全文获取类型
收费全文 | 193篇 |
免费 | 0篇 |
专业分类
化学 | 91篇 |
晶体学 | 1篇 |
力学 | 5篇 |
数学 | 45篇 |
物理学 | 51篇 |
出版年
2021年 | 5篇 |
2020年 | 3篇 |
2019年 | 4篇 |
2018年 | 6篇 |
2017年 | 3篇 |
2016年 | 8篇 |
2015年 | 2篇 |
2014年 | 4篇 |
2013年 | 10篇 |
2012年 | 2篇 |
2011年 | 5篇 |
2010年 | 6篇 |
2009年 | 3篇 |
2008年 | 5篇 |
2007年 | 2篇 |
2006年 | 5篇 |
2005年 | 3篇 |
2004年 | 3篇 |
2003年 | 4篇 |
2002年 | 7篇 |
2001年 | 4篇 |
2000年 | 6篇 |
1999年 | 4篇 |
1998年 | 4篇 |
1997年 | 1篇 |
1996年 | 5篇 |
1995年 | 1篇 |
1994年 | 8篇 |
1993年 | 4篇 |
1992年 | 4篇 |
1991年 | 3篇 |
1990年 | 1篇 |
1988年 | 2篇 |
1987年 | 7篇 |
1986年 | 1篇 |
1985年 | 8篇 |
1984年 | 1篇 |
1983年 | 3篇 |
1982年 | 4篇 |
1981年 | 2篇 |
1980年 | 4篇 |
1979年 | 3篇 |
1978年 | 2篇 |
1977年 | 5篇 |
1976年 | 2篇 |
1975年 | 5篇 |
1974年 | 3篇 |
1973年 | 1篇 |
1971年 | 2篇 |
1967年 | 3篇 |
排序方式: 共有193条查询结果,搜索用时 31 毫秒
151.
N. A. Pankrushina A. G. Druganov I. Yu. Bagryanskaya Yu. V. Gatilov V. A. Raldugin M. M. Shakirov E. V. Evtushenko V. A. Saprykin 《Chemistry of Natural Compounds》1994,29(4):479-483
1,2-Epoxygibberellin A3 has been obtained for the first time in almost quantitative yield by the dehydroiodination of the known 1-iodogibberellin A56, and the structure of its molecule has been established by the XSA method. An interpretation of all the signals in its1H and13C spectra has been made from the results of two-dimensional NMR. In the amylase biotest, 1,2-epoxgibberellin A3 exhibited an activity amounting to one third of the activity of gibberellin A3 at concentrations of 10–7 to 10–9 M.Novosibirsk Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences. Institute of Cytology and Genetics, Siberian Branch, Russian Academy of Sciences, Novosibirsk. Translated from Khimiya Prirodnykh Soedinenii, No. 4, pp. 549–553, July–August, 1993. 相似文献
152.
A. A. Efimova F. D. Mulashkin G. N. Rudenskaya E. G. Evtushenko V. N. Orlov N. S. Melik-Nubarov G. G. Krivtsov A. A. Yaroslavov 《Polymer Science Series B》2018,60(1):84-90
Using the electrostatic adsorption of anionic liposomes on the surface of cationic microparticles of ion-crosslinked chitosan, complexes in which each microparticle can bind up to 110 intact (undestroyed) liposomes are prepared. The saturated complex 350–400 nm in diameter does not dissociate to initial components in aqueous solutions with pH 7 and a NaCl concentration of 0.15 mol/L, but decomposes to 10-nm particles in the presence of proteolytic enzymes. The chitosan–liposome complex and its biodegradation products are characterized by a low cytotoxicity. The described technique may be used to obtain biodegradable multiliposomal containers for the encapsulation and delivery of drugs. 相似文献
153.
G. I. Gurina V. D. Evtushenko V. M. Verkhovod V. M. Koshkin 《Theoretical and Experimental Chemistry》1985,21(1):118-121
IR and diffuse-reflection spectroscopy have been used to detect the concentration threshold in intercalation, whose temperature dependence has been examined for systems composed of PbI2 with solutions of aniline and quinoline in benzene. The thermodynamic nature of the threshold has been established, and it is found that the penetration of the organic molecules between the layers involves the formation of an order intercalation phase. The enthalpies and entropies of formation have been calculated for the intercalation compounds. It is found that intercalation leads in the main to changes in the vibrational bands of the amino group, which indicates that it participates in forming the bond between the amine and the inorganic layered matrix.Translated from Teoreticheskaya i Éksperimental'naya Khimiya, Vol. 21, No. 1, pp. 123–127, January–February, 1985. 相似文献
154.
