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51.
Mathematical Notes - This paper provides an elementary proof of inequalities previously obtained by the operator method and having applications in additive combinatorics. The method of proof allows... 相似文献
52.
A. F. Nilov 《Physics of Atomic Nuclei》2006,69(5):891-908
The status of isospin-5/2 exotic baryons consisting of light-quarks is considered. A brief survey of theoretical studies devoted to them is given. Experimental searches for exotic baryons are traced from the first publication on the subject to the present day. Among possible candidates for an exotic baryon, the pentaquark baryon E 5/2 5/2 of mass M ≈ 1.44 GeV/c 2 and width Γ < 0.05 GeV/c 2 is the most probable. This state was recorded in six studies at five different facilities. Among these, there are two studies where the excess of the signal above the background is more than five standard deviations. The possibility of further searches for exotic baryons in various reactions is discussed. 相似文献
53.
Laura Gherardi Daniela Bettinelli Sergio Spreafico Fedor G m ry 《Physica C: Superconductivity and its Applications》1998,310(1-4):52-56
Transport AC losses measured in self-field conditions on multifilamentary Bi-2223 tapes are often found to be lower than those calculated within the framework of the critical state model for a bulk wire with elliptical cross section, though generally higher than predicted for a strip. This effect is sometimes ascribed to the non-ideal geometry of the tapes, which does not exactly reproduce either shape. Here we propose an alternative explanation assuming that the critical current density of superconducting material depends on magnetic field. In practice, we analyzed the AC loss curve and deduced different Ic values for the individual data points, using the standard Norris equation for elliptical conductor. This gives the relation between ‘calculated' Ic and the self-field associated to AC transport current, which can be regarded as an alternative way to qualify the dependence of Jc on magnetic field. Important is that this procedure covers the range of fields below the self-field at Ic where the measurement in background DC field can not be used to determine Jc(B). 相似文献
54.
Mathiessen B Jensen AT Zhuravlev F 《Chemistry (Weinheim an der Bergstrasse, Germany)》2011,17(28):7796-7805
A series of phosphazenium hydrofluorides, P(1)(tBu)·[(18/19)F]HF, P(1)(tOct)·[(18/19)F]HF, P(2)(Et)·[(18/19)F]HF, and P(4)(tBu)·[(18/19)F]HF, was synthesized. The radioactive phosphazenium [(18)F]hydrofluorides were obtained by the one-step formation and trapping of gaseous [(18)F]HF with the respective phosphazene bases. The [(19)F] isotopomers were prepared from the corresponding phosphazene bases and Et(3)N·3HF. Under the design of experiment (DoE)-optimized conditions, P(2)(Et)·HF and P(4)(tBu)·HF fluorinated alkyl chlorides, bromides, and pseudohalides in 76-98% yield, but gave lower yields with iodides and electron-deficient arenes. DoE models showed that fluorination can be performed in glass vessels, and that the reactivity of P(2)(Et)·HF and P(4)(tBu)·HF is dominated by solvent polarity but is insensitive to water to at least 2 equiv. In contrast, P(1)(tBu)·HF and P(1)(tOct)·HF were unstable towards autofluorolysis. DFT calculations were performed to rationalize this finding in terms of diminished steric bulk, higher Parr's electrophilicity, and chemical hardness of P(1)(R)H(+). The corresponding radiofluorination reaction gave no valid DoE model but displayed similar substrate scope. High specific activity and excellent radiochemical yields with various pseudohalides (81-91%) suggest that the proposed radiofluorination methodology can complement the current [(18)F]KF/Kryptofix methods, particularly in the areas for which nonpolar reaction conditions are required. 相似文献
55.
