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排序方式: 共有197条查询结果,搜索用时 31 毫秒
51.
Carrillo N León-Silva U Avalos T Nicho ME Serna S Castillon F Farias M Cruz-Silva R 《Journal of colloid and interface science》2012,369(1):103-110
The chemical and enzymatic deposition of polyaniline (PANI) films by in situ polymerization was studied and the resulting films were characterized. The film formation and polymerization processes were simultaneously monitored by the evolution of the open circuit potential and quartz-crystal microbalance measurements. Different substrates, such as Indium-Tin oxide electrodes and gold-coated quartz-crystal electrodes were used as substrates for PANI deposition. Electroactive PANI films were successfully deposited by in situ enzymatic polymerization at low oxidation potential. The electrogravimetric response of the enzymatically deposited PANI film was studied by cyclic voltammetry in monomer-free acidic medium. The morphology of the films was observed by scanning electron microscopy, revealing a granular structure in enzymatically deposited PANI. The PANI films were also characterized by thermogravimetric analysis, electrochemical impedance spectroscopy, and X-ray photoelectron and Fourier-transformed infrared spectroscopy. The simultaneous use of quartz crystal microbalance and open circuit potential is presented as a very useful technique to monitor enzymatic reactions involving oxidoreductases. 相似文献
52.
Robson Araújo de Freitas Junior Paloma Kênia de Moraes Berenguel Lossavaro Cndida Aparecida Leite Kassuya Edgar Julian Paredes-Gamero Nelson Carvalho Farias Júnior Maria Inês Lenz Souza Francielli Maria de Souza Silva-Comar Roberto Kenji Nakamura Cuman Denise Brentan Silva Mnica Cristina Toffoli-Kadri Saulo Euclides Silva-Filho 《Molecules (Basel, Switzerland)》2022,27(12)
The aim of this study is to evaluate the phytochemical profile, oral acute toxicity, and the effect of ylang-ylang (Cananga odorata Hook. F. & Thomson) essential oil (YEO) on acute inflammation. YEO was analyzed by gas chromatography/mass spectrometry. For in vitro tests, YEO was assessed using cytotoxicity, neutrophil chemotaxis induced by N-formyl methionyl leucyl phenylalanine (fMLP), and phagocytic activity tests. YEO was orally administered in zymosan-induced peritonitis, carrageenan-induced leukocyte rolling, and adhesion events in the in situ microcirculation model and in carrageenan-induced paw edema models. YEO (2000 mg/kg) was also tested using an acute toxicity test in Swiss mice. YEO showed a predominance of benzyl acetate, linalool, benzyl benzoate, and methyl benzoate. YEO did not present in vitro cytotoxicity. YEO reduced the in vitro neutrophil chemotaxis induced by fMLP and reduced the phagocytic activity. The oral treatment with YEO reduced the leukocyte recruitment and nitric oxide production in the zymosan-induced peritonitis model, reduced rolling and adherent leukocyte number induced by carrageenan in the in situ microcirculation model, and reduced carrageenan-induced edema and mechanical hyperalgesia. YEO did not present signs of toxicity in the acute toxicity test. In conclusion, YEO affected the leukocyte activation, and presented antiedematogenic, anti-hyperalgesic, and anti-inflammatory properties. 相似文献
53.
We give a special ordered set (SOS) approach that optimizes a discontinuous separable piecewise linear function, even when a mixed-integer programming (MIP) model is not available for it. When a MIP model is available, our SOS model gives a linear programming relaxation bound that is as good as the MIPs. 相似文献
54.
Summary The adsorptive stripping voltammetric behaviour of Arsenazo III, Eriochrome Black T, 4-(2-pyridylazo) resorcinol, Mordante Blue 9 and their uranyl complexes has been investigated in detail. All compounds and complexes adsorb on the static mercury drop electrode. Results are presented and the limitations of the methods are discussed. 相似文献
55.
Voltammetric determination of copper and lead in gasoline using sample preparation as microemulsions. 总被引:1,自引:0,他引:1
Carlos E Cardoso Wagner F Pacheco Rangel Sarubi Márcio L N Ribeiro Pércio A M Farias Ricardo Q Aucélio 《Analytical sciences》2007,23(9):1065-1069
A voltammetric method for the determination of Cu(II) and Pb(II) in gasoline using sample preparation as three-component solutions (gasoline:propan-1-ol:water, 25:60:15 v/v/v) is proposed. HNO(3) was employed as a supporting electrolyte and to allow the use of aqueous inorganic standards for calibration, even if the analyte species originally in gasoline is present as a metallo-organic form. A square-wave anodic sequential determination was used by measuring the stripping current of Cu(II) (at +104 mV) using a glassy carbon electrode (GCE) and, in a second run, measuring the Pb(II) stripping current (at -470 mV) using a bismuth-film deposited on the surface of the GCE. The method allowed the quantification of 1.7 x 10(-9) mol L(-1) of Cu and 1.4 x 10(-10) mol L(-1) of Pb employing a 1500-s accumulation time. Recovery tests using analyte spiked three-component solutions prepared with commercial gasoline samples enabled recoveries of Cu and Pb from 97 +/- 8 to 102 +/- 5%. 相似文献
56.