I. A. Gritskova V. S. Papkov I. G. Krasheninnikova A. M. Evtushenko 《Polymer Science Series A》2007,49(3):235-241
The heterophase polymerization of styrene has been carried out in the presence of surfactants—organosilicon compounds with different solubilities in aqueous and styrene phases and surface activities at the interface. It has been demonstrated that the stability of polymer suspensions prepared with water-insoluble organosilicon compounds is much higher than that in the presence of organosilicon surfactants soluble in organic and aqueous phases. In the former case, suspensions with narrower particle-size distributions are produced. The stability of polymer microspheres prepared at various monomer-to-water volume ratios has been tested. An increase in the monomer concentration above 25 vol % leads to the loss of system stability. 相似文献
155.
Analytical reactions for the determination of epoxy and isocyanate groups in the presence of each other in epoxy–isocyanate compositions were studied. For the determination of epoxy groups in the presence of isocyanate groups, a test with HBr in glacial acetic acid was proposed; acetic acid reacts with isocyanate groups and, hence, masks them. Isocyanate groups in the presence of epoxy groups were determined by potentiometric titration with a solution of piperidine in ethyl methyl ketone. The addition of toluene to the test solution decreases the fraction of the enol form of ethyl methyl ketone, which interferes with the determination. 相似文献
156.
A method is described for obtaining the methyl ethers of methyl -L-arabinopyranoside that is based on the partial methylation of methyl -L-arabinopyranoside followed by the liquid chromatography of the methyl ethers. The13C NMR spectra of the methyl ethers of methyl -L-arabinopyranoside have been studied.Pacific Ocean Institute of Bioorganic Chemistry, Far Eastern Scientific Center, Academy of Sciences of the USSR, Vladivostok. Translated from Khimiya Prirodnykh Soedinenii, No. 2, pp. 178–181, March–April, 1985. 相似文献
157.
A review is given of materials on the use of the method of gas-liquid chromatography in carbohydrate chemistry.Pacific Ocean Institute of Bioorganic Chemistry, Far Eastern Scientific Center, Academy of Sciences of the USSR, Vladivostok. Translated from Khimiya Prirodnykh Soedinenii, No. 4, pp. 411–428, July–August, 1984. 相似文献
158.
Our results lead to the following conclusions.
The authors are grateful to O. Ipat’eva, A. Kokh, and A. Yurkin of the “Single-Crystal” Collective Technica Institute for
supplying the high-quality high-voltage equipment elements. 相似文献
1. | A CVL with a nonlinear frequency converter can be regarded as a source of high-power UV radiation discretel tunable in three wavelengths. |
2. | The presence of the CVL beam of a low-coherence (single-pass) radiation is one of the main factors that limi the efficiency of the nonlinear conversion. |
159.
Application of the Fast Automatic Differentiation Technique for Solving Inverse Coefficient Problems
Albu A. F. Evtushenko Yu. G. Zubov V. I. 《Computational Mathematics and Mathematical Physics》2020,60(1):15-25
Computational Mathematics and Mathematical Physics - Results obtained by the authors in solving inverse coefficient problems are overviewed. The inverse problem under consideration is to determine... 相似文献
160.
Alexander V. Bulgakov Anton B. Evtushenko Yuri G. Shukhov Igor Ozerov Wladimir Marine 《Applied Physics A: Materials Science & Processing》2010,101(4):585-589
Neutral and cationic Zn
n
O
m
clusters of various stoichiometry have been produced by nanosecond laser ablation of ZnO in vacuum and investigated by time-of-flight
mass spectrometry. Particular attention was paid to the effect of laser wavelength (in the range from near-IR to UV) on cluster
composition. Under 193-nm laser ablation, the charged clusters are essentially substoichiometric with ZnnOn-1+\mathrm{Zn}_{n}\mathrm{O}_{n-1}^{+} and ZnnOn-3+\mathrm{Zn}_{n}\mathrm{O}_{n-3}^{+} being the most abundant series. Both sub- and stoichiometric cationic clusters are generated in abundance at 532- and 1064-nm
ablation whose composition depends on the cluster size. The reactivity of small stoichiometric ZnnOn+\mathrm{Zn}_{n}\mathrm{O}_{n}^{+} clusters (n<11) toward hydrogen is found to be high, while oxygen-deficient species are less reactive. The neutral plume particles are
mainly stoichiometric with Zn4O4 tetramer being a magic cluster. It is suggested that the Zn4O4 loss is the dominant fragmentation channel of large zinc oxide clusters upon electron impact. Plume expansion conditions
under ZnO ablation with visible and IR laser pulses are shown to be favorable for stoichiometric cluster formation. 相似文献