Preparation and characterization of pure polyacrylate polymer colloid through emulsion polymerization using a novel initiator

A series of acrylic polymer colloids were prepared via semi-continuous seeded emulsion polymerization of BA and MMA in water phase when OP-10 and AIBI is used to be emulsifier and initiator, respectively. FTIR spectrum identifies the formation of copolymers of P (MMA-co-BA). DSC confirms that the colloid is a kind of random copolymer and the consistency among the chain segment is fairly good. The emulsion polymerization conditions of preparing acrylic polymer colloid are optimized. Results show that the conversion rate is high and the coagulum is low and the particle size of the acrylic polymer colloids is small when the amount of AIBI is 0.75 g. The polymerization temperature is 70 °C, which is lower than the one that the emulsion polymerization is initiated with the persulfate.     

Global exponential stability of nonautonomous neural networks with time-varying delays and reaction-diffusion terms

A class of nonautonomous neural networks with time-varying delays and reaction-diffusion terms is considered. By means of Lyapunov functionals and differential inequality techniques, criteria on global exponential stability of this model with the Neumann boundary conditions and the Dirichlet boundary conditions are derived, respectively. The results of this paper are new and they improve and generalize previously known results.     

Global dynamical analysis of a heroin epidemic model on complex networks

In this paper, a heroin epidemic model on complex networks is proposed. By the next generation matrix, the basic reproduction number $R_0$ is obtained. If $R_0<1$, then the drug-free equilibrium is globally asymptotically stable. If $R_0>1$, there is an unique endemic equilibrium and it is also globally asymptotically stable. Our results show that if the degree of the network is large enough, the drug transmission always spreads. Sensitivity analysis of the basic reproduction number with the various parameters in the model are carried out to verify the important effects for control the drug transmission. Some simulations illustrate our theoretical results     

采用光纤拉曼放大改善1550 nm外调制有线电视系统的组合二阶失真指标

为克服长距离光纤有线电视（CATV）系统中采用高增益掺铒光纤放大器（EDFA）所带来的非线性损伤．对在残留边带调幅（AM—VSB）外调制光纤有线电视系统中采用光纤分布拉曼放大时的组合二阶失真（CSO）进行了,理论研究。根据拉曼放大对信号光强的增益作用。导出了分布拉曼放大条件下的薛定谔方程。并采用微扰法解出了存在拉曼分布放大时,残留边带调幅外调制有线电视系统中．自相位调制（SPM）导致的组合二阶失真的解析表达式。相应数值计算结果表明．相对于采用掺铒光纤放大器功放．采用相同放大倍数的分布托曼放大可使长距离系统中自相位调制导致的组合二阶失真性能改善10dB以上。因此可以得出结论：在长距离残留边带调幅凋制的有线电视系统中,采用分布式光纤拉曼放大可以较好地改善由自相位调制导致的组合二阶失真恶化。     

星载车尔尼-特纳型成像光谱仪像差校正的研究

为克服传统的车尔尼-特纳型光谱仪像差较大、空间分辨率低等缺点,提出了一种星载车尔尼-特纳型成像光谱仪像差校正方法.具体分析了像差校正的原理和方法,利用这种方法设计了视场角为2.3°,焦距为114.18 mm,F数为3.81,工作波段为540～850 nm星载车尔尼-特纳型成像光谱仪光学系统,运用光学设计软件Zemax对成像光谱仪总的光学系统进行光线追迹和优化,并对设计结果进行分析.结果表明,该系统的像差得到充分校正,全视场调制传递函数值在540～850 nm波段达0.58以上,完全满足设计指标要求,也证明了所提出的像差校正方法的可行性.     

用电热方法测定海水的比热容

该文运用电热学方法来测定海水的比热容,用电来加热海水,从而计算出升温所吸收的热量,利用测量液体升高温度所吸收的热量,来计算海水的比热容。通过计算和总结,得出测量液体比热容的普遍方法。     

Y(PO3)3双包覆改性对Li[Ni0.8Co0.15Al0.05]O2电化学性能的影响

在镍钴铝酸锂正极材料 Li[Ni_0.8Co_0.15Al_0.05]O₂(NCA)制备过程中表面遗留的碱性物质会严重影响其循环稳定性能,针对这一难题,提出使用Y(PO₃)₃对其进行表面包覆改性,利用Y(PO₃)₃与表面残留的LiOH反应消除表面残碱,并探讨包覆改性对NCA整体性能的影响机制。测试分析结果表明,在低温煅烧过程中前驱体表面会形成均匀致密的Y(PO₃)₃和LiPO₃包覆层,LiPO₃有较高的离子电导率,双包覆层能够防止活性物质在电化学循环过程中与电解液相互接触时发生有害副反应,提高电极材料的循环稳定性。其中Y(PO₃)₃包覆量(质量分数)为1%的样品在0.1C下的首次库仑效率从未改性样品的78.65%提高到88.50%,在1C下循环150圈后容量保持率从59.38%提高到85.33%,相比于未改性样品具有更高的首次库仑效率和更优异的循环性能。     

用同步辐射光研究CO在Cs/Ru(100)表面的吸附

(CO+Cs)/Ru(1010)共吸附的体系中,CO分子由于受CS原子强烈影响,分子轨道发生重新杂化组合.CO分子原来在清洁Ru(1010)表面上结合能位于7.5eV处相重叠的5σ和1π轨道对应谱峰分裂为两峰,结合能分别位于6.3和7.8eV处.其中6.3eV处的谱峰来自CO分子1π轨道的一支,它显示出该分子轨道沿衬底<0001>晶向的镜面反对称性.CO分子1π轨道的另一支和5σ轨道在结合能7.8eV处相重叠.