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11.
Yazicioglu Y Royston TJ Spohnholtz T Martin B Loth F Bassiouny HS 《The Journal of the Acoustical Society of America》2005,118(2):1193-1209
The vibration of a thin-walled cylindrical, compliant viscoelastic tube with internal turbulent flow due to an axisymmetric constriction is studied theoretically and experimentally. Vibration of the tube is considered with internal fluid coupling only, and with coupling to internal-flowing fluid and external stagnant fluid or external tissue-like viscoelastic material. The theoretical analysis includes the adaptation of a model for turbulence in the internal fluid and its vibratory excitation of and interaction with the tube wall and surrounding viscoelastic medium. Analytical predictions are compared with experimental measurements conducted on a flow model system using laser Doppler vibrometry to measure tube vibration and the vibration of the surrounding viscoelastic medium. Fluid pressure within the tube was measured with miniature hydrophones. Discrepancies between theory and experiment, as well as the coupled nature of the fluid-structure interaction, are described. This study is relevant to and may lead to further insight into the patency and mechanisms of vascular failure, as well as diagnostic techniques utilizing noninvasive acoustic measurements. 相似文献
12.
Hüseyin Deligz Sibel Vatansever Faruk
ksüzmer S. Naci Ko Saadet
zgümü M. Ali Gürkaynak 《先进技术聚合物》2008,19(8):1126-1132
This paper describes our work on the synthesis of a series of sulfonated homo‐/co‐polyimides (SPI) which were obtained by post‐sulfonation method over three steps. In the first step, 4,4′‐oxydianiline (ODA) and 4,4′‐diaminodiphenylsulfone (DDS) dissolved in N‐methyl pyrrolidone (NMP) were reacted with benzophenonetetracarboxylic dianhydride (BTDA) in order to yield poly(amic acid) (PAA). Secondly, precipitated PAA was sulfonated via concentrated sulfuric acid (95–98%) at room temperature to give post‐sulfonated PAA (PSPAA). Finally, PSPAA was converted into post‐sulfonated PI (PSPI) by the thermal imidization method. PSPIs with ion exchange capacity (IEC) ranging from 0.20 to 0.67 meq/g were prepared. The thermal properties of the PSPIs were evaluated and high desulfonation temperature was found in the range of 190–350°C, suggesting the high stability of sulfonic acid groups. In water, PSPI‐5 membrane displayed similar proton conductivity to Nafion®117, whereas this membrane showed poor conductivity in dry state. All PSPIs displayed good solubility in common polar aprotic solvents such as NMP and dimethylacetamide (DMAc). Furthermore, the effects of post‐sulfonation reaction on chemical structure, thermal oxidative behavior, and physical properties of the PSPI membranes such as membrane quality/stability and water uptake were discussed. Copyright © 2008 John Wiley & Sons, Ltd. 相似文献
13.
Faruk Civan 《Transport in Porous Media》2007,67(2):329-334
An Arrhenius-type asymptotic-exponential function is derived to describe the temperature dependence of the power needed for
detachment of fine particles from pore walls in porous media. 相似文献
14.
Fevzihan Basarir Farid Sayar Irani Arif Kosemen B. Tugba Camic Faruk Oytun Bahadir Tunaboylu Hee Jeong Shin Ki Young Nam Hyosung Choi 《Materials Today Chemistry》2017
Organic photovoltaics (OPVs) are considered as a future alternative for conventional silicon based solar cells, owing to their low cost, ease of production and high-throughput. The transparent conducting electrode (TCE) is a fundamental component of OPVs. Traditionally, indium tin oxide (ITO) has been mainly utilized as a TCE in OPV applications due to its relatively high transparency and low sheet resistance. However, increasing demand for the optoelectronic devices has led to large fluctuations in ITO prices in the past decade and ITO is known to account more than 50% of the total cost of OPV devices. Thus, it is believed that development of solution-processable alternative materials is of great importance in reducing the cost of OPVs. Numerous materials, including silver nanowires, carbon nanotubes, graphene and conducting polymers, have been offered as replacements for ITO. This article reviews recent progress on fabrication of TCE via solution based coating techniques of silver nanowires (Ag NWs). In addition, performance of the Ag NWs based TCE in OPVs is summarized. Finally, we explore the future outlook for Ag NWs based TCE at the end of the review. 相似文献
15.
Ali Coruh Faruk Yilmaz Busra Sengez Mustafa Kurt Mehmet Cinar Mehmet Karabacak 《Structural chemistry》2011,22(1):45-56
This work presents the synthesis and characterization of a novel compound, 4-(thiophene-3-ylmethoxy)phthalonitrile (TMP).
