全文获取类型
收费全文 | 901篇 |
免费 | 53篇 |
国内免费 | 6篇 |
专业分类
化学 | 640篇 |
晶体学 | 7篇 |
力学 | 9篇 |
数学 | 115篇 |
物理学 | 189篇 |
出版年
2024年 | 2篇 |
2023年 | 8篇 |
2022年 | 21篇 |
2021年 | 36篇 |
2020年 | 35篇 |
2019年 | 44篇 |
2018年 | 41篇 |
2017年 | 25篇 |
2016年 | 52篇 |
2015年 | 34篇 |
2014年 | 36篇 |
2013年 | 67篇 |
2012年 | 79篇 |
2011年 | 85篇 |
2010年 | 30篇 |
2009年 | 35篇 |
2008年 | 61篇 |
2007年 | 51篇 |
2006年 | 57篇 |
2005年 | 48篇 |
2004年 | 28篇 |
2003年 | 18篇 |
2002年 | 15篇 |
2001年 | 6篇 |
2000年 | 6篇 |
1999年 | 12篇 |
1998年 | 3篇 |
1997年 | 2篇 |
1996年 | 6篇 |
1995年 | 2篇 |
1994年 | 2篇 |
1993年 | 2篇 |
1992年 | 1篇 |
1991年 | 1篇 |
1986年 | 2篇 |
1985年 | 3篇 |
1984年 | 1篇 |
1982年 | 2篇 |
1981年 | 1篇 |
排序方式: 共有960条查询结果,搜索用时 93 毫秒
111.
Francisco Álvarez Christopher White Ashvin Kumar Narayana Swamy Evgeny Shafirovich 《Proceedings of the Combustion Institute》2013,34(2):2245-2252
Combustion of lunar regolith mixed with energetic additives is a potential method for production of construction materials in future moon missions. Recently, self-sustained combustion in the mixtures of JSC-1A lunar regolith and magnesium has been demonstrated. However, the concentration of magnesium in those mixtures was as high as 26 wt%. Note that magnesium must be either transported from Earth or recovered from lunar minerals or used structures. The present paper focuses on the minimization of magnesium content in JSC-1A/Mg mixtures. The mixtures were compacted into pellets and ignited in argon environment. Initial attempts to decrease magnesium concentration resulted in the observations of a spinning combustion wave at 23 wt% Mg. The observed spin combustion involved periodical motion of two counterpropagating hot spots along a helical path on the sample surface. These observations, including features such as formation of a faster hot spot after collision of the counterpropagating spots, confirm theoretical predictions for spin combustion in solid–solid mixtures. High-energy mechanical milling of JSC-1A in a planetary ball mill significantly increased its reactivity and improved combustion of its mixtures with magnesium. Mixtures of the obtained powder (the median diameter of about 3 μm) with 26 wt% Mg exhibit easy ignition and vigorous combustion. The minimum concentration of magnesium required for self-sustained propagation of a planar combustion front is as low as 13 wt%. 相似文献
112.
Mark Lenkewitz Evgeny Epelbaum H. -W. Hammer Ulf-G. Meißner 《The European Physical Journal A - Hadrons and Nuclei》2013,49(2):1-11
We calculate the electromagnetic neutral pion production off tri-nucleon bound states (3H, 3He) at threshold in chiral nuclear effective field theory to fourth order in the standard heavy baryon counting. We show that the fourth-order two-nucleon corrections to the S-wave multipoles at threshold are very small. This implies that a precise measurement of the S-wave cross section for neutral pion production off 3He allows for a stringent test of the chiral perturbation theory prediction for the S-wave electric multipole $E_{0+}^{\pi^0 n}$ . 相似文献
113.
Evgeny M. Buev Anastasia A. Smorodina Vladimir S. Moshkin Vyacheslav Y. Sosnovskikh 《Tetrahedron letters》2019,60(9):649-652
Nonstabilized azomethine ylides react with 4-arylidene-2-phenyloxazol-5(4H)-ones to form diazaspiro[4.4]nonenes, which were hydrolyzed to aryl cucurbitine derivatives in 35–67% overall yield. 相似文献
114.
Yuliya S. Rozhkova Irina V. Plekhanova Alexey A. Gorbunov Olga G. Stryapunina Evgeny N. Chulakov Victor P. Krasnov Marina A. Ezhikova Mikhail I. Kodess Pavel A. Slepukhin Yurii V. Shklyaev 《Tetrahedron letters》2019,60(11):768-772
A new approach for the synthesis of functionalized racemic 3,4-dihydroferroceno[c]pyridines via the Ritter reaction of 2-methyl-1-ferrocenylpropan-1-ol with nitriles in the presence of methansulfonic acid was developed. The scope and limitations of the reaction were evaluated. Selected racemic 3,4-dihydroferroceno[c]pyridines were successfully separated by preparative HPLC on a Chiralcel OD-H column. The absolute configuration of the enantiomers was determined by X-ray crystal structure analysis. 相似文献
115.
