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661.
In this study, the removal of a cationic thiazin dye such as Basic Blue 17 (Toluidin Blue, BB 17) by chemically crosslinked acrylamide (AAm)/acrylic acid sodium salt (AASS) hydrogels was investigated. Super water retainer AAm/AASS hydrogels with various compositions were prepared from ternary mixtures of AAm, AASS and water by free radical polymerization in aqueous solution using multifunctional crosslinkers such as ethylene glycol dimethacrylate (EGDMA), N,N′ methylenebisacrylamide (NMBA), 1,4 butanediol dimethacrylate (BDMA) and trimethylolpropane triacrylate (TMPTA). Adsorption of Basic Blue 17 from aqueous solutions was studied by batch sorption technique at 25°C. The effect of Basic Blue 17 concentration and mass of adsorbent on the dye adsorption were examined. In the experiments of the sorption, C type and L type sorption in the Giles classification system was found. Some binding parameters such as initial binding constant (K i ), equilibrium constant (K), monolayer coverage (n), site-size (u), and maximum fractional occupancy (Ô) for AAm/AASS hydrogel-dye binding system were calculated by using Klotz linearization method. Finally, the amount of sorbed Basic Blue 17 per gram of dry hydrogel (q) was calculated to be 1.96–21.35 μ mol dye per gram for AAm/AASS hydrogels. Adsorption of Basic Blue 17 was changed range 39.17–96.63%. AAm/AASS hydrogels crosslinked by TMPTA, EGDMA, BDMA or NMBA can be used a sorbent in biotechnology, environment, sorption, separation, purification, immobilization and enrichment of some species. 相似文献
662.
If f() is an analytic function from a domain D of the complex plane into a Jordan-Banach algebra we prove that Sp f() is an analytic multivalued function. From this derives the subharmonicity of Log (f()), where denotes the spectral radius. We apply these results to prove that a Jordan-Banach algebra A is associative if and only if the spectral radius is subadditive and submultiplicative on A and to prove that A/Rad A is isomorphic to the complex plane if and only if each element of A has only one point in its spectrum.
Le travail du permier auteur a été subventionné par le Conseil de recherches en sciences naturelles et en génie du Canada (subvention A 7668) 相似文献
Le travail du permier auteur a été subventionné par le Conseil de recherches en sciences naturelles et en génie du Canada (subvention A 7668) 相似文献
663.
Z. Biber H. Özakay P. Ünak F. Yurt 《Journal of Radioanalytical and Nuclear Chemistry》1999,240(1):395-396
Iodide traces in common salts consumed in Turkey have been determined by isotope dilution analysis. Iodide was precipitated
by stoichiometric amount of AgNO3. Iodide-131 was used as tracer. Electrophoresis was performed to separate Ag131I from excess131I−. Zone of Ag131I was cut off electrophoresis paper and counted with a NaI(Tl) scintillation counter. Count rates were plotted versus added
KI concentrations. Unknown iodide amounts were found by using these linear plots. Iodide concentrations found in analyzed
salts were 9–58 μg/g. 相似文献
664.
We obtain lower asymptotic at ∞ estimates of the distance between a maximum modulus point and zero set of an entire function provided that the function is of regular growth with respect to a proximate order. The more regular the growth is the better the estimates are, and they are sharp in some sense. The case of infinite order is also considered; in this case a suitable analogue of usual proximate order is exploited. To cite this article: I. Ostrovskii, E. Üreyen, C. R. Acad. Sci. Paris, Ser. I 341 (2005). 相似文献
665.
Nevin Süleymanoğlu Yasemin Ünver Reşat Ustabaş Şahin Direkel Yelda Bingöl Alpaslan 《光谱学快报》2017,50(2):96-101
Ethyl{4-[3-(1H-imidazole-1-yl)propyl]-3-methyl-5-oxo-4,5-dihydro-1H-1,2,4-triazol-1-yl}-acetate (I) was synthesized as described in the literature and studied by proton and carbon-13 nuclear magnetic resonance, Fourier transform infrared spectroscopic techniques. Theoretical calculations were performed by the density functional method with 6-311G(d,p) and 6-311++G(d,p) basis sets. Structural parameters of compound I, vibrational frequencies, and chemical shift values were determined. The antimicrobial activity of compound I was tested for seven standard bacteria; Staphylococcus aureus, Escherichia coli, Salmonella typhimurium, Yersinia enterocolitica, Listeria monocytogenes, Shigella flexneri, Pseudomonas aeruginosa, and one standard fungi isolate by microdilution broth assay with Alamar Blue Dye. The in vitro results show that compound I has antimicrobial activity against to two standard bacteria, Shigella flexneri and Listeria monocytogenes. And also, the antifungal activity was not detected against selected fungi isolate, Candida tropicalis. 相似文献
666.