The spectroscopic properties of the compound were examined by FT-IR, FT-Raman, NMR, and UV techniques. FT-IR and FT-Raman
spectra in solid state were observed in the region 4000–400 cm−1 and 3500–50 cm−1, respectively. The 1H and 13C NMR spectra were recorded in CDCl3 solution. The UV absorption spectrum of the compound that dissolved in THF was recorded in the range of 200–800 nm. The structural
and spectroscopic data of the molecule in the ground state were calculated using density functional theory (DFT) employing
B3LYP exchange correlation and the 6-311++G(d,p) basis set. The vibrational wavenumbers were calculated and scaled values
were compared with experimental FT-IR and FT-Raman spectra. The complete assignments were performed on the basis of the experimental
results and total energy distribution (TED) of the vibrational modes, calculated with scaled quantum mechanics (SQM) method.
Isotropic chemical shifts (13C NMR and 1H NMR) were calculated using the gauge-invariant atomic orbital (GIAO) method. A study on the electronic properties, such
as HOMO and LUMO energies, were performed by time-dependent DFT (TD-DFT) approach. The HOMO and LUMO analyses have been used
to elucidate information regarding charge transfer within the molecule. Comparison of the calculated frequencies, NMR chemical
shifts, absorption wavelengths with the experimental values revealed that DFT method produces good results. 相似文献
16.
In the present paper, we consider the classical Widder transform, the Hν-transform, the Kν-transform, and the Yν-transform. Some identities involving these transforms and many others are given. By making use of these identities, a number of new Parseval-Goldstein type identities are obtained for these and other well-known integral transforms. 相似文献
17.
Shale-Gas Permeability and Diffusivity Inferred by Improved Formulation of Relevant Retention and Transport Mechanisms 总被引:5,自引:0,他引:5
A theoretically improved model incorporating the relevant mechanisms of gas retention and transport in gas-bearing shale formations
is presented for determination of intrinsic gas permeability and diffusivity. This is accomplished by considering the various
flow regimes according to a unified Hagen–Poiseuille-type equation, fully compressible treatment of gas and shale properties,
and numerical solution of the non-linear pressure equation. The present model can accommodate a wide range of fundamental
flow mechanisms, such as continuum, slip, transition, and free molecular flow, depending on the prevailing flow conditions
characterized by the Knudsen number. The model indicates that rigorous determination of shale-gas permeability and diffusivity
requires the characterization of various important parameters included in the present phenomenological modeling approach,
many of which are not considered in previous studies. It is demonstrated that the improved model matches a set of experimental
data better than a previous attempt. It is concluded that the improved model provides a more accurate means of analysis and
interpretation of the pressure-pulse decay tests than the previous models which inherently consider a Darcian flow and neglect
the variation of parameters with pressure. 相似文献
18.
The temperature independent esr spectrum of di-i-Propyl-t-butylmethyl radical, derived from photolysis of oxalate ester, indicates a frozen “cogwhell” conformation for this specie. The neo-pentyl substituted oxalate esters are suggested to qive β-hydrogen abstraction on presence of di-t-butylperoxide on photolysis. 相似文献
19.
The effects of assuming equal or unequal crystal fields (CF) on the phase diagrams of a mixed spin-1 and spin-5/2 system are investigated in terms of the recursion relations on the Bethe lattice (BL). The equal CF case was considered for the coordination numbers q=3, 4, and 6, while for q=3 the unequal CF case was also studied. It was found that for the equal CF case, the model exhibits second-order phase transitions and two compensation temperatures for all q, the reentrant behavior for q=4 and first-order phase transitions and tricritical point (TCP) for q=6. In the unequal CF case for q=3, the system yields first- and second-order phase transitions, TCP's, and three compensation temperatures. In addition, the TCP's in a very short range are classified as the stable and unstable ones depending on their free energies. 相似文献
20.
Dr. Jingxia Yang Dr. Nevzat Yigit Jury Möller Prof. Günther Rupprechter 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(68):16947-16955
In an effort to combine the favorable catalytic properties of Co3O4 and CeO2, nanocomposites with different phase distribution and Co3O4 loading were prepared and employed for CO oxidation. Synthesizing Co3O4-modified CeO2 via three different sol-gel based routes, each with 10.4 wt % Co3O4 loading, yielded three different nanocomposite morphologies: CeO2-supported Co3O4 layers, intermixed oxides, and homogeneously dispersed Co. The reactivity of the resulting surface oxygen species towards CO were examined by temperature programmed reduction (CO-TPR) and flow reactor kinetic tests. The first morphology exhibited the best performance due to its active Co3O4 surface layer, reducing the light-off temperature of CeO2 by about 200 °C. In contrast, intermixed oxides and Co-doped CeO2 suffered from lower dispersion and organic residues, respectively. The performance of Co3O4-CeO2 nanocomposites was optimized by varying the Co3O4 loading, characterized by X-ray diffraction (XRD) and N2 sorption (BET). The 16–65 wt % Co3O4−CeO2 catalysts approached the conversion of 1 wt % Pt/CeO2, rendering them interesting candidates for low-temperature CO oxidation. 相似文献