I. Lima M.L.F. Farias N. Percegoni D. Rosenthal J.T. de Assis M.J. Anjos R.T. Lopes 《Spectrochimica Acta Part B: Atomic Spectroscopy》2010
Characterization of trabeculae structures is one of the most important applications of imaging techniques in the biomedical area. The aim of this study was to investigate structure modifications in trabecular and cortical bones using non destructive techniques such as X-ray microtomography, X-ray microfluorescence by synchrotron radiation and scanning electron microscopy. The results obtained reveal the potential of this computational technique to verify the capability of characterization of internal bone structures. 相似文献
57.
58.
Tiago C. Adorno Alexander I. Breev Antonio J. D. Farias Jr. Dmitri M. Gitman 《Annalen der Physik》2023,535(7):2300118
The problem of the electromagnetic radiation produced by charge distributions in the framework of a semiclassical approach proposed in the work by Bagrov, Gitman, Shishmarev, and Farias Jr. [J. Synchrotron Rad. 27 , 902–911 (2020)] is addressed here. In this approach, currents, generating the radiation are considered classically, while the quantum nature of the radiation is kept exactly. Quantum states of the electromagnetic field are solutions of Schrödinger's equation, and relevant quantities to the problem are evaluated with the aid of transition probabilities. This construction allows us to introduce the quantum transition time in physical quantities and assess its role in radiation problems by classical currents. Radiated electromagnetic energies are studied in detail and a definition for the rate at which radiation is emitted from sources is presented. In calculating the total energy and rate radiated by a pointlike charged particle accelerated by a constant and uniform electric field, it is discovered that these results are compatible with results obtained by other authors in the framework of the classical radiation theory under an appropriate limit. Numerical and asymptotic analyses of the results are also performed. 相似文献
59.
Gaiao Eda N Martins VL Lyra Wda S de Almeida LF da Silva EC Araújo MC 《Analytica chimica acta》2006,570(2):283-290
The exploitation of digital images obtained from a CCD camera (WebCam) as a novel instrumental detection technique for titration is proposed for the first time. Named of digital image-based (DIB) titration, it also requires, as a traditional titration (for example, spectrophotometric, potentiometric, conductimetric), a discontinuity in titration curves where there is an end point, which is associated to the chemical equivalence condition. The monitored signal in the DIB titration is a RGB-based value that is calculated, for each digital image, by using a proposed procedure based on the red, green, and blue colour system. The DIB titration was applied to determine HCl and H3PO4 in aqueous solutions and total alkalinity in mineral and tap waters. Its results were compared to the spectrophotometric (SPEC) titration and, by applying the paired t-test, no statistic difference between the results of both methods was verified at the 95% confidence level. Identical standard deviations were obtained by both titrations in the determinations of HCl and H3PO4, with a slightly better precision for DIB titration in the determinations of total alkalinity. The DIB titration shows to be an efficient and promising tool for quantitative chemical analysis and, as it employs an inexpensive device (WebCam) as analytical detector, it offers an economically viable alternative to titrations that need instrumental detection. 相似文献
60.
Luciano Farias de Novaes Lucas Oliveira Borges José Alberto Domingues Rodrigues Suzana Maria Ratusznei Marcelo Zaiat Eugenio Foresti 《Applied biochemistry and biotechnology》2010,162(3):885-899
Many lab-scale studies have been carried out regarding the effect of feed strategy on the performance of anaerobic sequencing
batch reactors (ASBR); however, more detailed pilot-scale studies should be performed to assess the real applicability of
this type of operation. Therefore, the objective of this work was to assess the effect of feed strategy or fill time in a
1-m3 mechanically stirred pilot-scale sequencing batch reactor, treating 0.65 m3 sanitary wastewater in 8-h cycles at ambient temperature. Two reactor configurations were used: one containing granular biomass
(denominated ASBR) and the other immobilized biomass on polyurethane foam as inert support (denominated anaerobic sequencing
batch biofilm reactor (AnSBBR)). The reactors were operated under five distinct feed strategies, namely: typical batch and
fed-batch for 25%, 50%, 75%, and 100% of the cycle length. Stirring frequency in the ASBR was 40 rpm with two flat-blade turbine
impellers and 80 rpm in the AnSBBR with two helix impellers. The results showed that both the ASBR and AnSBBR when operated
under typical batch, fed-batch for 50% and 75% of the cycle length, presented improved organic matter removal efficiencies,
without significant differences in performance, thus showing important operational flexibility. In addition, the reactors
presented operation stability under all conditions. 相似文献