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71.
The reaction of 3,3-diphenylindan-1,2-dione with trimethyl phosphite in dry benzene at room temperature for about 15 h led
to the formation of a mixture containing dimethyl (3,3-diphenyl-2-methoxy-1-indenyl)phosphate and dimethyl (3,3-diphenyl-1H-2-oxo-1-indanyl)phosphate, whereas with triisopropyl phosphite, diisopropyl (3,3-diphenyl-2-isopropoxy-1-indenyl)phosphate
is the only product. Treatment of the dione with dialkyl phosphites under different experimental conditions gave dialkyl (3,3-diphenyl-1-hydroxy-2-oxo-1-indanyl)phosphates.
Reaction mechanisms are presented which account for the experimental results. Structural assignments of the new compounds
are based on the spectroscopic evidences and two examples were elucidated by X-ray crystallography. 相似文献
72.
We consider the problem of simultaneously selecting customers to be served by external carriers and routing a heterogeneous internal fleet. Very little attention was devoted to this problem. A recent paper proposed a heuristic solution procedure. Our paper shows that better results can be obtained by a simple method and corrects some erroneous results presented in the previous paper. 相似文献
73.
M-C Bolduc J Renaud F Boctor G Laporte 《The Journal of the Operational Research Society》2008,59(6):776-787
The purpose of this article is to propose a perturbation metaheuristic for the vehicle routing problem with private fleet and common carrier (VRPPC). This problem consists of serving all customers in such a way that (1) each customer is served exactly once either by a private fleet vehicle or by a common carrier vehicle, (2) all routes associated with the private fleet start and end at the depot, (3) each private fleet vehicle performs only one route, (4) the total demand of any route does not exceed the capacity of the vehicle assigned to it, and (5) the total cost is minimized. This article describes a new metaheuristic for the VRPPC, which uses a perturbation procedure in the construction and improvement phases and also performs exchanges between the sets of customers served by the private fleet and the common carrier. Extensive computational results show the superiority of the proposed metaheuristic over previous methods. 相似文献
74.
We report the synthesis and superconductivity in iron-based oxypnictide LaO0.89F0.11FeSb, with the phase transition in the resistivity at 78.6 K and the onset transition temperature at 20.3 K. This compound showed an anomalous change in the resistivity slope, where a transition between the semiconducting and superconducting state has occurred. 相似文献
75.
Jilan A. Nazeam Ghada M. Ragab Amira A. El-Gazar Shereen S. El-Mancy Lina Jamil Sahar M. Fayez 《Molecules (Basel, Switzerland)》2021,26(18)
Antimicrobial resistance is a dramatic global threat; however, the slow progress of new antibiotic development has impeded the identification of viable alternative strategies. Natural antioxidant-based antibacterial approaches may provide potent therapeutic abilities to effectively block resistance microbes’ pathways. While essential oils (EOs) have been reported as antimicrobial agents, its application is still limited ascribed to its low solubility and stability characters; additionally, the related biomolecular mechanisms are not fully understood. Hence, the study aimed to develop a nano-gel natural preparation with multiple molecular mechanisms that could combat bacterial resistance in an acne vulgaris model. A nano-emulgel of thyme/clove EOs (NEG8) was designed, standardized, and its antimicrobial activity was screened in vitro and in vivo against genetically identified skin bacterial clinical isolates (Pseudomonas stutzeri, Enterococcus faecium and Bacillus thuringiensis). As per our findings, NEG8 exhibited bacteriostatic and potent biofilm inhibition activities. An in vivo model was also established using the commercially available therapeutic, adapalene in contra genetically identified microorganism. Improvement in rat behavior was reported for the first time and NEG8 abated the dermal contents/protein expression of IGF-1, TGF-β/collagen, Wnt/β-catenin, JAK2/STAT-3, NE, 5-HT, and the inflammatory markers; p(Ser536) NF-κBp65, TLR-2, and IL-6. Moreover, the level of dopamine, protective anti-inflammatory cytokine, IL-10 and PPAR-γ protein were enhanced, also the skin histological structures were improved. Thus, NEG8 could be a future potential topical clinical alternate to synthetic agents, with dual merit mechanism as bacteriostatic antibiotic action and non-antibiotic microbial pathway inhibitor. 相似文献
76.
