One-pot Synthesis of 1,8-Dioxo-decahydroacridine Derivatives in Aqueous Media

A new and efficient method for the synthesis of 1,8‐dioxo‐9‐aryl‐decahydroacridine derivatives was developed via a one‐pot three component reaction of dimedone, aromatic aldehydes and ammonium acetate in the presence of ammonium chloride, or Zn(OAc)₂·2H₂O or L‐proline separately in water in the short period of time and high yields.     

An enaminone-directed benzannulation/macrocyclization approach to cyclophane ring systems

A straightforward and modular preparative approach to 1,3,5-triaroylbenzene-based functionalized cyclophane ring systems has been developed. The key cyclophane-forming macrocyclization reaction was accomplished during the course of a regioselective cross-benzannulation between bis(aryl ethynyl) ketone and enaminone reactants. Macrocyclic products with ring sizes ranging from 18- to 22-membered were successfully constructed. The composition of the tether connecting the two aryl ethynyl ketone fragments can be easily varied; consequently, this method is suitable for construction of a diverse range of structurally distinct cyclophane products. To illustrate this feature, cyclophanes possessing xylyl, alkyl, di(ethylene triamine), and di(ethylene oxy) bridging units were synthesized in isolated yields of 11-46%. Three new cyclophanes (calixarene-like macrocyles 8 and 9, as well as crownophane 18) were structurally characterized by X-ray diffractometry.     

Low Temperature Preparation of 3D Solid and Hollow ZnS Nanosphere Self-Assembled from Nanoparticles by Varying Sulfur Source

In this work, we report a facile hydrothermal method for the preparation of three dimensional hollow ZnS nanostructures, using Zinc bis(salicyle aldehitato), Zn(Sal)₂, thioacetamide (TAA) and thioglycolic acid (TGA) as Zn²⁺, sulfur source and capping agent, respectively. The ZnS solid and hollow sphere was produced from the self-assembly of nanoparticles with diameters of 11 ± 2 nm with TGA and TGA, TAA, respectively. Furthermore, with changing zinc precursor from Zn(Sal)₂ to zinc acetate [Zn(OAC)₂], ZnS nanorods were obtained. The products were characterized by XRD, SEM, TEM, selected area electron diffraction, and FT-IR spectra. The influence of surfactant (Polyethylene glycol) on the morphology of the products was also investigated. Possible formation mechanism and optical properties of these architectures were also reported.     

Spectral Investigations of Preferential Solvation and Solute–Solvent Interactions of Free Base and Protonated 5,10,15,20-Tetrakis(4-trimethyl-ammonio-phenyl)-porphine Tetratosylate in Aqueous Organic Mixed Solvents

The solvatochromic properties of the free base and the protonated 5,10,15,20-tetrakis(4-trimethyl-ammonio-phenyl)-porphine tetratosylate (TTMAPP) were studied in pure water, methanol, ethanol, 2-propanol, and their corresponding aqueous mixtures. The correlation of the empirical solvent polarity scale (E _T) values of TTMAPP with composition of the solvents were analyzed by the solvent exchange model of Bosch and Roses to clarify the preferential solvation of the probe dyes in the binary mixed solvents. The solvation shell composition effects in preferential solvation of the solute dyes were investigated in terms of both solvent–solvent and solute–solvent interactions and also the local mole fraction of each solvent composition was calculated in the cybotactic region of the probe. The effective mole fraction variation may provide significant physicochemical insights in the microscopic and molecular level of interactions between TTMAPP species and the solvent components and, therefore, can be used to interpret the solvent effect on kinetics and thermodynamics of TTMAPP.     

Preparation of an experimental glass-ionomer cements and evaluation of their properties

The preparation of glass-ionomer cements based on the composition of SiO₂–Al₂O₃–CaO–SrO–F and evaluation of their properties is described. Cements were prepared via the sol–gel method and characterized by XRD, BET, SEM, and EDAX analysis. The effect of various concentrations of Sr on in vitro bioactivity of the glass speciments was investigated. In vitro bioactivity of the samples was evaluated by soaking them in simulated body fluid followed by structural characterization using SEM and atomic absorption analysis. A glass specimen with 0.5 mol of Sr exhibited appropriate bioactivity.     

Solvothermal Synthesis and Characterization of PbSe Nanostructures with the Aid of Schiff-base Ligand

In this work, Pb(II)N,N-bis(salicylidene)-ethylenediamine; [Pb(salen)]; was applied as lead precursor to synthesis PbSe nanostructures. Besides [Pb(salen)], SeCl₄ and reducing agents like N₂H₄·H₂O have been employed for the production of PbSe nanostructures via a solvothermal route at 180 °C for 3 h in propylene glycol. The effect of preparation factors such as temperature, reaction time, and surfactant on the morphology of PbSe nanostructures was investigated. The experimental results indicated that PbSe synthesized at 150 and 210 °C was composed of agglomerated particles. On the other hand, the use of KBH₄ as reducing agent led to produce PbSe with higher particle size and agglomeration. The as-prepared PbSe nanostructures were characterized by XRD, SEM, TEM, EDS, and FT-IR.     

68Ga-5, 10, 15, 20-Tetrakis (2, 4, 6-trimethoxy phenyl) porphyrin: a novel radio-labeled porphyrin complex for positron emission tomography

Journal of Radioanalytical and Nuclear Chemistry - Porphyrins and 68Ga have emerged as novel synergic options for PET applications so the idea of preparation of a novel porphyrin complex using this...     

One-pot Synthesis of 3-Aminoimidazo[1,2-a]pyridines Catalyzed by Heteropolyacids

Condensation of aldehydes, isonitriles and 2‐aminopyridines in the presence of H₃PMo₁₂O₄₀ affords different derivatives of 3‐aminoimidazo[1,2‐a]pyridine in good to excellent yields.     

Keggin Heteropolyacid Catalyzed Synthesis of Isoxazolo[5,4-d]pyrimidine-4,6(5H,7H)-diones at Room Temperature

Isoxazolo[5,4‐d]pyrimidine‐4,6(5H,7H)diones 2a – 2f have been synthesized from the reaction of ethyl 5‐amino‐3‐methyl‐4‐isoxazole carboxylate ( 1 ) with aryl isocyanates in the presence of Keggin heteropolyacid H₃[PW₁₂O₄₀] as a green solid acid catalyst at room temperature in a one‐pot process in good yields.     

Nano-sized Cu6Sn5 alloy prepared by a co-precipitation reductive route

Nano-sized Cu₆Sn₅ alloy powders were prepared by a co-precipitation reductive route using a hydrothermal method at 80 °C. The nano-size and morphology of the synthesized Cu₆Sn₅ alloy powders were evaluated by X-ray diffraction (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The obtained morphologies, chemical compositions are comparatively discussed. A variety of synthesis parameters, such as time, capping agent and sort of reductant, has an effect on the morphology of the obtained materials, and will be particularly highlighted.