$ , is proven. These results are obtained using geometrical methods, exploiting the equivalence between NMDS codes of dimension $3$ and $(n,3)$ -arcs in $PG(2,q)$ . Along the way the packing problem for complete $(n,3)$ -arcs in $PG(2,16)$ is solved, proving that $m_{3}(2,16)=28$ and $t_{3}(2,16)=15$ and that the complete $(28,3)$ -arc and the complete $(15,3)$ -arc are unique up to collineations. 相似文献
44.
In this paper, we present a new hybrid algorithm for convex Mixed Integer Nonlinear Programming (MINLP). The proposed hybrid algorithm is an improved version of the classical nonlinear branch-and-bound (BB) procedure, where the enhancements are obtained with the application of the outer approximation algorithm on some nodes of the enumeration tree. The two methods are combined in such a way that each one collaborates to the convergence of the other. Computational experiments with benchmark instances of the MINLP problem show the good performance of the proposed algorithm, which is compared to the outer approximation algorithm, the nonlinear BB algorithm and the hybrid algorithm implemented in the solver Bonmin. 相似文献
45.
Received June 4, 1996 / Revised version received November 19, 1997
Published online November 24, 1998 相似文献
46.
Maria Fernanda Elbert 《Proceedings of the American Mathematical Society》2000,128(5):1443-1450
We generalize Efimov's Theorem for graphs in Euclidean space using the scalar curvature, with an additional hypothesis on the second fundamental form. 相似文献
47.
A rigorous wave-theoretic approach to the Michelson-Morley (M-M) experiment is presented, with special emphasis on the Huygens' principle derivation of the laws of reflection by a moving mirror. A detailed discussion of the Lorentz-Fitzgerald contraction hypothesis (CH) is included. Several mistakes appearing in the standard textbook treatments of these issues are pointed out, and a number of related historical questions are considered. 相似文献
48.
Bruno Fernandes Ana C. Correia Fernanda Cosme Fernando M. Nunes 《Natural product research》2015,29(1):37-45
The purpose of this work was to study the volatile composition of vine leaves and vine leaf infusion prepared from vine leaves collected at 30 and 60 days after grape harvest of two Vitis vinifera L. species. Eighteen volatile compounds were identified by gas chromatography–mass spectrometry in vine leaves and in vine leaf infusions. It was observed that the volatile compounds present in vine leaves are dependent on the time of harvest, with benzaldehyde being the major volatile present in vine leaves collected at 30 days after harvesting. There are significant differences in the volatile composition of the leaves from the two grape cultivars, especially in the sample collected at 60 days after grape harvest. This is not reflected in the volatile composition of the vine leaf infusion made from this two cultivars, the more important being the harvesting date for the volatile profile of vine leaf infusion than the vine leaves grape cultivar. 相似文献
49.
Effects of Ultraviolet Radiation (UVA+UVB) and Copper on the Morphology,Ultrastructural Organization and Physiological Responses of the Red Alga Pterocladiella capillacea
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Éder C. Schmidt Marianne Kreusch Marthiellen R. de L. Felix Debora T. Pereira Giulia B. Costa Carmen Simioni Luciane C. Ouriques Francine L. Farias‐Soares Neusa Steiner Fungyi Chow Fernanda Ramlov Marcelo Maraschin Zenilda L. Bouzon 《Photochemistry and photobiology》2015,91(2):359-370
The effect of ultraviolet (UV) radiation and copper (Cu) on apical segments of Pterocladiella capillacea was examined under two different conditions of radiation, PAR (control) and PAR+UVA+UVB (PAR+UVAB), and three copper concentrations, ranging from 0 (control) to 0.62, 1.25 and 2.50 μm . Algae were exposed in vitro to photosynthetically active radiation (PAR) at 70 μmol photons m?2 s?1, PAR + UVB at 0.35 W m?2 and PAR +UVA at 0.70 W m?2 during a 12‐h photocycle for 3 h each day for 7 days. The effects of radiation and copper on growth rates, content of photosynthetic pigments and photosynthetic performance were analyzed. In addition, samples were processed for light and transmission electron microscopy. The content of photosynthetic pigments decreased after exposure to radiation and Cu. Compared with PAR radiation and copper treatments modified the kinetics patterns of the photosynthesis/irradiance curve. The treatments also caused changes in the ultrastructure of cortical and subcortical cells, including increased cell wall thickness and accumulation of plastoglobuli, as well as changes in the organization of chloroplasts. The results indicate that the synergistic interaction between UV radiation and Cu in P. capillacea, led to the failure of protective mechanisms and causing more drastic changes and cellular imbalances. 相似文献
50.
Roberto Kawakami Harrop Galvão Sófacles Figueredo Carreiro Soares Marcelo Nascimento Martins Maria Fernanda Pimentel Mário César Ugulino Araújo 《Analytica chimica acta》2015
This paper proposes a new method for calibration transfer, which was specifically designed to work with isolated variables, rather than the full spectrum or spectral windows. For this purpose, a univariate procedure is initially employed to correct the spectral measurements of the secondary instrument, given a set of transfer samples. A robust regression technique is then used to obtain a model with low sensitivity with respect to the univariate correction residuals. The proposed method is employed in two case studies involving near infrared spectrometric determination of specific mass, research octane number and naphthenes in gasoline, and moisture and oil in corn. In both cases, better calibration transfer results were obtained in comparison with piecewise direct standardization (PDS). The proposed method should be of a particular value for use with application-targeted instruments that monitor only a small set of spectral variables. 相似文献