I view the solar system in my paper as basically a double star, with the sun and Jupiter as components. Although the acceptance of this model may still be a philosophical choice, I introduce in my paper powerful arguments in favor of its support. Those arguments cover a wide range of conceptual, physical, and mathematical analysis. 相似文献
77.
The behaviour of the silicone rubber-based copper(II)-selective electrode in the presence of complexing agents is discussed. The electrode shows well defined responses to several complexing agents in solutions practically free of copper(II) ions. Titrimetric determinations of citrates and 8-hydroxyquinoline with potentiometric end-point detection are described. 相似文献
78.
We report on the electrical resistivity and far-infrared reflectance measurements of LaO1?xFxFeGe samples. Furthermore, we introduce a new method to probe the energy gap and determine its value. The onset transition temperature was 22.8 K for x = 0.13, and a clear anomaly was observed at 90 K in the ρ(T) curve for x = 0.11 with Tc = 20.6 K. We clearly observed the phonon-suppressed feature in reflectance spectra where F-doping caused a strong suppression of a peak at 200 cm?1. The energy gap above Tc, 2Δ = 2.10 meV, was determined from the measured spectra based on the changes in reflectivity by F-doping. 相似文献
79.
Stability indicating assays for determination of Donepezil Hydrochloride in presence of its oxidative degradate were developed and validated. The first three are spectrophotometric methods depending on using zero order (D(0)), first order (D(1)) and second order (D(2)) spectra. The absorbance was measured at 315 nm for (D(0)) while the amplitude was measured at 332.1nm for (D(1)) and 340 nm for (D(2)) using deionized water as a solvent. Donepezil Hydrochloride (I) can be determined in the presence of up to 70% of its oxidative degradate (II) using (D(0)), 80% using (D(1)) and 90% using (D(2)). The linearity range was found to be 8-56 microg ml(-1) for (D(0)), (D(1)) and (D(2)). These methods were applied for the analysis of I in both powder and tablet form. Also, a spectrofluorimetric method depending on measuring the native fluorescence of I in deionized water using lambda excitation 226 nm and lambda emission 391 nm is suggested. The linearity range was found to be 0.32-3.20 microg ml(-1) using this method, I was determined in the presence of up to 90% of II. The proposed method was applied for the analysis of I in tablet form as well as in human plasma. The last method depends on using TLC separation of I from its oxidative degradate II and I was then determined spectrodensitometrically. The mobile phase was methanol : chloroform : 25% ammonia (16 : 64 : 0.1 by volume). The linearity range was found to be 2-15 microg/spot. This method was applied to the analysis of I in both powder and tablet form using acetonitrile as a solvent. 相似文献
80.
El-Sherif ZA Mohamed AO El-Bardicy MG El-Tarras MF 《Chemical & pharmaceutical bulletin》2006,54(6):814-818
A simple sensitive, selective and accurate reversed-phase high performance liquid chromatographic method was developed and validated for the quantitative determination of lansoprazole, omeprazole and pantoprazole sodium sesquishydrate in the presence of their acid-induced degradation products. The three compounds were monitored at 280 nm using Nova-Pak C(18) column and a mobile phase consisting of 0.05 M potassium dihydrogen phosphate : methanol : acetonitrile (5 : 3 : 2 v/v/v). Linearity ranges were 2-20 mug ml(-1), 2-36 mug ml(-1) and 0.5-20 mug ml(-1) for lansoprazole, omeprazole and pantoprazole, respectively. The corresponding recoveries were 100.61+/-0.84%, 100.50+/-0.80% and 99.78+/-0.88%. The minimum detection limits were 0.55, 0.54 and 0.03 mug ml(-1) for lansoprazole, omeprazole and pantoprazole, respectively. The method could be successfully applied to the determination of pure, laboratory prepared mixtures and pharmaceutical dosage forms. The results obtained were compared with the reported methods for lansoprazole and pantoprazole or the official U.S.P method for omeprazole. 相似文献