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71.
聚丙烯熔融接枝马来酸酐反应机理的研究 总被引:17,自引:0,他引:17
改变聚丙烯(PP)熔融接枝马来酸酐(MAH)反应中的单体和引发剂的浓度以及添加适当助剂,考察了接枝产物的接枝率和恒定剪切应力(600kPa)及温度(210℃)下的剪切粘度,验证了作先前所提出的PP熔融接枝MAH的反应机理。即:在PP熔融接枝MAH的过程中,过氧化物自由基在熔融接枝过程中直接引发MAH单体及MAH单体在聚丙烯的大分子链段发生β断裂前直接被其引发而产生的接枝反应是影响产物的接枝率和分子量的关键。在不改变单体和引发剂浓度的情况下,降低过氧化物自由基在熔融接枝过程中直接引发MAH单体反应的程度而提高聚丙烯的大分子自由基直接引发MAH单体的反应趋势,是提高接枝产物接枝率和分子量的有效途径。 相似文献
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高效液相色谱法测定油田水中的非离子表面活性剂 总被引:6,自引:1,他引:6
提出了一种用高效液相色谱法测定油田水中聚氧乙烯辛基苯酚醚-10(OP-10)总量的方法,讨论了固定相和流动相体系的选择、操作参数的优化、共存物对测定的干扰。测定了模拟油田水样品。 相似文献
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Cover Feature: [CH3NH3]4Ga4SbS9S0.28O0.72H: A Three‐Dimensionally Open‐Framework Heterometallic Chalcogenidoantimonate Exhibiting Ni2+ Ion‐Exchange Property (Chem. Asian J. 6/2018) 下载免费PDF全文
Dr. Bo Zhang Wei‐An Li Yi‐Yu Liao Chen Zhang Dr. Mei‐Ling Feng Prof. Dr. Xiao‐Ying Huang 《化学:亚洲杂志》2018,13(6):585-585
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A Multi‐Stimuli‐Responsive Oxazine Molecular Switch: A Strategy for the Design of Electrochromic Materials 下载免费PDF全文
Xiaojun Wang Chang Gu Hongzhi Zheng Dr. Yu‐Mo Zhang Prof. Sean Xiao‐An Zhang 《化学:亚洲杂志》2018,13(9):1206-1212
A multi‐state and multi‐stimuli‐responsive oxazine molecular switch that combines an electro‐base property and sensitive base/acid‐responsive properties was designed and synthesized. The multi‐state structures of the molecular switch, with different colors, were predicted by comparing the optical properties with reference molecules and confirmed by using NMR spectroscopy. The color‐switching mechanism under stimulation with acids and bases was investigated by using DFT calculations. Three single states can be obtained and the switching is unidirectional under acid and base stimulation. The electrochromic phenomenon of the molecular switch, which combines its electro‐base and base‐sensitive properties, was demonstrated. An electrochromic device that exhibited good electrochromic properties with excellent reversibility (2000 cycles) and high coloration efficiency (804 cm2 C?1) was successfully constructed. 相似文献
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A Rapidly Self‐Healing Host–Guest Supramolecular Hydrogel with High Mechanical Strength and Excellent Biocompatibility 下载免费PDF全文
Dr. Ye Zhu Dr. Lijing Hao Dr. Yunhua Chen Prof. Dr. Geng An Prof. Dr. Hongkai Wu Prof. Dr. Xuetao Shi Prof. Dr. Chuanbin Mao 《Angewandte Chemie (International ed. in English)》2018,57(29):9008-9012
It is still a challenge to achieve both excellent mechanical strength and biocompatibility in hydrogels. In this study, we exploited two interactions to form a novel biocompatible, slicing‐resistant, and self‐healing hydrogel. The first was molecular host–guest recognition between a host (isocyanatoethyl acrylate modified β‐cyclodextrin) and a guest (2‐(2‐(2‐(2‐(adamantyl‐1‐oxy)ethoxy)ethoxy)ethoxy)ethanol acrylate) to form “three‐arm” host–guest supramolecules (HGSMs), and the second was covalent bonding between HGSMs (achieved by UV‐initiated polymerization) to form strong cross‐links in the hydrogel. The host–guest interaction enabled the hydrogel to rapidly self‐heal. When it was cut, fresh surfaces were formed with dangling host and guest molecules (due to the breaking of host–guest recognition), which rapidly recognized each other again to heal the hydrogel by recombination of the cut surfaces. The smart hydrogels hold promise for use as biomaterials for soft‐tissue repair. 相似文献
79.
Božidar Čobeljić Andrej Pevec Stepan Stepanović Milica R. Milenković Iztok Turel Maja Gruden Dušanka Radanović Katarina Anđelković 《Structural chemistry》2018,29(6):1797-1806
The isothiocyanato Zn(II) complex (1) and mixed isothiocyanato/thiocyanato Cd(II) complex (2) with the condensation product of 2-acetylpyridine and trimethylammoniumacetohydrazide chloride (Girard’s T reagent) (HLCl) were investigated both experimentally and theoretically. The crystal structures of both complexes showed tridentate N2O coordination of hydrazine ligand. In complex 1 square-pyramidal coordination surrounding of Zn(II) consists of deprotonated hydrazone ligand and two isothiocyanato ligands, while in octahedral Cd(II) complex ligand is coordinated without deprotonation as a positively charged species and coordination geometry is completed with two N-coordinated and one S-coordinated NCS? anions. NMR spectroscopy and molar conductivity results for Cd(II) and Zn(II) complexes indicated their instability in solution. DFT calculations were performed to explain coordination preference and stability of complexes 1 and 2 in solid state and in solution. The obtained Cd(II) complex is the first reported mononuclear pseudohalide/halide Cd(II) complex with quinoline-/pyridine-based hydrazone ligands possessing octahedral geometry in solid state. In this complex, H-bonding has significant impact on coordination number and supramolecular assembly in solid state. 相似文献
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