三苯基锡(Ⅳ)荒酸盐Ph3SnS2CN(C2H5)2的波谱及结构研究

合成了三苯基锡(Ⅳ)Ⅳ，Ⅳ-二乙基荒酸盐。通过元素分析、红外光谱和核磁共振氢谱对其结构进行了表征。用X-射线单晶衍射测定了该化合物的晶体结构；结果表明，化合物中锡原子呈五配位畸变三角双锥构型。     

退火温度对KDP晶体光学均匀性的影响研究

 研究了磷酸二氢钾（KDP）晶体热退火前后光学均匀性的变化，发现适当温度下退火可以降低KDP晶体的内应力，提高晶体的消光比，从而提高晶体的光学均匀性。实验证明，50℃下退火即可消除部分内应力，110℃下退火可以消除生长鬼影和鬼线。但是,退火温度太高（如170℃）,也可能使晶体的均匀性降低。     

Event generators for η/η’ rare decays into π~+π~-1~+1~- and e~+e~-μ~+μ~-

Study of the rare and forbidden decays of η/η offers a sensitive probe to test fundamental symmetries of quantum chromodynamics and search for new physics beyond the Standard Model. To study the rare decays of η/η to π + π - e + e - , π + π - μ + μ - and e + e - μ + μ - at the BES detector, we developed several event generators based on the vector meson dominant model with finite-width corrections and the pseudoscalar mesons mixing theory. The various distributions from event generators are in good agreement with the theoretical predictions, which indicates that the event generators work very well after implemention in the BES Monte Carlo simulation package. In the BES physics analysis, the performance of the event generators will be improved in accordance with the distributions of different variables of η/η from data and the improvement on the theoretical calculations.     

New tetraphenylpyridinium-baseci luminogens with aggregation-induced emission characteristics

The research on aggregation-induced emission （AIE） has drawn increasing interests in the past decade. With the efforts scientists paid, a variety of AIE systems have been developed, among which the tetraphenylethelene and silole derivatives are the most studied. Development of new AIE systems could further enrich the AIE molecules and promote the development of AIE area. In this communication, we prepared a new AIE system based on 1,2,4,6-tetraphenylpyridinium ions according to the restriction of intramolecular rotation mechanism. These molecules could be facilely synthesized via one-step and one-pot reaction. The ionic AIE-active molecules could find wide application in sensing and optoelectronic areas.     

硫杂吡啶番的合成和X射线结构分析

采用与文献不同的方法，在同一反应中同时得到了2，11-二硫[3．3]（3，5）吡啶番、2，11，20-三硫[3．3．3]（3，5）吡啶番和2,11，20，29-四硫[3．3．3．3]（3，5）吡啶番，通过^1H NMR、MS以及X射线晶体结构分析确定了其结构；丰富了吡啶番类化合物和与其形成配位化合物的结构和物性上的知识，为这些新型化合物的进一步研究提供了新的理论依据。     

L-脯氨酸催化的不对称Aldol缩合反应实验设计

介绍了L-脯氨酸催化的对硝基苯甲醛与丙酮的不对称Aldol反应的实验设计。室温反应2 h后，柱层析得到（R）-4-（4-硝基苯基）-4-羟基-2-丁酮，利用手性高效液相色谱测试得到产物的ee值。学生实验结果显示，收率范围为53%~74%，对映选择性范围为62%~69%。本实验方案将Aldol反应的研究成果设计成综合性实验，不仅强化训练了学生基本的实验技能和操作，同时拓宽了知识面，培养了学生分析问题、解决问题等方面的综合能力。     

Effect of deuteron density distribution on the deduction of screening potential from the D(d,p)T reaction in Be metals

The D(d,p)T reaction in Be metal environments has been measured to investigate the electron screening effect in metals in an energy region of from 5.5 keV to 10 keV in a center of mass system(CMS)at a temperature of 121 K.The depth distribution of deuteron density in Be metals has an impact on the observed reaction yields.A model of deuteron density distribution in metal has been proposed to obtain the original yields.A screening energy of(116±46)eV has been obtained with the assumed deuteron density distribution model.     

毛细管电泳非接触电导法测定4种中枢神经系统用药

运用毛细管电泳非接触式电导检测方法对4种中枢神经系统用药-盐酸阿扑吗啡、氢溴酸加兰他敏、富马酸喹硫平、氯氮平的分离进行了研究。考察了电泳介质的种类、浓度、分离电压、进样时间对分离效果的影响,在10 mmol/L三羟基氨基甲烷(Tris)-8 mmol/L柠檬酸(Cit)-20%甲醇的运行缓冲液中,激发电压为60V,激发频率为600kHz,4种药物在15 min内得到了分离。4种药物的线性范围分别为0.97～15.6 mg/L;0.97～15.6 mg/L;0.48～15.6 mg/L和0.97～250 mg/L,检测限为0.32,0.32,0.16和0.32 mg/L。     

Photolyses of mammalian carboxy-hemoglobin studied by photoacoustic calorimetry

The enthalpy and conformational volume changes in the photolyses of carboxy-hemoglobin (HbCO) of human, bovine, pig, horse and rabbit are investigated by photoacoustic calorimetry. Considering the time scales of the exciting laser pulse and the receiving ultrasound transducers (PVDF films and PZT ceramics), as well as the reaction lifetimes in the photolysis processes of HbCO, the measured results are related to the geminate recombination and tertiary relaxation in photolyses of HbCO. Moreover, the quantum yields of the five mammals are also measured by laser pump-probe technique. The results show that the dynamic parameters, such as enthalpy and conformational volume changes, differ between the processes of the geminate recombination and tertiary relaxation. Also, the dynamic parameters differ among the five mammals although some of them may be consistent with each other.     

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Different ratios of methane/air in the low power arc discharges assisted methane combustion were studied at atmospheric pressure. Plasma emission spectroscopy was recorded by an optical emission spectrometer. The possible physical and chemical reaction process and mechanisms were discussed. With a plasma in the on or off state, the physical appearances of the methane combustion flame were observed and compared, the temperature of the flame in the main combustion zone was investigated. The gas compositions of CH₄, CO and O₂ were analyzed by the gas chromatography and flue gas analyzer. The results showed that when plasma was in the on state, the temperature of flame increased and the combustion efficiency enhanced in stable combustion due to decrease of CH₄, CO and O₂; the combustion enhancement was more obvious at low ratio of methane/air; the rich combustion limits in terms of the ratio of methane/air was extended from 16% to 21%.