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111.
M. Duran Toksarı Selçuk K. İşleyen Ertan Güner Ömer Faruk Baykoç 《Applied Mathematical Modelling》2008
In this paper, we introduced learning effect into assembly line balancing problems. In many realistic settings, the produced worker(s) (or machine(s)) develops continuously by repeated the same or similar activities. Therefore, the production time of product shortens if it is processed later. We show that polynomial solutions can be obtained for both simple assembly line balancing problem (SALBP) and U-type line balancing problem (ULBP) with learning effect. 相似文献
112.
Kirby AJ Lima MF da Silva D Roussev CD Nome F 《Journal of the American Chemical Society》2006,128(51):16944-16952
The hydrolysis of methyl 8-dimethylamino-1-naphthyl phosphate 4 and its reactions with a representative range of nucleophiles are catalyzed by the dimethylammonium group at acidic pH with rate accelerations of the order of 106. The reaction persists up to pH 7 because the strong intramolecular hydrogen bond, which is the key to efficient general acid catalysis, is present also in the reactant. The sensitivity to the basicity of the nucleophile (Br?nsted beta(nuc) = 0.29) lies between values measured previously for mono- and triesters. The comparisons suggest that general acid catalyzed reactions of phosphate mono- or diesters with strongly basic oxyanion nucleophiles (like those derived from a serine oxygen or a bound water molecule in an enzyme active site) will be fastest when their negative charges are neutralized by protonation. Reactions with NH2OH and its N-methylated derivatives show an apparent alpha-effect, but NH2OMe reacts no faster than a primary amine of similar basicity. It is suggested that the reaction involving NH2OH as an oxygen nucleophile proceeds through the pre-equilibrium formation of the tautomer H3N+-O- as the active nucleophile: ab initio calculations support this idea. 相似文献
113.
Let {δt}t>0 be a non-isotropic dilation group on R n . Let τ: R n → [0,∞) be a continuous function that vanishes only at the origin and satisfies τ(δ t x) = tτ(x), t > 0, x ∈ R n . In this paper we obtain two-sided inequalities for spherical means of the form $\int_{S^{n-1}}\tau(r_1\omega_1,\cdots,r_n\omega_n)^{-\alpha}d\sigma (\omega),$ where α is a positive constant, and r1,…, rn are positive parameters. 相似文献
114.
For dephosphorylation of bis(2,4-dinitrophenyl) phosphate (BDNPP) by hydroxylamine in water, pH region 4-12, the observed first-order rate constant, k(obs), initially increases as a function of pH, but is pH-independent between pH 7.2 and pH 10. The initial BDNPP cleavage by nonionic NH(2)OH (<0.2 M) involves attack by the OH group and follows first-order kinetics, but the overall initial reaction of BDNPP liberates ca. 1.7 mol of 2,4-dinitrophenoxide ion (DNP). This initial reaction generates a short-lived O-phosphorylated hydroxylamine, 2, followed by three possible reactions: (1) reaction of 2 with hydroxylamine, generating 2,4-dinitrophenyl phosphate (DNPP, 3), which subsequently forms DNP; (2) intramolecular displacement of the second DNP group and rapid decomposition of the cyclic intermediate to form phosphonohydroxylamine and eventually inorganic phosphate; (3) a novel rearrangement with intramolecular aromatic nucleophilic substitution involving a cyclic intermediate and migration of the 2,4-dinitrophenyl group from O to N. Values of k(obs) increase modestly with pH > 10, the reaction is biphasic, and the yield of DNP increases. An increase in [NH(2)OH] also increases the yield of DNP, due largely to accelerated hydrolysis of DNPP. 相似文献
115.
116.
