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11.
Rois Benassi Adriano Benedetti Ferdinando Taddei Roberto Cappelletti Dante Nardi Alberto Tajana 《Magnetic resonance in chemistry : MRC》1982,20(1):26-30
Aryl- and 2-furylaldehyde ethylaminoacetylhydrazones were examined in different solvents and over a wide temperature range with 1H NMR in order to study their conformational properties. Nearly equal amounts of the E/Z isomers, relative to the C?N bond, are present, even when the solvents and the substituents on the aldimino carbon produce small changes in the isomeric mixture. The activation parameters of the thermal isomerization process were measured, and the results are in the line with a lateral-shift type mechanism, also supported by theoretical calculations on a model compound. No other internal process was noted from the low-temperature spectral behaviour, and this was interpreted in terms of a highly biased equilibrium concerning the rotation around the C(O)? N bond. Chemical shifts obtained in different solvents also enable the most stable arrangement of the whole molecule of these compounds to be postulated. 相似文献
12.
Fringuelli F Pizzo F Vittoriani C Vaccaro L 《Chemical communications (Cambridge, England)》2004,(23):2756-2757
Polystyryl supported-TBD (PSTBD) is an efficient and reusable heterogeneous basic catalyst under solvent-free conditions for a variety of organic transformations such as 1,2-epoxide ring-opening, aldol-type condensation and Michael addition. 相似文献
13.
The role of citric acid in the demineralization of dental enamel, which is mainly constituted by hydroxyapatite, is important for periodontal regeneration and in the conditioning of enamel or dentin for bonding restorative resins. The adsorption of citric acid from aqueous solutions onto synthetic hydroxyapatite at 278, 288, 298, and 308 K and pH 4.8 has been studied by means of UV spectroscopy. The adsorption reaction, which takes place by an interaction between phosphate groups and citrate anions at the solid-solution interface, yields an adsorbate-adsorbent complex of high stability. The adsorption isotherms fit the Langmuirian shape. The proposed adsorption model, where citrate species interact in a bidentate manner (one citrate ion links two phosphate sites), is coherent with the experimental data. The activation standard heat and activation standard entropy were calculated. All the thermodynamic and kinetic parameters were in concordance with the adsorption reaction proposed in this work. 相似文献
14.
Michele Conti Michele Marconi Giulia Campanile Alessandro Reali Daniele Adami Raffaella Berchiolli Ferdinando Auricchio 《Meccanica》2017,52(3):633-644
Nitinol self-expanding stents are used for the endovascular management of peripheral artery diseases of the popliteal artery, which is located behind the knee joint. Unfortunately, the complex kinematics of the artery during the leg flexion leads to severe loading conditions, favouring the mechanical failure of the stent, calling for a specific biomechanical analysis. For this reason, in the present study we reconstruct by medical image analysis the patient-specific popliteal kinematics during leg flexion, which is subsequently exploited to compute the mechanical response of a stent model, virtually implanted in the artery by structural finite element analysis (FEA). The medical image analysis indicates a non-uniform configuration change of the artery during the leg flexion, leading to an increase of the vessel curvature above the knee. The computed mechanical response of the stent reflects the non-uniform configuration change of the artery as after the flexion the average stress is higher in the part of the stent located above the knee. Although the proposed analysis is limited to a case-study, it shows the capability of patient-specific FEA simulations to compute the mechanical response of a stent model subjected to the complex and severe loading conditions of the popliteal artery during leg flexion. 相似文献
15.
Curcumin, a chemical compound present in the well-known Indian spice turmeric, has uses in many different fields ranging from
medicinal chemistry to the dye industry. Its poor water solubility, though, makes Curcumin difficult to handle, making it
less appealing for potential uses. The principal aim of this work is to perform a computational study of the structural and
electronic properties of Curcumin {IUPAC name: 1,7-bis(4-hydroxy-3-methoxyphenyl)-1,6-heptadiene-3,5-dione} in several solvents,
and a comparison with experimental data. Rotameric equilibria, vibrational and thermochemical analysis, and electronic absorption
spectra (with ab initio and semi-empirical methodologies) have been studied, both in vacuum and in three selected solvents. Different computational
techniques have been applied and the results compared. Combined approaches resulted in very satisfactory results. Interesting
results have emerged, which suggest subsequent investigations about the nature of the excited states and potential derivatives
of Curcumin that possibly have non-linear optical applications, as a π-core for innovative materials in laser engineering and photonics. 相似文献
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18.
Ferdinando Stassi-D'Alia 《Meccanica》1969,4(4):349-363
Summary The known Limiting Conditions of Yielding presuppose homogeneity andisotropy of the material. Formulas for anisotropic materials have been proposed: but they cannot be applied to all practical applications. The Limiting Condition of Yielding already proposed by the A. for isotropic materials can easily be extended to materials with different mechanical properties in different directions: the formulas obtained confirm the particular cases and the particular formulas already known for isotropic materials. The various solutions proposed by the A. for anisotropic bodies are usually represented by paraboloids whose characteristics obviously depend on the experimental parameters.
相似文献
Sommario Le condizioni di plastificazione che si conoscono presuppongono omogeneità eisotropia del materiale. Per corpi anisotropi sono state proposte espressioni che non possono essere applicate in casi riguardanti le pratiche applicazioni. La condizione di plastificazione proposta dall'A. per i corpi isotropi può essere con opportune trasformazioni adattata a materiali presentanti differenti proprietà meccaniche nelle tre direzioni principali: le formule che se ne ottengono confermano i casi particolari e le formule già note per i corpi isotropi. Le soluzioni proposte dall'A. per i corpi anisotropi sono rappresentate in genere da paraboloidi le cui caratteristiche dipendono ovviamente dai parametri sperimentali.
相似文献
19.
Giorgio Barbieri Rois Benassi Romano Grandi Ugo Maria Pagnoni Ferdinando Taddei 《Magnetic resonance in chemistry : MRC》1979,12(3):159-162
The relative reactivity toward protonation and methylation of the two nitrogen atoms in N,N-dimethylaminopyridines has been examined by 1H NMR. The ring position of the dimethylamino group has no influence on protonation, which occurs in all the derivatives at the heterocyclic nitrogen. The N-methylation reaction does not follow a homogeneous behaviour, occurring at the exocyclic nitrogen in the 2-substituted dimethylamino derivative. The electronic characteristics of the molecules, determined by MO calculations at a semi-empirical level, indicate that both protonation and methylation should occur at the heterocyclic nitrogen; the calculated relative stabilites, however, of the N-protonated and N-methylated forms are in full agreement with the experimental results, and it appears that the anomalous behaviour of 2-dimethylaminopyridine in the N-methylation reaction is caused by steric factors. 相似文献
20.
Ferdinando Pezzella Roberto Bonanno Bernardo Nicoletti 《European Journal of Operational Research》1981,8(2):139-146
The paper presents a methodology for partitioning a given region in geographical areas in such a way as to insure an optimal allocation of the available health services. Two steps compose the proposed approach. In the first step, via mathematical programming one determines optimal hospital districts by taking into account demand and capacity, measured in number of hospital-beds. In the second step, one determines health-districts by aggregating together hospital districts, by taking into account lower and upper bounds for the population in each district and the existence of districts with a different nature (political, educational, etc.). A case study is presented for the Italian province of Cosenza. Although developed within the context of health-care services, the approach is general enough to be applicable also to the partition in a given region of other social services, i.e. school districts. 相似文献