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931.
Fabrizio Melani Lucia Cecchi Giovanna Palazzino Guido Filacchioni 《Journal of heterocyclic chemistry》1985,22(4):1109-1112
The synthesis of pyrazolo[4,5-c][1]benzazepin-10-ones 10 and 13 and pyrazolo[4,3-c][1]benzazepin-10-ones 11 and 12 is reported. The structure of compounds 10-13 and that of their parent compounds 2-5 ensues from a 13C nmr study. 相似文献
932.
Bergami C Donzello MP Ercolani C Monacelli F Kadish KM Rizzoli C 《Inorganic chemistry》2005,44(26):9852-9861
A new octacationic macrocycle, tetrakis-2,3-[5,6-di{2-(N-methyl)pyridiniumyl}pyrazino]porphyrazine, was obtained in its hydrated form as the water-soluble iodide salt. This compound, abbreviated as [(2-Mepy)(8)TPyzPzH(2)](I(8)).8H(2)O (2-Mepy = 2(N-methyl)pyridiniumyl moiety), was obtained by demetalation of the corresponding Mg(II) complex, [(2-Mepy)(8)TPyzPzMg(H(2)O)](I(8)).5H(2)O, which in turn was prepared from its corresponding neutral hydrated species tetrakis-2,3-[5,6-di(2-pyridyl)pyrazino]porphyrazinato(monoaquo)magnesium(II), [Py(8)TPyzPzMg(H(2)O)].4H(2)O, by reaction with CH(3)I in N,N-dimethylformamide. The quaternization reactions by using CH(3)I or methyl p-toluenesulfonate were also conducted on the monomeric precursor 2,3-dicyano-5,6-di(2-pyridyl)-1,4-pyrazine, [(CN)(2)Py(2)Pyz], with formation of the monoquaternized ion [(CN)(2)Py(2-Mepy)Pyz](+) neutralized by iodide and p-toluenesulfonate anions. Single-crystal X-ray work allowed elucidation of the structure of the two salt-like species. The diquaternized ion [(CN)(2)(2-Mepy)(2)Pyz](2+) could also be obtained as a p-toluenesulfonate salt, but attempts at direct macrocyclization of this dicationic species were unsuccessful. The iodide salt [(2-Mepy)(8)TPyzPzH(2)](I(8)).8H(2)O is water-soluble, with different solubilities depending on the range of pH explored. It was established that the macrocycle [(2-Mepy)(8)TPyzPzH(2)](8+) undergoes facile deprotonation and behaves as a strong acid. Aggregation phenomena are observed for both the octacation [(2-Mepy)(8)TPyzPzH(2)](8+) and its corresponding centrally deprotonated species [(2-Mepy)(8)TPyzPz](6+). Nevertheless, both cationic moieties exist in their monomeric form under specific experimental conditions. UV-visible monitored titrations with NaOH provide information about the type of protonation/deprotonation equilibria which are complicated by the occurrence of aggregation phenomena. 相似文献
933.
Sunto Per un problema relativo allo studio di campi elettrici armonici con una condizione al contorno dissipativa espressa dalla relazione: (*) Et=*Ht×n si perviene a un teorema di esistenza, unicità e dipendenza continua. Cioè si prova la correttezza del problema ehe invece non sussiste se si sostituisce la relazione (*) con la usuale condizione al contorno dei conduttori perfetti: Et×n=0.
Lavoro eseguito nell'ambito delle attività del G.N.F.M. 相似文献
Summary For the problem relating to the study of electromagnetic fields with a dissipative boundary condition expressed by the relation: (*) Et=*Ht×n we prove a theorem of existence, uniqueness and continuous dependence. That is we prove the correctness of the problem that does not exist if we replace the relation (*) by the customary boundary condition for a perfect conducting medium: Et×n=0.
Lavoro eseguito nell'ambito delle attività del G.N.F.M. 相似文献
934.
Ottorino DeLucchi Arif Datan Aliye Altunda Fabrizio Fabris Metin Balci 《Helvetica chimica acta》2004,87(9):2364-2367
An efficient synthetic route to the concave‐shaped, potentially ionophoric syn‐ and anti‐isomers of 5,6,11,12,17,18‐hexahydro‐5,18:6,11:12,17‐triepoxytrinaphthylene ( 4 ) was elaborated. Starting from ‘oxabenzonorbornadiene’ ( 5 ), the stannylated precursor 9 was prepared in three steps, followed by cyclotrimerization catalyzed by copper(I) thiophene‐2‐carboxylate (CuTC) , which afforded 4 in a syn/anti ratio of 5 : 4. 相似文献
935.
Carlo Di Nallo Fabrizio Frezza Alessandro Galli Paolo Lampariello 《International Journal of Infrared and Millimeter Waves》1996,17(8):1403-1418
The resonance modes of dielectric resonators having parallelepiped shape are extensively investigated in this work referring to the nonradiative dielectric (NRD) topology. Different numerical techniques, both rigorous and approximated (boundary elements, point matching, finite elements, transmission line approaches), are proposed and implemented to compute the relevant resonance spectrum as a function of the involved geometric and electromagnetic parameters. The theoretical results are discussed and compared also in connection with experimental investigations, carried out on suitable prototypes of NRD components. Qualitative and quantitative information is thus achieved to characterize with accuracy and efficiency the basic parameters (resonant frequencies, field configurations, etc.) involved in filter design and in other applications at microwaves and millimeter waves. 相似文献
936.
937.
938.
939.
Franco Bellesia Laurent De Buyck Franco Ghelfi Adele Mucci Ugo M. Pagnoni Fabrizio Roncaglia 《Tetrahedron》2006,62(4):746-757
Chaetomellic anhydride A was efficiently attained in three steps, starting from 2,2-dichloropalmitic acid and 2-(3-chloro-2-propenylamino)pyridine. Atom transfer radical cyclisation selectively formed the cis-stereoisomer of the trichloropyrrolidin-2-one, which underwent a stereospecific functional rearrangement to form a substituted maleimide. The choice of 2-pyridyl, as ‘cyclisation auxiliary’ in the atom transfer radical cyclisation step, proved beneficial for hydrolysis of the maleimide to form the desired anhydride. 相似文献
940.
Phononic properties of hexagonal chiral lattices 总被引:1,自引:0,他引:1