Marlyn C. Ortiz Villamizar Carlos E. Puerto Galvis Silvia A. Pedraza Rodríguez Fedor I. Zubkov Vladimir V. Kouznetsov 《Molecules (Basel, Switzerland)》2022,27(23)
A rapid, efficient, and original synthesis of novel pyrido[3,2,1-de]phenanthridin-6-ones is reported. First, the key cinnamamide intermediates 8a–f were easily prepared from commercial substituted anilines, cinnamic acid, and 2-bromobenzylbromide in a tandem amidation and N-alkylation protocol. Then, these N-aryl-N-(2-bromobenzyl) cinnamamides 8a–f were subjected to a TFA-mediated intramolecular Friedel-Crafts alkylation followed by a Pd-catalyzed direct C–H arylation to obtain a series of potentially bioactive 4-phenyl-4,5-dihydro-6H,8H-pyrido[3,2,1-de]phenanthridin-6-one derivatives 4a–f in good yields. Finally, the toxicological profile of the prepared final compounds, including their corresponding intermediates, was explored through in silico computational methods, while the acute toxicity toward zebrafish embryos (96 hpf-LC50, 50% lethal concentration) was also determined in the present study. 相似文献
56.
Daria V. Vorobyeva Dmitry A. Petropavlovskikh Ivan A. Godovikov Fedor M. Dolgushin Sergey N. Osipov 《Molecules (Basel, Switzerland)》2022,27(23)
A convenient pathway to a new series of α-CF3-substituted α-amino acid derivatives bearing pharmacophore isoquinolone core in their backbone has been developed. The method is based on [4+2]-annulation of N-(pivaloyloxy) aryl amides with orthogonally protected internal acetylene-containing α-amino carboxylates under Rh(III)-catalysis. The target annulation products can be easily transformed into valuable isoquinoline derivatives via a successive aromatization/cross-coupling operation. 相似文献
57.
Anton V. Makarenkov Sergey S. Kiselev Elena G. Kononova Fedor M. Dolgushin Alexander S. Peregudov Yurii A. Borisov Valentina A. Olshevskaya 《Molecules (Basel, Switzerland)》2022,27(21)
An efficient one-pot synthesis of carborane-containing high-energy compounds was developed via the exploration of carbon–halogen bond functionalization strategies in commercially available 2,4,6-trichloro-1,3,5-triazine. The synthetic pathway first included the substitution of two chlorine atoms in s-triazine with 5-R-tetrazoles (R = H, Me, Et) units to form disubstituted tetrazolyl 1,3,5-triazines followed by the sequential substitution of the remaining chlorine atom in 1,3,5-triazine with carborane N- or S-nucleophiles. All new compounds were characterized by IR- and NMR spectroscopy. The structure of four new compounds was confirmed by single crystal X-ray diffraction analysis. The density functional theory method (DFT B3LYP/6-311 + G*) was used to study the geometrical structures, enthalpies of formation (EOFs), energetic properties and highest occupied and lowest unoccupied molecular orbital (HOMO and LUMO) energies and the detonation properties of synthesized compounds. The DFT calculation revealed compounds processing the maximum value of the detonation velocity or the maximum value of the detonation pressure. Theoretical terahertz frequencies for potential high-energy density materials (HEDMs) were computed, which allow the opportunity for the remote detection of these compounds. 相似文献
58.
Fedor A. Smirnov 《Communications in Mathematical Physics》1993,155(3):459-487
We study the limit of asymptotically free massive integrable models in which the algebra of nonlocal charges turns into affine algebra. The form factors of fields in that limit are described by KZ equations on level 0. We show the limit to be connected with finite-gap integration of classical integrable equations. 相似文献
59.
60.
Distant correlations are investigated within the framework of quantum mechanics. They are inherent to any physical situation in which two separated quantal systems are described by one composite state vector. Owing to correlations of this kind one can perform a measurement on one of the systems, thereby measuring a certain observable on the other (distant) system without interacting with it. Necessary and sufficient conditions are given for such a distant measurement to take place. It is found which are the observables that can be measured distantly, and which are the states of the distant system obtainable in this way. Solution of these problems is achieved by replacing the composite state vector by two entities equivalent to it: the reduced statistical operator of the system which is directly measured and a correlation operator. The latter gives a connection between states, observables, and probabilities of the two systems. Experimental evidence for distant measurement is discussed. 相似文献