全文获取类型
收费全文 | 192篇 |
免费 | 5篇 |
国内免费 | 5篇 |
专业分类
化学 | 99篇 |
晶体学 | 1篇 |
数学 | 62篇 |
物理学 | 40篇 |
出版年
2021年 | 4篇 |
2020年 | 3篇 |
2019年 | 4篇 |
2018年 | 1篇 |
2017年 | 4篇 |
2016年 | 4篇 |
2015年 | 3篇 |
2014年 | 4篇 |
2013年 | 9篇 |
2012年 | 7篇 |
2011年 | 7篇 |
2010年 | 13篇 |
2009年 | 11篇 |
2008年 | 12篇 |
2007年 | 18篇 |
2006年 | 10篇 |
2005年 | 20篇 |
2004年 | 7篇 |
2003年 | 13篇 |
2002年 | 6篇 |
2001年 | 5篇 |
2000年 | 5篇 |
1999年 | 7篇 |
1998年 | 9篇 |
1997年 | 2篇 |
1996年 | 1篇 |
1995年 | 2篇 |
1994年 | 3篇 |
1985年 | 2篇 |
1984年 | 2篇 |
1981年 | 1篇 |
1979年 | 2篇 |
1977年 | 1篇 |
排序方式: 共有202条查询结果,搜索用时 15 毫秒
11.
Dmitri Vassiliev 《General Relativity and Gravitation》2002,34(8):1239-1265
In abstract Yang–Mills theory the standard instanton construction relies on the Hodge star having real eigenvalues which makes it inapplicable in the Lorentzian case. We show that for the affine connection an instanton-type construction can be carried out in the Lorentzian setting. The Lorentzian analogue of an instanton is a spacetime whose connection is metric compatible and Riemann curvature irreducible (pseudoinstanton). We suggest a metric-affine action which is a natural generalization of the Yang–Mills action and for which pseudoinstantons are stationary points. We show that a spacetime with a Ricci flat Levi-Civita connection is a pseudoinstanton, so the vacuum Einstein equation is a special case of our theory. We also find another pseudoinstanton which is a wave of torsion in Minkowski space. Analysis of the latter solution indicates the possibility of using it as a model for the neutrino. 相似文献
12.
[reaction: see text] A convenient one-pot synthesis of 4-fluoroquinolinones that are active against KDR kinase is described. The mechanism of the reaction is believed to involve the formation of a quinone methide intermediate. 相似文献
13.
Transient isotopic experiments reveal that the mechanism of N2O formation in the high-temperature NH3 oxidation over Pt-Rh gauze involves the reaction of adsorbed ammonia intermediate species (NHx) and NO. 相似文献
14.
15.
Evgueni Riaplov John P Maier Dietmar Panten Pavel Rosmus 《Journal of Molecular Spectroscopy》2003,222(1):15-21
Mass selected C2S− ions have been co-deposited with neon to grow a matrix at 6 K. The and electronic absorption spectra of the linear CCS− anion have been identified with origin band at 10 606 and 22 273 cm−1, respectively. After exposure to UV radiation a new electronic transition of CCS is observed (origin band at 30 563 cm−1) in addition to its known band system. Ab initio calculations provide support for the symmetry assignment of the upper electronic states of CCS−, CCS and of the vibrational structure in the spectra. 相似文献
16.
The reaction between C3H8 and N2O over steam-activated FeMFI zeolites leads to high yields towards propene (24%) and propionaldehyde (6%) at 773-798 K. 相似文献
17.
We study the theory of lovely pairs of geometric structures, in particular o-minimal structures. We use the pairs to isolate a class of geometric structures called weakly locally modular which generalizes the class of linear structures in the settings of SU-rank one theories and o-minimal theories. For o-minimal theories, we use the Peterzil-Starchenko trichotomy theorem to characterize for a sufficiently general point, the local geometry around it in terms of the thorn U-rank of its type inside a lovely pair. 相似文献
18.
The structural properties of a-Al2O3/Ge, a-Al2O3/In0.5Ga0.5As and a-Al2O3/In0.5Al0.5As/InGaAs interfaces were investigated by density-functional theory (DFT) molecular dynamics (MD) simulations. Realistic a-Al2O3 samples were generated using a hybrid classical-DFT MD “melt and quench” approach. The interfaces were formed by annealing at 700 K/800 K and 1100 K with subsequent cooling and relaxation. The a-Al2O3/Ge interface demonstrates pronounced interface intermixing and interface bonding exclusively through Al–O–Ge bonds generating high interface polarity. In contrast, the a-Al2O3/InGaAs interface has no intermixing, Al–As and O–In/Ga bonding, low interface polarity due to nearly compensating interface dipoles, and low substrate deformation. The a-Al2O3/InAlAs interface demonstrated mild intermixing with some substrate Al atoms being adsorbed into the oxide, mixed Al–As/O and O–Al/In bonding, medium interface polarity, and medium substrate deformation. The simulated results demonstrate strong correlation to experimental measurements and illustrate the role of weak bonding in generating an unpinned interface for metal oxide/semiconductor interfaces. 相似文献
19.
Bishop SR Clemens JB Chagarov EA Shen J Kummel AC 《The Journal of chemical physics》2010,133(19):194702
Ordered, low coverage to monolayer, high-κ oxide adsorption on group III rich InAs(0 0 1)-(4×2) and In(0.53)Ga(0.47)As(0 0 1)-(4×2) was modeled via density functional theory (DFT). Initial adsorption of HfO(2) and ZrO(2) was found to remove dangling bonds on the clean surface. At full monolayer coverage, the oxide-semiconductor bonds restore the substrate surface atoms to a more bulklike bonding structure via covalent bonding, with the potential for an unpinned interface. DFT models of ordered HfO(2)/In(0.53)Ga(0.47)As(0 0 1)-(4×2) show it fully unpins the Fermi level. 相似文献
20.
Clemens JB Chagarov EA Holland M Droopad R Shen J Kummel AC 《The Journal of chemical physics》2010,133(15):154704
The reaction of trimethyl aluminum on the group III rich reconstructions of InAs(0 0 1) and In(0.53)Ga(0.47)As(0?0?1) is observed with scanning tunneling microscopy/spectroscopy. At high coverage, a self-terminated ordered overlayer is observed that provides the monolayer nucleation density required for subnanometer thick transistor gate oxide scaling and removes the surface Fermi level pinning that is present on the clean InGaAs surface. Density functional theory simulations confirm that an adsorbate-induced reconstruction is the basis of the monolayer nucleation density and passivation. 相似文献