全文获取类型
收费全文 | 717篇 |
免费 | 52篇 |
国内免费 | 2篇 |
专业分类
化学 | 552篇 |
晶体学 | 1篇 |
力学 | 23篇 |
数学 | 80篇 |
物理学 | 115篇 |
出版年
2023年 | 9篇 |
2022年 | 8篇 |
2021年 | 11篇 |
2020年 | 20篇 |
2019年 | 13篇 |
2018年 | 23篇 |
2017年 | 5篇 |
2016年 | 38篇 |
2015年 | 22篇 |
2014年 | 28篇 |
2013年 | 35篇 |
2012年 | 60篇 |
2011年 | 80篇 |
2010年 | 39篇 |
2009年 | 47篇 |
2008年 | 64篇 |
2007年 | 69篇 |
2006年 | 55篇 |
2005年 | 52篇 |
2004年 | 24篇 |
2003年 | 26篇 |
2002年 | 23篇 |
2001年 | 4篇 |
2000年 | 3篇 |
1999年 | 2篇 |
1998年 | 2篇 |
1997年 | 1篇 |
1996年 | 2篇 |
1995年 | 1篇 |
1992年 | 2篇 |
1991年 | 2篇 |
1981年 | 1篇 |
排序方式: 共有771条查询结果,搜索用时 343 毫秒
731.
Gloaguen E Mestdagh JM Poisson L Lepetit F Visticot JP Soep B Coroiu M Eppink AT Parker DH 《Journal of the American Chemical Society》2005,127(47):16529-16534
The existence of a mediating state for the ultrafast electronic relaxation in ethylenic-like molecules has been shown by femtosecond electron imaging techniques. This state is of Rydberg character, and its high efficiency is due to its ability to link the electron distributions of the initial and final electronic states. 相似文献
732.
Beam uniformity is a crucial building block of CO2 experiments aimed at fusing and stretching optical fibers in a lossless manner. When the irradiation beam is expanded through a galvanometer mirror, ways to achieve beam uniformity are investigated. 相似文献
733.
734.
Using some properties of the Hardy spaces, we give a regularity result on the advection term of the shallow-water equations and we show a bound holding up to the boundary on the water height with Dirichlet boundary conditions. To cite this article: F. Flori, P. Orenga, C. R. Acad. Sci. Paris, Ser. I 340 (2005). 相似文献
735.
We present in this Note an existence result for a bi-layer shallow water problem, with Dirichlet boundary conditions. The main difficulty arises from the terms coupling the two layers. To handle these, we must couple the natural energy estimate with an estimation of the thickness in . To obtain this -estimate, we introduce the Stokes operator and we use results for Hardy spaces to treat the nonlinear terms. To cite this article: F. Flori et al., C. R. Acad. Sci. Paris, Ser. I 340 (2005). 相似文献
736.
Alet F Jacobsen JL Misguich G Pasquier V Mila F Troyer M 《Physical review letters》2005,94(23):235702
We study a model of close-packed dimers on the square lattice with a nearest neighbor interaction between parallel dimers. This model corresponds to the classical limit of quantum dimer models [D. S. Rokhsar and S. A. Kivelson, Phys. Rev. Lett. 61, 2376 (1988)]. By means of Monte Carlo and transfer matrix calculations, we show that this system undergoes a Kosterlitz-Thouless transition separating a low temperature ordered phase where dimers are aligned in columns from a high temperature critical phase with continuously varying exponents. This is understood by constructing the corresponding Coulomb gas, whose coupling constant is computed numerically. We also discuss doped models and implications on the finite-temperature phase diagram of quantum dimer models. 相似文献
737.
We propose an alternative formulation of many-body perturbation theory that uses the density-functional concept. Instead of the usual four-point integral equation for the polarizability, we obtain a two-point one, which leads to excellent optical absorption and energy-loss spectra. The corresponding three-point vertex function and self-energy are then simply calculated via an integration, for any level of approximation. Moreover, we show the direct impact of this formulation on the time-dependent density-functional theory. Numerical results for the band gap of bulk silicon and solid argon illustrate corrections beyond the GW approximation for the self-energy. 相似文献
738.
Increasing interest in oxide supported nanoparticle science and technology is stimulating research into controlling nanocrystal shape. Pd forms nanocrystals on the surface of SrTiO3(001), and depending on the crystallographic interface of the Pd with the substrate three shapes can be created: truncated pyramids, huts, and hexagonal shaped disks. Scanning tunneling microscopy reveals that the nanocrystal shapes are determined by the substrate reconstruction and the substrate temperature during deposition. A thermodynamic model is used to show that the pyramids and huts are stable structures, and that the hexagons are trapped in a metastable state. 相似文献
739.
Dr. Lambert Sicard Fabien Lucas Dr. Olivier Jeannin Dr. Pierre-Antoine Bouit Dr. Joëlle Rault-Berthelot Dr. Cassandre Quinton Dr. Cyril Poriel 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(27):11159-11165
For the last ten years, ring-shaped π-conjugated macrocycles possessing radially directed π-orbitals have been subject to intense research. The electronic properties of these rings are deeply dependent on their size. However, most studies involve the flagship family of nanorings: the cyclo-para-phenylenes. We report herein the synthesis and study of the first examples of cyclofluorenes possessing five constituting fluorene units. The structural, optical and electrochemical properties were elucidated by X-ray crystallography, UV-vis absorption and fluorescence spectroscopy, and cyclic voltammetry. By comparison with a shorter analogue, we show how the electronic properties of [5]-cyclofluorenes are drastically different from those of [4]-cyclofluorenes, highlighting the key role played by the ring size in the cyclofluorene family. 相似文献
740.
Dr. Maxime Debost Dr. Paul B. Klar Dr. Nicolas Barrier Dr. Edwin B. Clatworthy Dr. Julien Grand Dr. Fabien Laine Dr. Petr Brázda Dr. Lukas Palatinus Dr. Nikolai Nesterenko Dr. Philippe Boullay Dr. Svetlana Mintova 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(52):23697-23701
Small-pore zeolites such as chabazite (CHA) are excellent candidates for the selective separation of CO2; however, the current synthesis involves several steps and the use of organic structure-directing agent (OSDA), increasing their cost and energy requirements. We report the synthesis of small-pore zeolite crystals (aluminosilicate) with CHA-type framework structure by direct synthesis in a colloidal suspension containing a mixture of inorganic cations only (Na+, K+, and Cs+). The location of CO2 molecules in the host structure was revealed by 3D electron diffraction (3D ED). The high sorption capacity for CO2 (3.8 mmol g−1 at 121 kPa), structural stability and regenerability of the discreate CHA zeolite nanocrystals is maintained for 10 consecutive cycles without any visible degradation. The CHA zeolite (Si:Al=2) reaches an almost perfect CO2 storage capacity (8 CO2 per unit cell) and high selectivity (no CH4 was adsorbed). 相似文献