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81.
Marian Vîrgolici Corneliu Ponta Mihaela Manea Daniel Neguţ Mihalis Cutrubinis Ioan Moise Rareş Şuvăilă Eugen Teodor Costel Sârbu Andrei Medvedovici 《Journal of chromatography. A》2010,1217(12):1977-1987
Research on the chemical composition of fossil resins has evolved during the last decades as a multidisciplinary field and is strongly oriented toward the correlation with their geological and botanical origin. Various extraction procedures and chromatographic techniques have been used together for identifying the volatile compounds contained in the fossil resin matrix. Hyphenation between thermal desorption (TD), gas chromatography (GC) and mass spectrometry detection (MS) has been chosen to investigate the volatile compounds fraction from ambers with a focus on Romanite (Romanian amber) and Baltic amber species. A data analysis procedure was developed for the main purpose of fingerprinting ambers based on the MS identity of the peaks generated by the volatile fraction, together with their relative percentual area within the chromatogram. Chromatographic data analysis was based entirely on Automated Mass Spectral Deconvolution & Identification System (AMDIS) software to produce deconvoluted mass spectra which were used to build-up a mixed mass spectra and relative retention scale library. Multivariate data analysis was further applied on AMDIS results with successful discrimination between Romanite and Baltic ambers. A special trial was conducted to generate pyrolysis “like” macromolecular structure breakdown to volatile compounds by gamma irradiation with a high absorbed dose of 500 kGy. Contrary to our expectations the volatile fraction fingerprints were not modified after irradiation experiments. A complementary non-destructive new approach by ESR spectroscopy was also proposed for discriminating between Romanite and Baltic ambers. 相似文献
82.
We construct generalizations of the Kerr black holes by including higher-curvature corrections in the form of the Gauss-Bonnet density coupled to the dilaton. We show that the domain of existence of these Einstein-Gauss-Bonnet-dilaton (EGBD) black holes is bounded by the Kerr black holes, the critical EGBD black holes, and the singular extremal EGBD solutions. The angular momentum of the EGBD black holes can exceed the Kerr bound. The EGBD black holes satisfy a generalized Smarr relation. We also compare their innermost stable circular orbits with those of the Kerr black holes and show the existence of differences which might be observable in astrophysical systems. 相似文献
83.
A generalized theory of elasticity, taking into account the rotational degrees of freedom of point bodies constituting a continuum, was proposed at the beginning of the twentieth century by the Cosserat brothers. We report the experimental observation of coupled rotational-translational modes in a noncohesive granular phononic crystal. While absent in the classical theory of elasticity, these elastic wave modes are predicted by the Cosserat theory. However the Cosserat theory fails to predict correctly the dispersion of the elastic modes in granular crystals even in the long-wavelength limit. 相似文献
84.
85.
Ion Grosu Lo?c Toupet Gerard Plé Sorin Mager Eugen Mesaros Andreea Varga Elena Bogdan 《Monatshefte für Chemie / Chemical Monthly》2000,54(5):277-286
The synthesis and stereochemistry of new dibrominated spiro-1,3-dioxane derivatives are reported. Investigations by means
of NMR methods and single crystal X-ray diffraction for two compounds revealed the high regio- and diastereoselectivity of
the bromination reaction of some new spiro-1,3-dioxanes and the asymmetric induction of the chiral carbon atom located in
the spiro skeleton. 相似文献
86.
Eugen Borgmann 《Fresenius' Journal of Analytical Chemistry》1883,22(1):58-60
Ohne Zusammenfassung 相似文献
87.
S. L. Molodtsov A. Gutiérrez E. Navas M. Domke G. Kaindl M. Merkel N. Nücker J. Fink V. P. Antropov O. K. Andersen O. Jepsen 《Zeitschrift für Physik B Condensed Matter》1993,92(3):347-351
The electronic structure of K-doped C60 was investigated by photoemission (PE) and X-ray absorption near-edge structure (XANES) studies at the C-1s and K-2p thresholds. In addition, information on the local K-derived partial density of states in superconducting K3C60 was obtained by resonant PE at the K-2p
1/2 threshold. The experimental observations support a complete charge transfer from K to C60 and we clearly observe a finite density of states atE
F
. From resonant PE, occupied states with K-p, d character could be identified in the binding-energy region from 1.5 to 8 eV below, but not directly at the Fermi level. This partial-density-of-states structure agrees well with the results of our band-structure calculations based on the local-density approximation. 相似文献
88.
Eugen J. Ionascu 《Journal of Number Theory》2007,126(1):52-67
In this paper, we study the function H(a,b), which associates to every pair of positive integers a and b the number of positive integers c such that the triangle of sides a, b and c is Heron, i.e., it has integral area. In particular, we prove that H(p,q)?5 if p and q are primes, and that H(a,b)=0 for a random choice of positive integers a and b. 相似文献
89.
D. G. Middleton J. R. M. Annand C. Barbieri P. Barneo P. Bartsch D. Baumann J. Bermuth D. Bosnar H. P. Blok R. Böhm M. Ding M. O. Distler D. Elsner J. Friedrich C. Giusti D. I. Glazier P. Grabmayr S. Grözinger T. Hehl J. Heim W. H. A Hesselink E. Jans F. Klein M. Kohl L. Lapikás I. J. D. MacGregor I. Martin J. C. McGeorge H. Merkel P. Merle F. Moschini U. Müller Th. Pospischil G. Rosner H. Schmieden M. Seimetz A. Süle H. de Vries Th. Walcher D. P. Watts M. Weis B. Zihlmann 《The European Physical Journal A - Hadrons and Nuclei》2006,30(2):469-469
90.