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101.
102.
Dr. Burcin Akgun Prof. Dr. Dennis G. Hall 《Angewandte Chemie (International ed. in English)》2018,57(40):13028-13044
Over the past two decades, bioorthogonal chemistry has become a preferred tool to achieve site‐selective modifications of proteins. However, there are only a handful of commonly applied bioorthogonal reactions and they display some limitations, such as slow rates, use of unstable or cytotoxic reagents, and side reactions. Hence, there is significant interest in expanding the bioorthogonal chemistry toolbox. In this regard, boronic acids have recently been introduced in bioorthogonal chemistry and are exploited in three different strategies: 1) boronic ester formation between a boronic acid and a 1,2‐cis diol; 2) iminoboronate formation between 2‐acetyl/formyl‐arylboronic acids and hydrazine/hydroxylamine/semicarbazide derivatives; 3) use of boronic acids as transient groups in a Suzuki–Miyaura cross‐coupling or other reactions that leave the boronyl group off the conjugation product. In this Review, we summarize progress made in the use of boronic acids in bioorthogonal chemistry to enable site‐selective labeling of proteins and compare these methods with the most commonly utilized bioorthogonal reactions. 相似文献
103.
In this paper we consider the equation y
+q(t)y
+ p(t)h(y)=0, where p, q are real valued continuous functions on [0, ) such that q(t) 0, p(t) 0 and h(y) is continuous in (–, ) such that h(y)y > 0 for y 0. We obtain sufficient conditions for solutions of the considered equation to be nonoscillatory. Furthermore, the asymptotic behaviour of these nonoscillatory solutions is studied. 相似文献
104.
Aydin Aytuna Vyacheslav Zakharyuta 《Proceedings of the American Mathematical Society》2008,136(5):1733-1742
The main theorem of this note is the following refinement of the well-known Lelong-Bremermann Lemma: converges to uniformly on each compact subset of .
Let be a continuous plurisubharmonic function on a Stein manifold of dimension Then there exists an integer , natural numbers , and analytic mappings such that the sequence of functions
In the case when is a domain in the complex plane, it is shown that one can take in the theorem above (Section 3); on the other hand, for -circular plurisubharmonic functions in the statement of this theorem is true with (Section 4). The last section contains some remarks and open questions.
105.
Fatma Türkyilmaz Dr. Gerald Kehr Dr. Jun Li Dr. Constantin G. Daniliuc Matthias Tesch Prof. Armido Studer Prof. Gerhard Erker 《Angewandte Chemie (International ed. in English)》2016,55(4):1470-1473
B(C6F5)2‐containing boryldienes 4 underwent the addition of two molar equivalents of TEMPO to give N,O‐bonded four‐membered heterocyclic products 7 . The reaction is a metal‐free example of the generation of reactive nitrogen‐centered TEMPO radical derivatives, in this case by the addition of TEMPO to the borane, followed by carbon–nitrogen bond formation and subsequent trapping of the resulting allyl radical by the second equivalent of TEMPO. 相似文献
106.
This paper is concerned with the existence of positive solutions of second-order impulsive boundary value problem with integral boundary conditions on time scales. Existence results of at least three positive solutions are established via a new fixed point theorem in a cone. Also, an example is given to illustrate the effectiveness of our result. 相似文献
107.
Haydar Kilic Omer Aydin Sinan Bayindir Nurullah Saracoglu 《Journal of heterocyclic chemistry》2016,53(6):2096-2101
Bismuth nitrate catalyzed condensation reactions of indoline with 1,2‐ and 1,3‐diketones were investigated and were reported to proceed via different reaction pathways with the involvement of one or two of the carbonyl groups. While the reaction of indoline with cyclohexane‐1,3‐dione ( 4 ) gave solely condensation product, the reaction between the acetylacetone ( 5 ) and indoline provided N‐acetyl indoline as single products on retro‐aldol process. In contrast to 1,3‐diketones, the reaction with benzil ( 17 ) was performed under difficult conditions and proceeded to give secondary products. 相似文献
108.
Hakan Demirtas Robab Ahmadian Sema Atis Fatma Ezgi Can Ilker Ercan 《Computational Statistics》2016,31(4):1385-1401
Two algorithms for establishing a connection between correlations before and after ordinalization under a wide spectrum of nonnormal underlying bivariate distributions are developed by extending the iteratively found normal-based results via the power polynomials. These algorithms are designed to compute the polychoric correlation when the ordinal correlation is specified, and vice versa, along with the distributional properties of latent, continuous variables that are subsequently ordinalized through thresholds dictated by the marginal proportions. The method has broad applicability in the simulation and random number generation world where modeling the relationships between these correlation types is of interest. 相似文献
109.
In this paper Fermi-Walker derivative and Fermi-Walker parallelism and non-rotating frame concepts are given along the spherical indicatrix of a curve in E 3. First, we consider a curve in Euclid space and investigate the Fermi-Walker derivative along the tangent. The concepts which Fermi-Walker derivative are analyzed along its tangent. Then, the Fermi-Walker derivative and its theorems are analyzed along the principal normal indicatrix and the binormal indicatrix of any curve in E 3. 相似文献
110.
In this paper, we are reporting the influence of addition of aromatic acids (anthranilic and benzoic acid) and their sodium salts on the micellar morphological changes in three cationic gemini surfactant solutions, viz. 5 mM tetramethylene-1,4-bis(N-hexadecyl-N,N-dimethylammonium bromide), 10 mM pentamethylene-1,5-bis(N-hexadecyl-N,N-dimethylammonium bromide), and 10 mM hexamethylene-1,6-bis(N,-hexadecyl-N,N-dimethylammonium bromide). The solubilization site of the counterions (obtained from the additives) near the micellar surface are inferred by 1H NMR. The behavior is explained in the light of binding of counterions to the micelle as well as the nature of the functional group attached to the additive. 相似文献