Kristina O. Kvashnina Anna Yu. Romanchuk Ivan Pidchenko Lucia Amidani Evgeny Gerber Alexander Trigub Andre Rossberg Stephan Weiss Karin Popa Olaf Walter Roberto Caciuffo Andreas C. Scheinost Sergei M. Butorin Stepan N. Kalmykov 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2019,131(49):18044-18044
116.
Gazizov Denis A. Fedotov Victor V. Gorbunov Evgeny B. Ulomskiy Evgeny N. Yeltsov Oleg S. Rusinov Gennady L. Rusinov Vladimir L. 《Chemistry of Heterocyclic Compounds》2019,55(6):573-577
Chemistry of Heterocyclic Compounds - Condensation of aminoazoles with (2E)-(3-morpholin-4-yl)acrylonitrile and 3,3-diethoxypropionitrile was used to synthesize a series of... 相似文献
117.
Madhura Bellare Vasantha Krishna Kadambar Paolo Bollella Maria Gamella Evgeny Katz Artem Melman 《Electroanalysis》2019,31(11):2274-2282
His‐tagged molecular species, a ferrocene derivative and Protein A, were immobilized on electrode surfaces (Au and graphite) through formation of a chelated complex in the presence of Cu2+ cations used as bridging units. The complex was cleaved and the attached molecules were released from the electrode surface by applying reductive potential to the electrodes resulting in Cu2+ reduction, thus decomposing the chelate complex. The molecule release process was followed by cyclic voltammetry in case of the ferrocene derivative. His‐tagged Protein A was additionally labeled with a fluorescent tag and its release was followed by fluorescence measurements in the solution and by impedance spectroscopy at the electrode. The studied release of the His‐tagged redox species and biomolecules was considered as a new generic approach to the signal‐controlled molecule release applicable in various biotechnological and biomedical applications. 相似文献
118.
The inverse scattering problem for the one-dimensional Helmholtz wave equation is studied. The equation is reduced to a Fresnel set that describes multiple bulk reflection and is similar to the coupled-wave equations. The inverse scattering problem is equivalent to coupled Gel'fand-Levitan-Marchenko integral equations. In the discrete representation its matrix has T?plitz symmetry, and the fast inner bordering method can be applied for its inversion. Previously the method was developed for the design of fiber Bragg gratings. The testing example of a short Bragg reflector with deep modulation demonstrates the high efficiency of refractive-index reconstruction. 相似文献
119.
Dr. Haixiang Han Jesse C. Carozza Audra P. Colliton Yuxuan Zhang Dr. Zheng Wei Dr. Alexander S. Filatov Prof. Dr. Yu-Sheng Chen Melisa Alkan Prof. Dr. Andrey Yu. Rogachev Prof. Dr. Evgeny V. Dikarev 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(24):9711-9717
A known trinuclear structure was used to design the heterobimetallic mixed-valent, mixed-ligand molecule [CoII(hfac)3−Na−CoIII(acac)3] ( 1 ). This was used as a template structure to develop heterotrimetallic molecules [CoII(hfac)3−Na−FeIII(acac)3] ( 2 ) and [NiII(hfac)3−Na−CoIII(acac)3] ( 3 ) via isovalent site-specific substitution at either of the cobalt positions. Diffraction methods, synchrotron resonant diffraction, and multiple-wavelength anomalous diffraction were applied beyond simple structural investigation to provide an unambiguous assignment of the positions and oxidation states for the periodic table neighbors in the heterometallic assemblies. Molecules of 2 and 3 are true heterotrimetallic rather than a statistical mixture of two heterobimetallic counterparts. Trinuclear platform 1 exhibits flexibility in accommodating a variety of di- and trivalent metals, which can be further utilized in the design of molecular precursors for the NaMM′O4 functional oxide materials. 相似文献
120.
DNA release electrochemically stimulated by applying ?10 mV on the modified electrode was studied. The release process was based on the local (interfacial) pH change produced upon H2O2 reduction electrocatalyzed by the immobilized microperoxidase‐11. SiO2 nanoparticles attached to the electrode surface and functionalized with trigonelline and boronic acid species changed their electrical charge from positive to negative upon the interfacial pH change, thus allowing electrostatic adsorption of negatively charged DNA on the positive interface and then its repulsion/release from the negative interface. The loaded/released DNA molecules were labeled with a fluorescent dye to allow easy detection of the released DNA molecules. The important feature of the developed system is the controlled DNA release upon applying very small electrical potential on the modified electrode. 相似文献