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131.
Eugen Scholz 《Fresenius' Journal of Analytical Chemistry》1980,303(3):203-207
Zusammenfassung Karl Fischer-Reagentien, die SO2 und Amin im üblichen Molverhältnis 12 enthalten, können nur mit Pyridin hergestellt werden. Stark basische Amine bewirken eine rasche Zersetzung der Reagenslösung und einen instabilen Endpunkt. Erhöht man den SO2-Anteil soweit, daß das Molverhältnis SO2Amin mindestens 11 ist, geben auch stark basische Amine hervorragende KF-Reagentien. Sie zeichnen sich durch stabile Endpunkte und hohe Reaktionsgeschwindigkeit aus. Besonders vorteilhaft ist die Anwendung als Zweikomponentenreagens, da beide Komponenten absolut lagerstabil und titerkonstant sind.
Karl Fischer Reagents without pyridine
Summary Karl Fischer-Reagents containing SO2 and amine in the normally applied molar ratio of 12 can be prepared only by using pyridine. Strong basic amines lead to a rapid decomposition of the reagent solution and to an instable endpoint. By raising the SO2-content to a molar ratio SO2amine of 11, even strong basic amines can be applied yielding KF-reagents of superior quality. They are characterized by stable endpoints and a high speed of reaction. Application as a two-solution reagent gives an additional advantage, because the single components are absolutely stable for storage and the titre remains constant.相似文献
132.
The current distribution is investigated theoretically in a shielded superconducting film, which is a film deposited on an insulating superconducting ground plate. An exact result is obtained in the case of a thin and wide film on the basis of London's equation. 相似文献
133.
A short review about nonassociative algebraic systems (mainly nonassociative algebras) and their physical applications is presented. We begin with some motivations, then we give a brief historical overview about the formation and development of the concept of hypercomplex number system and about some earlier applications. The main directions discussed are the octonionic, Lie-admissible, and quasigroup approaches. Also, some problems investigated in Tartu, the octonionic approach, Moufang–Mal'tsev symmetry, and associator quantization are discussed. This review does not pretend to be complete as the accent is placed on ideas and not on the techniques, also the references are quite sporadic (there are many authors and results mentioned in the text without references). 相似文献
134.
Eugen Scholz 《Fresenius' Journal of Analytical Chemistry》1988,330(8):694-697
Summary Karl Fischer titration can be applied to many phenols without any interference, though some are oxidized during titration. One-component reagents are to be preferred because they are less sensitive to interferences. Only pyrogallol and aminophenols are oxidized in this case. With two-component reagents dihydroxybenzenes and naphthols are oxidized, too. With coulometric titration interferences are more frequent. The oxidation rate depends on the pH and can be suppressed or minimised by adding salicylic acid to the Karl Fischer reagent. 相似文献
135.
A sturdy home-built sheathless CE/ESI-QTOF-MS system was developed and optimized for carbohydrate analysis. The interface and employed methodology provided a simple analytical solution to laborious CE/MS interfacing methods and to problems in characterization of complex carbohydrate mixtures that require high-resolution separation of the components. The CE/ESI interface, feasible in any MS laboratory, consists of a one-piece CE column having the CE terminus in-laboratory shaped as a microsprayer and coated with copper. The CE microsprayer was inserted into an in-house made stainless steel clenching device and the whole assembly was mounted onto a quadrupole TOF mass spectrometer. The analytical potential of the interface in terms of suitability, microsprayer performance, copper coat durability, ionization efficiency, spray stability, and sensitivity was tested first on a simple mixture of standard saccharides, which were separated, resolved, and detected with high separation efficiency. The approach was next assessed for the screening of a biological sample, a complex mixture of O-glycosylated sialylated amino acids from urine of a patient suffering from Schindler disease. Preliminary data allow this method to be considered as one of general applicability in structural glycobiology and glycomics and easy to be implemented for proteomic surveys as well. 相似文献
136.
137.
We have observed reactive scattering damage to fundamental DNA building blocks by the type of hyperthermal secondary ions that are produced along heavy ion tracks in biological media. Reactions include carbon abstraction by N+, and hydrogen abstraction by O- and N+, at collision energies down to 1 eV. Our results show that localized reactive scattering by hyperthermal secondary fragments can lead to important physicochemical damage to DNA in cells irradiated by heavy ions. This suggests a fundamentally different picture of nascent DNA damage induced by heavy ion tracks, compared to conventional (x or gamma) radiation tracks. 相似文献
138.
S is a local maximum stable set of a graph G, and we write S∈Ψ(G), if the set S is a maximum stable set of the subgraph induced by S∪N(S), where N(S) is the neighborhood of S. In Levit and Mandrescu (2002) [5] we have proved that Ψ(G) is a greedoid for every forest G. The cases of bipartite graphs and triangle-free graphs were analyzed in Levit and Mandrescu (2003) [6] and Levit and Mandrescu (2007) [7] respectively.In this paper we give necessary and sufficient conditions for Ψ(G) to form a greedoid, where G is:
- (a)
- the disjoint union of a family of graphs;
- (b)
- the Zykov sum of a family of graphs;
- (c)
- the corona X°{H1,H2,…,Hn} obtained by joining each vertex x of a graph X to all the vertices of a graph Hx.
139.
The SmA*–SmC* phase transition was studied by measuring the temperature and electric field dependences of the optical tilt angle, the electric polarisation and the dielectric spectra collected in a wide frequency range. Critical behaviour of the phase transition was analysed by varying the length of the fluorinated part of the alkyl terminal chain and by differing fluorine substitution in the terphenyl core. Both tilt and polarisation show tricritical mean-field behaviour for all homologues with n?>?2. Almost all coefficients that describe the SmA*–SmC* transition in the frame of the Landau theory were derived for homologue series. Double fluorine substitution in the central ring of the core seems to promote the ‘de Vries'-type smectic A*–C* phase transition with a little layer shrinkage. These well correspond with the lower tilt angle and smaller changes of the birefringence at the phase transition compared to the other homologues. 相似文献
140.
Dr. Shu‐Xian Hu M. Sc. Wan‐Lu Li M. Sc. Jun‐Bo Lu Dr. Junwei Lucas Bao Dr. Haoyu S. Yu Prof. Dr. Donald G. Truhlar Dr. John K. Gibson Dr. Joaquim Marçalo Prof. Dr. Mingfei Zhou Prof. Dr. Sebastian Riedel Prof. Dr. W. H. Eugen Schwarz Prof. Dr. Jun Li 《Angewandte Chemie (International ed. in English)》2018,57(12):3242-3245
The concept of oxidation state ( OS ) is based on the concept of Lewis electron pairs, in which the bonding electrons are assigned to the more electronegative element. This approach is useful for keeping track of the electrons, predicting chemical trends, and guiding syntheses. Experimental and quantum‐chemical results reveal a limit near +8 for the highest OS in stable neutral chemical substances under ambient conditions. OS =+9 was observed for the isolated [IrO4]+ cation in vacuum. The prediction of OS =+10 for isolated [PtO4]2+ cations is confirmed computationally for low temperatures only, but hasn't yet been experimentally verified. For high OS species, oxidation of the ligands, for example, of O?2 with formation of .O?1 and O?O bonds, and partial reduction of the metal center may be favorable, possibly leading to non‐Lewis type structures. 相似文献