Alvaro B. Onofrio Eliezer Jger Tiago A. S. Brando Adailton J. Bortoluzzi Faruk Nome 《Acta Crystallographica. Section C, Structural Chemistry》2006,62(5):o237-o239
The title compound (with the systematic name 2‐{[(1S)‐1‐(methoxycarbonyl)‐3‐methylbutyl]aminocarbonyl}benzoic acid), C15H19NO5, crystallizes in the monoclinic space group P21, with two independent molecules per asymmetric unit. The most notable difference between the two molecules is in the dihedral angles between the planes of the carboxyl group and the benzene ring, which are 3.5 (3) and 25.7 (1)°. This difference may account for the fact that two competing reactions are observed in aqueous solution, namely cyclization to form the imide N‐phthaloylleucine and hydrolysis of N‐(2‐carboxybenzoyl)‐l ‐leucine methyl ester to phthalic acid and leucine. 相似文献
117.
Kirby AJ Souza BS Medeiros M Priebe JP Manfredi AM Nome F 《Chemical communications (Cambridge, England)》2008,(37):4428-4429
The reaction of hydroxylamine with 2,4-dinitrophenyl diethyl phosphate gives the O-phosphorylated product, which is rapidly converted to hydrazine and nitrogen gas in the presence of the excess of hydroxylamine. 相似文献
118.
Priebe JP Lal Satnami M Tondo DW Souza BS Priebe JM Micke GA Costa AC Fiedler HD Bunton CA Nome F 《The journal of physical chemistry. B》2008,112(46):14373-14378
The rate of specific hydrogen ion-catalyzed hydrolysis of 2-( p-heptoxyphenyl)-1,3-dioxolane and acid-base equilibrium of 4-carboxy-1-n-dodecylpyridinium in zwitterionic micelles of SB3-14, C14H29NMe2+(CH2)3SO3(-) are controlled by NaClO4, which induces anionic character and uptake of H3O+ in the micelles. Other salts, e.g., NaF, NaCl, NaBr, NaNO3, NaI, NaBF4, have similar, but smaller, effects on the uptake of H3O+. Salt effects upon zeta potentials of SB3-14 micelles, estimated by capillary electrophoresis, are anion specific, and the anion order is similar to that of the rates of acid hydrolysis and of acid-base equilibria. Fluorescence quenching shows that the micellar aggregation number is not very sensitive to added salts, consistent with electrophoretic evidence. These specific anion effects follow the Hofmeister series and are related to anion hydration free energies. 相似文献
119.
Ozlem Gunes Adem Sarilmaz Salih Zeki Bas Mustafa Ozmen Faruk Ozel Mustafa Ersoz 《Electroanalysis》2021,33(12):2460-2468
This study presents a new electrochemical sensor (NiO−ERGO/SPE) for sensitive and selective detection of epinephrine (EPI) on the screen-printed electrode (SPE) which is modified with a nanocomposite film consisting of electrochemically reduced graphene oxide and NiO nanoparticles. After surface functionalization, structural and electrochemical characterization of NiO−ERGO film, DPV signals of NiO−ERGO/SPE towards the oxidation of EPI exhibited a linear correlation in the concentration range of 0.025 μM to 175 μM with a detection limit of 0.015 μM, which reveals NiO−ERGO film is manifested a good electrocatalytic activity for EPI detection compared with the previous reports. The selectivity of NiO−ERGO film was also tested on a very wide scale of possible interferents (ascorbic acid, uric acid, dopamine, lactic acid, phenylalanine, tyrosine, tryptophan, Li+, Na+, K+, Ca2+, and Zn2+). Moreover, to evaluate the applicability of the proposed sensor for real sample analysis, NiO−ERGO/SPE was successfully utilized for the determination of EPI in pharmaceutical samples. 相似文献
120.
Brandão TA Orth ES Rocha WR Bortoluzzi AJ Bunton CA Nome F 《The Journal of organic chemistry》2007,72(10):3800-3807
Rate constants for the hydrolysis of 2-(2'-imidazolium)phenyl hydrogen phosphate (IMPP) in water at pH<6 indicate that activation by the imidazolium moiety disappears with the deprotonation of the phosphate group, and the reaction involves the hydrogen-bonding of the imidazolium NH with the aryl oxygen leaving group. The reaction should involve a near-planar conformation of the imidazolium and the phenyl groups in the activated complex, which favors proton-transfer. The crystal structure of IMPP was solved, and a bond length-reactivity correlation for reactions of phosphate monoester monoanions is described. 相似文献