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151.
Eva Hoffmann GyÖrgy Marko-Varga Istvan Csiky Jan Årke JÖnsoon 《International journal of environmental analytical chemistry》2013,93(1-3):161-171
Abstract A three-column ion chromatographic system for the removal of humic substances from natural waters, and subsequent on-line concentration and determination of nitrate and sulfate using non-suppressed ion chromatography is presented. Humic substances are removed using disposable adsorption columns packed with chemically bonded amine silica material. The sample is directly transfered to an ion exchange column where the anions are concentrated ca 10 times. After reversing the flow, the ions are transferred to a third column where they are separated and quantified. The detection limit is less than 1 mg L?1 of nitrate or sulfate in water containing 45mgL?1 of humic acid. 相似文献
152.
Two glasses, the first one with the composition of Li2O·2SiO2 and the second one with the addition of CaO, P2O5 and CaF2 in the stoichiometric ratio corresponding to fluoroapatite were prepared and their tendency to crystallize has been studied
by non-isothermal DTA analysis. The values of kinetic parameters calculated using the isoconversional integral method have
been used to determine the temperature dependencies of both the length of isothermal induction period and the length of overall
isothermal crystallization for both glasses. The estimated dependencies indicate that the glass containing CaO, P2O5 and CaF2 has a lower thermal stability. 相似文献
153.
154.
A rapid conversion of aldehydes to corresponding nitriles has been achieved under microwave irradiation using hydroxylamine and phthalic anhydride or hydroxylamine and Envirocatalyst EPZGR in solvent free conditions. 相似文献
155.
156.
Eva Kanso 《Theoretical and Computational Fluid Dynamics》2010,24(1-4):201-207
We present a set of equations governing the motion of a body due to prescribed shape changes in an inviscid, planar fluid with nonzero vorticity. The derived equations, when neglecting vorticity, reduce to the model developed in Kanso et al. (J Nonlinear Sci 15:255–289, 2005) for swimming in potential flow, and are also consistent with the models developed in Borisov et al. (J Math Phys 48:1–9, 2007), Kanso and Oskouei (J Fluid Mech 800:77–94, 2008), Shasikanth et al. (Phys Fluids 14(3):1214–1227, 2002) for a rigid body interacting dynamically with point vortices. The effects of cyclic shape changes and the presence of vorticity on the locomotion of a submerged body are discussed through examples. 相似文献
157.
Dr. Jingjun Hao Prof. Arnold L. Rheingold Marzieh Kavand Dr. Kipp J. van Schooten Prof. Christoph Boehme Dr. Marçal Capdevila‐Cortada Prof. Juan J. Novoa Eva Wöss Prof. Günther Knör Prof. Joel S. Miller 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(35):12312-12315
The reaction of 2,3,5,6‐tetracyanopyridine (TCNPy) and Cr(C6H6)2 forms diamagnetic σ‐[TCNPy]22? possessing a 1.572(3) Å intrafragment sp3–sp3 bond. This is in contrast to the structurally related 1,2,4,5‐tetracyanobenzene and 1,2,4,5‐tetracyanopyrazine that form π‐dimer dianions possessing long, multicenter bonds. 相似文献
158.
Analysis of diverse direct arylation polymerization (DArP) conditions toward the efficient synthesis of polymers converging with stille polymers in organic solar cells 下载免费PDF全文
Barry C. Thompson Eva Bundgaard 《Journal of polymer science. Part A, Polymer chemistry》2016,54(18):2907-2918
Despite the emergence of direct arylation polymerization (DArP) as an alternative method to traditional cross‐coupling routes like Stille polymerization, the exploration of DArP polymers in practical applications like polymer solar cells (PSCs) is limited. DArP polymers tend to have a reputation for being marginally inferior to Stille counterparts due to the increased presence of defects that result from unwanted side reactions in direct arylation, such as unselective C‐H bond activation and homocoupling. We report ten DArP protocols across the three major classes of DArP to generate poly[(2,5‐bis(2‐hexyldecyloxy)phenylene)‐alt‐(4,7‐di(thiophen‐2‐yl)benzo[c][1,2,5]thiadiazole)] (PPDTBT). Through evaluation of the method and resulting photophysical and electronic properties, we show not all DArP methods are suitable for generating device‐quality alternating copolymers. When DArP PPDTBT was synthesized in superheated THF with Cs2CO3, neodecanoic acid, and P(o‐anisyl)3, it generated polymers of exceptional quality that performed comparably to Stille counterparts in both roll coated ITO‐free and spin‐coated ITO devices. © 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2016 , 54, 2907–2918 相似文献
159.
N‐(2‐Ethylhexyl)carbazole: A New Fluorophore Highly Suitable as a Monomolecular Liquid Scintillator 下载免费PDF全文
Eva Montbarbon Dr. Fabien Sguerra Dr. Guillaume H. V. Bertrand Élodie Magnier Dr. Romain Coulon Dr. Robert B. Pansu Dr. Matthieu Hamel 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(34):12074-12080
The synthesis, photophysical properties, and applications in scintillation counting of N‐(2‐ethylhexyl)carbazole (EHCz) are reported. This molecule displays all of the required characteristics for an efficient liquid scintillator (emission wavelength, scintillation yield), and can be used without any extra fluorophores. Thus, its scintillation properties are discussed, as well as its fast neutron/gamma discrimination. For the latter application, the material is compared with the traditional liquid scintillator BC‐501 A, and other liquid fluorescent molecules classically used as scintillation solvents, such as xylene, pseudocumene (PC), linear alkylbenzenes (LAB), diisopropylnaphthalene (DIN), 1‐methylnaphthalene (1‐MeNapht), and 4‐isopropylbiphenyl (iPrBiph). For the first time, an excimeric form of a molecule has been advantageously used in scintillation counting. A moderate discrimination between fast neutrons and gamma rays was observed in bulk EHCz, with an apparent neutron/gamma discrimination potential half of that of BC‐501 A. 相似文献
160.
Ralph Chill Eva Fasangová 《Proceedings of the American Mathematical Society》2002,130(3):675-681
We show that a new notion of a spectrum of a function ( is a Banach space), defined by B. Basit and the first author, coincides with the Arveson spectrum of some shift group, provided is uniformly continuous. We apply this result to prove a new version of a tauberian theorem. 相似文献