Negative molecular ions of azafullerenes and their hydrogenated derivatives

The formation and decay of negative molecular ions of azafullerenes and their hydrogenated derivatives are investigated by mass spectrometry. The mechanisms of resonant electron capture and the lifetimes of negative molecular ions with respect to the electron autodetachment in azafullerene molecules are discussed. A comparative analysis of the data obtained for azafullerenes and hydrogenated fullerene derivatives is carried out.     

A simplified method of computing the process of opening of a parachute

We propose a simplified method of determining the integral characteristics of the opening of a parachute which makes it possible to compute the maximal stress on a parachute and the trajectory parameters of the motion of the load in the region of the opening of the parachute, and to determine the size of the portion of the canopy at the time of maximal stress.Translated fromDinamicheskie Sistemy, No. 6, 1987, pp. 38–41.     

An expedient route to diaza-spirocycles utilizing a sequential multicomponent α-aminoallylation/ring-closing metathesis strategy

A general method for the preparation of diaza-spirocycles is reported. This method used an olefin metathesis in order to construct the desired spirocyclic framework. Beginning with commercially available protected amino ketones, this strategy ultimately produced pharmacologically relevant diaza-scaffolds in an efficient and high-yielding process.     

A Class of C ·0-Contractions: Hyperinvariant Subspaces and Intertwining Operators

We consider a class of C_·0-contractions that is a generalization of the class of C_·0-contractions with finite defect indices. Some results of Uchigama and Wu for C_·0-contractions with finite defect indices are generalized: the lattices of hyperinvariant subspaces of such a contraction T is isomorphic to that of its Jordan model and is generated by subspaces of the form Ker ϕ(T) and Ran ϕ(T), where ϕ ∈ H^∞. The form of the inverse to an isomorphism of the invariant subspace lattices given by an intertwining quasiaffinity is also studied. Next, for C_·0-contractions in question, the characteristic disc related to the lattice of invariant subspaces is computed. Bibliography: 13 titles. __________ Translated from Zapiski Nauchnykh Seminarov POMI, Vol. 315, 2004, pp. 48–62.     

Effect of Alkali Metal Cation on Copolymerization of Acrylamide with Salts of 2-Acrylamido-2-methylpropanesulfonic Acid in Aqueous Solutions

The kinetics of radical copolymerization of acrylamide with lithium, sodium, and potassium 2-acrylamido-2-methylpropanesulfonates in concentrated aqueous solutions in the presence of potassium persulfate as initiating agent at pH 9 and 50°C was studied by dilatometry.     

The application of a vehicle routing model to a waste-collection problem: two case studies

In this paper we suggest a unique model for estimating the operating cost of each of three waste-collection systems. Under the traditional system, which is widely used, waste is typically collected in plastic bags and a three-man crew is needed on each vehicle. The other two systems require a one-man crew for vehicle collecting street containers. The side-loader system with fixed body automatically empties street containers into the vehicle body and empties the load at the disposal site. The side-loader system with demountable body allows the separation of the waste collection phase from transport to the disposal site, since the vehicle body can be demounted. We also present two case studies and show how the estimation of operating costs is a critical issue in decisions regarding the type of system to be used for waste collection.     

Contact Interaction of Two Elastic Wedges

We consider the problem of contact of two elastic wedges and assume that only the vertices of the wedges touch before loading. After loading, the edges of both wedges come in contact near their common vertex. We reduce the constructed system of dual integral equations to a Fredholm integral equation of the second kind with difference kernel given on the semiaxis. We analytically solve the Fredholm equation by reducing it to the boundary-value Riemann problem for analytic functions. We obtain an analytic expression for contact stresses.     

The study and applications of photochemical-dynamical gravity wave model II

A nonlinear, compressible, non-isothermal gravity wave model that involves photochemistry is used to study the effects of gravity wave on atmospheric chemical species distributions in this paper. The changes in the distributions of oxygen compound and hydrogen compound density induced by gravity wave propagation are simulated. The results indicate that when a gravity wave propagates through a mesopause region, even if it does not break, it can influence the background distributions of chemical species. The effect of gravity wave on chemical species at night is larger than in daytime.     

A NOTE ON FINITE DIFFERENCE ESTIMATION OF ACOUSTIC PARTICLE VELOCITY

The influence of instrumentation amplitude and phase mismatch on finite difference measurement of mean square particle velocity is examined. It is shown theoretically and demonstrated experimentally that the resulting error depends on two properties of the sound field, the ratio of the active intensity to the mean square particle velocity and the ratio of the reactive intensity to the mean square particle velocity. Very large errors can occur near particle velocity nodes in interference fields even with well-matched state-of-the-art sound intensity measurement systems. However, outside of such regions, moderate phase mismatch has very little influence on the performance of the measurement system. Amplitude mismatch is somewhat more problematic.