Determination of environmentally important metal ions by fluorescence quenching in anionic micellar solution

This work describes the effect of a variety of metal ions as quenchers of the fluorescence of naphthalene, in aqueous micellar solutions of sodium dodecyl sulfate (SDS). The quenching by the metal ions can be adequately described by the Stern-Volmer equation and the best signal to noise ratios are obtained with low micellized detergent concentrations. Apparent Stern-Volmer constants decrease in the order: Fe3+ > Cu2+ > Pb2+ > Cr3+ > Ni2+ and directly reflect the relative sensitivity of the method for these ions. Detection limits (defined as three times the standard deviation of the blank for n= 10) for the fluorescence quenching of naphthalene by the metal ions in aqueous micellar SDS are in the range of 1.0 x 10(-6) to 1.0 x 10(-5) mol dm(-3). The proposed fluorescence quenching method shows good repeatibility for a variety of added quencher metal ions, indicating that anionic micelle-enhanced fluorescence quenching by metal ions constitutes an analytical method of rather general application.     

The boundaries of the solutions of the linear Volterra integral equations with convolution kernel

Some boundaries about the solution of the linear Volterra integral equations of the second type with unit source term and positive monotonically increasing convolution kernel were obtained in Ling, 1978 and 1982. A method enabling the expansion of the boundary of the solution function of an equation in this type was developed in I. Özdemir and Ö. F. Temizer, 2002.

In this paper, by using the method in Özdemir and Temizer, it is shown that the boundary of the solution function of an equation in the same form can also be expanded under different conditions than those that they used.

     

Evaluation of high hydrostatic pressure effects on bovine red blood cells and platelets

The objective of this study was to investigate the effects of high hydrostatic pressure (HHP) on the stability of red blood cells (RBCs) and platelets. Bovine blood cells (n=5) were treated with the pressure of 55, 110, 154 and 220 MPa at 25 °C for 5 min. Light microscopy, atomic force microscopy and flow cytometry studies revealed that RBCs were morphologically stable up until the 220 MPa pressure treatments, at which surface modifications were observed. The platelets were found to be less stable than RBCs. HHP application did not cause any significant change in the signal intensity, band area and frequency values of the infrared bands with the exception that a significant variation was observed in the area of the cholesterol band. No statistically significant variations were observed in the secondary structure elements due to HHP treatment according to the artificial neural network study based on the FTIR data.     

Dynamic analysis of linear viscoelastic cylindrical and conical helicoidal rods using the mixed FEM

The objective of this study is to investigate the influence of the rotary inertia on dynamic behavior of linear viscoelastic cylindrical and conical helixes by means of the Laplace transform-mixed finite element formulation and solution. The element matrix is based on the Timoshenko beam theory. The influence of rotary inertias is considered in the dynamic analysis, which is original in the literature. Rectangular, sine and step type of impulsive loads are applied on helices having rectangular cross-sections with various aspect ratios. The Kelvin and standard models are used for defining the linear viscoelastic material behavior; and by means of the correspondence principle (the elastic-viscoelastic analogy), the material parameters are replaced with their complex counterparts in the Laplace domain. The analysis is carried out in the Laplace domain and the results are transformed back to time space numerically by modified Durbin?s algorithm. First, the solution algorithm is verified using the existing open sources in the literature and afterwards some benchmark examples such as conical viscoelastic rods are handled.     

Supramolecular inclusion complexes of a star polymer containing cholesterol end‐capped poly(ε‐caprolactone) arms with β‐cyclodextrin

A novel hexa‐armed and star‐shaped polymer containing cholesterol end‐capped poly(ε‐caprolactone) arms emanating from a phosphazene core (N₃P₃‐(PCL‐Chol)₆) was synthesized by a combination of ring‐opening polymerization and “click” chemistry techniques. For this purpose, the terminal ? OH groups of the synthesized precursor (N₃P₃‐(PCL‐OH)₆) were converted into –Chol through a series of reaction. Both N₃P₃‐(PCL‐OH)₆ and N₃P₃‐(PCL‐Chol)₆ were then employed in the preparation of supramolecular inclusion complexes (ICs) with β‐cyclodextrin (β‐CD). The latter formed ICs with β‐CD in higher yield. The host–guest stoichiometry (ε‐CL:β‐CD, mol:mol) in the ICs of N₃P₃‐(PCL‐Chol)₆ was found to be 1.2. The formation of supramolecular ICs of N₃P₃‐(PCL‐Chol)₆ with β‐CD was confirmed by using Fourier transform infrared (FTIR) and ¹H nuclear magnetic resonance (NMR) spectroscopic methods, wide‐angle X‐ray diffraction (WAXD), and thermal analysis techniques. WAXD data showed that the obtained ICs with N₃P₃‐(PCL‐Chol)₆ had a channel‐type crystalline structure, indicating the suppression of the original crystallization of N₃P₃‐(PCL‐Chol)₆ in β‐CD cavities. Moreover, the thermal stabilities of ICs were found to be higher than those of the free star polymer and β‐CD. Furthermore, the surface properties of N₃P₃‐(PCL‐Chol)₆ and its ICs with β‐CD were investigated by static contact angle measurements. The obtained results proved that the wettability of N₃P₃‐(PCL‐Chol)₆ successfully increased with the formation of its ICs with β‐CD. © 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2014 , 52, 3406–3420     

What determines the banking sector performance in globalized financial markets? The case of Turkey

This study attempts to give an insight into the trend in the performance of the Turkish banking sector by conducting a panel data fixed effects regression analysis. The results reveal that efficiency change is negatively related to the number of branches. We find a positive relationship between the loan ratio and the performance indices efficiency and efficiency change. Furthermore, bank capitalization is positively related to efficiency change. Interestingly however, return on equity is not statistically significant in explaining any of the efficiency measures. There is also no robust relationship between foreign ownership and efficiency. Finally, restructuring attempts in post-crises epoch robustly account for the improvement in efficiency scores in recent years.     

DFT - based study of electronic structures and mechanical properties of LiTaO3: ferroelectric and paraelectric phases

Abstract

By applying ab initio calculation within density functional theory (DFT), we study the structure parameters, electronic band structure, elastic coefficients, polycrystalline elastic properties, anisotropy factors and Debye temperature of ferroelectric and paraelectric phases of LiTaO₃ within the generalised gradient approximation at ambient pressure. The atomic structure in both phases is fully relaxed and the lattice constant, angle and atomic positions are well consistent with experimental values. The computed single-crystal elastic coefficients indicate that mechanical stability of LiTaO₃ in both phases is confirmed using the generalised Born criteria. The shear, bulk and Young’s modulus, Poisson’s ratio, and Vickers hardness were computed according to theoretical elastic constants by Voight–Reuss–Hill method. Several anisotropy factors and indexes are computed to illustrate mechanical anisotropy. Both phases are shown to be weakly anisotropic. The Debye temperature is estimated using the longitude and transverse elastic wave velocity of the ideal polycrystalline LiTaO₃ aggregates. We have found that LiTaO₃ in both phases has an indirect energy band gap. The differences in the electronic structure and density of states for both phases are quite small. Our results indicate that the mechanical and bonding properties of both phases are very similar. The obtained results were compared with the available experimental and theoretical values.     

Static and free vibration analysis of straight and circular beams on elastic foundation

Static and free vibration analyses of straight and circular beams on elastic foundation are investigated. The Timoshenko beam theory is adopted in the derivation of the governing equation. Ordinary differential equations in scalar form obtained in the Laplace domain are solved numerically using the complementary functions method. The static and free vibration analyses of beams on elastic foundation are analyzed through various examples.