Artur Kochanke Christoph Üffing Andreas Hartwig 《Surface and interface analysis : SIA》2019,51(11):1059-1069
Silicone-based materials often contain vinylsiloxane and hydrosiloxane groups for cross-linking by a radical or addition reaction. Such functional groups can influence the interactions with fillers or with surfaces of substrates when used as adhesives. This work examined how these functional groups interact with aluminum oxide surfaces. For this purpose, aluminum oxide powders with large surface areas of 150 m2/g and different acid-base properties were examined. Siloxanes were applied as thin layers to mainly obtain information from the interphase by vibrational spectroscopy. It was observed that vinyl groups show low interactions with aluminum oxide surfaces even at elevated temperatures. In contrast to this, hydrosiloxanes undergo strong interactions and reactions with aluminum oxides already at room temperature. Activated Si─H species were observed as an intermediate state. On the one hand, interactions and reactions might contribute to adhesion, but on the other hand, the cross-linking reaction can be influenced near the surface, leading to lower mechanical strength. 相似文献
667.
In spite of the many unstandardized literature methods for the determination of the antioxidant activity/capacity (AOA/AOC) of food extracts, there are a very limited number of documented voltammetric nanosensors, despite the fact that commercial electrochemical devices for rapid AOA estimation are on the rise. The mechanism of the developed sensor is based on the chemical reduction of hexacyanoferrate(III) to hexacyanoferrate(II) by antioxidants, followed by the decrement of the cathodic current intensity of hexacyanoferrate(III) in proportion to antioxidant concentration. During voltammetric measurements, the surface of the glassy carbon electrode was coated with an o-phenylenediamine-aniline copolymer and gold nanoparticles were accumulated on this electrode surface to increase the conductivity. It was shown that the developed electrode gave a reversible voltammogram for the hexacyanoferrate(III)/(II) redox couple, and that the cathodic peaks due to strong antioxidants having a standard redox potential less than that of this couple (Eo < 0.36 V) continuously emerged at very close peak potentials. Single antioxidants as well as binary–ternary mixtures were analyzed with this electrode using square wave voltammetry. The trolox-equivalent antioxidant capacities of selected antioxidants were evaluated with this electrode. The modified voltammetric sensor allowed precise measurement of the total antioxidant capacity of plant tea samples such as green tea, lime, and coral moss, and was not interfered by the food preservative sulfite. The results of the developed voltammetric sensor were statistically compared with those of a reference differential pulse voltammetry-cupric reducing antioxidant capacity electrochemical method established in literature. 相似文献
668.
Hajnalka Szabó-Szentjóbi Péter Bagi Judit Müller György Tibor Balogh Tünde Tóth Péter Huszthy 《Tetrahedron》2019,75(9):1275-1281
The synthesis of four new enantiopure crown ethers containing a diarylphosphinic acid unit has been carried out. As a continuation of our work in this field, the enantioselective transport ability of these ligands for chiral amines has been studied in an aqueous source phase/lipophilic organic bulk liquid membrane/aqueous receiving phase system controlled by the pH of the media. By altering the structures of the carriers we improved the enantioselectivity of the transport. 相似文献
669.
The photoinitiated and cerium(III)-catalyzed aqueous reaction between sulfite ion and oxygen has been studied in a diode-array spectrophotometer using the same light beam for excitation and detection. Cerium(III) is identified as the photoactive absorbing species, and the production of cerium(IV) initiates a radical chain reaction. To interpret all the experimental findings, a simple scheme is proposed, in which the additional chain carriers are sulfite ion radical (SO3(-.)), sulfate ion radical (SO4(-.), and peroxomonosulfate ion radical (SO5(-.). The overall rate of oxidation is proportional to the square root of the light intensity per unit volume, which is readily interpreted by the second-order termination reaction of the proposed scheme. It is also shown that the reaction proceeds for an extended period of time in the dark following illumination, and a quantitative analysis is presented for this phase as well. The postulated model predicts that cerium(III) should have a cocatalytic or synergistic effect on the autoxidation of sulfite ion in the presence of other catalysts. This prediction was confirmed in the iron(III)-sulfite ion-oxygen system. The experimental method and the mathematical treatment used might be applicable to a wide range of photoinduced chain reactions. 相似文献
670.