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排序方式: 共有638条查询结果,搜索用时 15 毫秒
141.
Butler F Boyer J Gidal G Abrams G Amidei D Baden AR Gold MS Goldhaber G Golding L Haggerty J Herrup D Juricic I Kadyk JA Levi ME Nelson ME Rowson PC Schellman H Schmidke WB Sheldon PD Trilling GH Wood DR Riles K Perl ML Barklow T Boyarski A Burchat PR Burke DL Dorfan JM Feldman GJ Gladney L Hanson G Hayes K Hollebeek RJ Innes WR Jaros JA Karlen D Klein SR Lankford AJ Larsen RR LeClaire BW Lockyer NS Lüth V Ong RA Richter B Yelton JM Schaad T 《Physical review D: Particles and fields》1990,42(5):1368-1384
142.
G W Milne A Feldman J A Miller G P Daly 《Journal of chemical information and computer sciences》1986,26(4):168-179
The Chemistry Module of the Drug Information System (DIS) handles a database of 400,000 structures. New or modified records are created in this database on a daily basis and are merged into the file promptly. The Chemistry database is searchable in a wide variety of ways and provides novel methods for both input and output of chemical structures. 相似文献
143.
A. V. Egorov I. A. Baranova A. A. Zezin A. A. Andriyanova V. I. Feldman 《High Energy Chemistry》2007,41(6):409-414
The processes of positive charge (hole) transfer between organic molecules of different classes occurring upon irradiation of their frozen freonic solutions at 77 K were studied by ESR spectroscopy. The efficiency of positive hole transfer was characterized by the “redistribution coefficient”, which was determined as ratio of concentrations of the radical cations of different compounds at equal concentrations of the parent neutral molecules. A very effective positive hole transfer to toluene was shown to occur for alkane-toluene pairs (K > 10). Meanwhile, much lower K values (~ 2 to 3) were observed for alkane-alkene pairs, in spite of a rather high difference in the ionization potentials (ca. 1 eV). This effect was explained by the conformation dispersion and distribution of environment configurations of ionized molecules for the alkane-alkene pairs. An effective positive hole transfer (K ~ 6) was observed for the pair dimethyl ether-acetone, where the conformation dispersion was absent, although the difference in ionization potentials for this pair was only 0.3 eV. 相似文献
144.
Abstract— The quantum yields and lifetimes of the fluorescence of tyrosine and tryptophan were determined in D2O-H2O and glycerol-H2O solvent mixtures of varying composition from 10 vol.% to 100% H2O at 15°C. Forboth amino acids the ratio of the quantum yields in D2O and H2O (i.e., qD/qH) was smaller than the ratio of the corresponding lifetimes (D/H). For tyrosine the ratio of the quantum yields in glycerol and H2O (qG/qH) was also smaller than the corresponding G/H ratio, but for tryptophan qG/gHG/H. The proximity of the q vs. plots for tyrosine in the two solvent mixtures indicates that at 15°C neither D2O nor glycerol, in the pure state or when diluted with H2O, quench tyrosine significantly. However, H2O quenches tyrosine by a dynamic process, which increases both the radiative and the nonradiative rate constant. The quenching action is attributed to a tyrosine-H2O exciplex, whose formation is independent of bulk viscosity and dielectric constant. Unlike tyrosine, tryptophan is quenched weakly by D2O by a static process at 15°C (i.e., involving no change in), but H2O quenches tryptophan much more efficiently by a dynamic process, which involves the nonradiative rate constant, but not the radiative constant. These results are explained on the basis of electrostatic complexation of the ammonium group to the carbon atom adjacent to the ring nitrogen with a lifetime which is longer thanin D2O but shorter thanin H2O, with solvent reorientation possibly also being an important factor in the quenching. This explanation is consistent with the fact that concentrated (8 M) urea increases q andof aqueous tryptophan ? 15–20%, while guanidine hydrochloride (6.4 M) has the opposite effect, i.e., it decreases q and t of tryptophan ? 15–20%, and with the fact that neither 8 M urea nor 6.4 M guanidine hydrochloride affects any fluorescence parameter of tyrosine at all. 相似文献
145.
J. Feldman 《Israel Journal of Mathematics》1976,24(1):16-38
A property is introduced, for 1-1 measure-preserving transformations of probability spaces, calledloose Bernoulliness (LB), which is invariant under taking factors, inducing, and tower-building. It amounts to replacing, in Ornstein’s definition
ofvery weak Bernoulli, the Hamming distance on strings by a coarser metric. The main result is the construction of a transformationT
0 which is ergodic and of entropy 0 butnot LB. On the other hand, any irrational rotationis LB. Consequently, the equivalence relation generated by inducing and tower-building (which I callKakutani equivalence, and the Russians callmonotone equivalence) has at least two distinct equivalence classes among the ergodic entropy zero transformations. A similar situation exists
for ergodic positive-entropy transformations: on the one hand, any Bernoulli shift is LB, while on the other hand a non LBK-automorphism
can be made by skewingT
0 over a Bernoulli base. 相似文献
146.
Abrams GS Adolphsen CE Averill D Ballam J Barish BC Barklow T Barnett BA Bartelt J Bethke S Blockus D Bonvicini G Boyarski A Brabson B Breakstone A Bulos F Burchat PR Burke DL Cence RJ Chapman J Chmeissani M Cords D Coupal DP Dauncey P DeStaebler HC Dorfan DE Dorfan JM Drewer DC Elia R Feldman GJ Fernandes D Field RC Ford WT Fordham C Frey R Fujino D Gan KK Gero E Gidal G Glanzman T Goldhaber G Gomez Cadenas JJ Gratta G Grindhammer G Grosse-Wiesmann P Hanson G Harr R Harral B Harris FA 《Physical review letters》1989,63(22):2447-2451
147.
Klein SR Himel T Abrams G Amidei D Baden AR Barklow T Boyarski AM Boyer J Burchat PR Burke DL Butler F Dorfan JM Feldman GJ Gidal G Gladney L Gold MS Goldhaber G Haggerty J Hanson G Hayes K Herrup D Hollebeek RJ Innes WR Jaros JA Juricic I Kadyk JA Karlen D Lankford AJ Larsen RR LeClaire BW Levi M Lockyer NS Lüth V Nelson ME Ong RA Perl ML Richter B Riles K Rowson PC Schaad T Schellman H Schmidke WB Sheldon PD Trilling GH de la Vaissiere C Wagner SR Wood DR Yelton JM 《Physical review letters》1989,62(21):2444-2447
148.
R. C. Y. Auyeung D. M. Zielke B. J. Feldman 《Applied physics. B, Lasers and optics》1989,48(4):293-297
The nonlinear material Tl3AsSe3 is used to convert pulsed 9.6 m CO2 laser radiation into its second, third, fourth and fifth harmonic. Internal (external) conversion efficiencies of 28, 14(6.7), 3.6(3.1), and 0.5(0.3)% from the pump fundamental are achieved in 4.8, 3.2, 2.4, and 1.9 m generation respectively. 相似文献
149.
150.