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111.
Ohne Zusammenfassung 相似文献
112.
Monatshefte für Chemie - Chemical Monthly - 相似文献
113.
Eugen Schilow 《Fresenius' Journal of Analytical Chemistry》1929,76(5-6):212-216
Ohne Zusammenfassung 相似文献
114.
Merkel PB Roh Y Dinnocenzo JP Robello DR Farid S 《The journal of physical chemistry. A》2007,111(7):1188-1199
Quantum yields as high as 120 were achieved for triplet-sensitized photoisomerizations of several Dewar benzene reactants, R, to the corresponding benzene products, P. Considerable chain amplification is maintained even at high conversion. All relevant rate constants of this triplet chain reaction were extracted from laser flash photolysis plus steady-state photolysis experiments. The crucial rate constant ka for adiabatic isomerization of the triplet reactant to triplet product (R* --> P*) cannot be directly measured because it is so large relative to the bimolecular rate of R* formation via sensitization. However, ka was obtained indirectly using a cage/encounter complex model to analyze the competition between the dissociation of encounter pairs with the sensitizer, e.g., S/R* --> S + R*, and the in-cage processes, S/R* --> S/P* --> S*/P, in nonviscous and viscous solvents. These measurements yielded ka values of (approximately 4-9) x 10(9) s(-1), which suggests that only a small (approximately 3 kcal/mol) energy barrier exists along the potential energy surface from R* to P*. Steady-state data indicated that the chain-terminating rate constant R* --> R is negligibly small, an ideal condition for chain amplification. Triplet energy transfer from a series of sensitizers to the Dewar benzene derivatives shows a nonclassical falloff in rate constants with decreasing sensitizer triplet energy, suggesting energy transfer to thermally distorted configurations having lower singlet-triplet energy gaps. As a result of distorted geometries of R* and P*, the chain-propagating energy transfer from P* to R proceeds with a rate constant of only approximately 2 x 10(7) M(-1) s(-1), despite strong exothermicity. The isomerization reaction can release over 100 kcal/kcal of absorbed photons due to the high-energy content of the reactant together with the large chain length. 相似文献
115.
Schmidt A Habeck T Merkel L Mäkinen M Vainiotalo P 《Rapid communications in mass spectrometry : RCM》2005,19(16):2211-2216
Pyrazolium-3-carboxylate and indazolium-3-carboxylate, which belong to the class of pseudo-cross-conjugated mesomeric betaines and which represent the electronically relevant partial structures of the betaine alkaloid Nigellicin, were examined by electrospray ionization mass spectrometry. These compounds decarboxylate to pyrazol-3-ylidene and indazol-3-ylidene. The formation of adducts of these new nucleophilic carbenes under the measurement conditions was examined. 相似文献
116.
S. L. Molodtsov A. Gutiérrez E. Navas M. Domke G. Kaindl M. Merkel N. Nücker J. Fink V. P. Antropov O. K. Andersen O. Jepsen 《Zeitschrift für Physik B Condensed Matter》1993,92(3):347-351
The electronic structure of K-doped C60 was investigated by photoemission (PE) and X-ray absorption near-edge structure (XANES) studies at the C-1s and K-2p thresholds. In addition, information on the local K-derived partial density of states in superconducting K3C60 was obtained by resonant PE at the K-2p
1/2 threshold. The experimental observations support a complete charge transfer from K to C60 and we clearly observe a finite density of states atE
F
. From resonant PE, occupied states with K-p, d character could be identified in the binding-energy region from 1.5 to 8 eV below, but not directly at the Fermi level. This partial-density-of-states structure agrees well with the results of our band-structure calculations based on the local-density approximation. 相似文献
117.
D. I. Glazier M. Seimetz J. R. M. Annand H. Arenhövel M. Ases Antelo C. Ayerbe P. Bartsch D. Baumann J. Bermuth R. Böhm D. Bosnar M. Ding M. O. Distler D. Elsner J. Friedrich S. Hedicke P. Jennewein G. Jover Ma nas F. H. Klein F. Klein M. Kohl K. W. Krygier K. Livingston I. J. D. MacGregor M. Makek H. Merkel P. Merle D. Middleton U. Müller R. Neuhausen L. Nungesser M. Ostrick R. Pérez Benito J. Pochodzalla Th. Pospischil M. Potokar A. Reiter G. Rosner J. Sanner H. Schmieden A. Süle Th. Walcher D. P. Watts M. Weis 《The European Physical Journal A - Hadrons and Nuclei》2005,24(1):101-109
The electric form factor of the neutron, GE,n, has been measured at the Mainz Microtron by recoil polarimetry in the quasielastic D(¯e, e¯n)p reaction. Three data points have been extracted at squared four-momentum transfers Q
2 = 0.3, 0.6 and 0.8 (GeV/c)2. Corrections for nuclear binding effects have been applied.This revised version was published online in March 2005. In the previous version, the email address of one author was inadvertently assigned to multiple authors. 相似文献
118.
Rouven F. Pfleger Sören Schlittenhardt Dr. Marcel P. Merkel Prof. Dr. Mario Ruben Prof. Dr. Karin Fink Dr. Christopher E. Anson Prof. Jesper Bendix Prof. Dr. Annie K. Powell 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(61):15086-15095
We report three structurally related single ion Dy compounds using the pentadentate ligand 2,6-bis((E)-1-(2-(pyridin-2-yl)-hydrazineylidene)ethyl)pyridine (H2dapp) [Dy(H2dapp)(NO3)2]NO3 ( 1 ), [Dy(H2dapp)(OAc)2]Cl ( 2 ) and [Dy(H2dapp)(NO3)2]Cl0.92(NO3)0.08 ( 3 ). The (H2dapp) occupies a helical twisted pentagonal equatorial arrangement with two anionic ligands in the axial positions. Further influence on the electronic and magnetic structure is provided by a closely associated counterion interacting with the central N−H group of the (H2dapp). The slow relaxation of the magnetisation shows that the anionic acetates give the greatest slowing down of the magnetisation reversal. Further influence on the relaxation properties of compounds 1 and 2 is the presence of short nitrate-nitrate intermolecular ligand contact opening further lattice relaxation pathways. 相似文献
119.
Bald I Deng Z Illenberger E Huels MA 《Physical chemistry chemical physics : PCCP》2006,8(10):1215-1222
We report that 10-100 eV Ar+ ion irradiation induces severe damage to the biologically relevant sugar molecules D-ribose and 2-deoxy-D-ribose in the condensed phase on a polycrystalline Pt substrate. Ar+ ions with kinetic energies down to 15 eV induce effective decomposition of both sugar molecules, leading to the desorption of abundant cation and anion fragments, including CH3+, C2H3+, C3H3+, H3O+, CHO+, CH3O+, C2H3O+, H-, O-, and OH-, etc. Use of isotopically labelled molecules (5- 13C D-ribose and 1-D D-ribose) reveals the site specificity for some of the fragment origins, and thus the nature of the chemical bond breaking. It is found that all of the chemical bonds in both molecules are vulnerable to ion impact at energies down to 15 eV, particularly both the endo- and exocyclic C-O bonds. In addition to molecular fragmentation, several chemical reactions are also observed. A small amount of O-/O fragments abstract hydrogen to form OH-. It is found that the formation of the H3O+ ion is related to the hydroxyl groups of the sugar molecules, and is associated with additional hydrogen loss from the parent or adjacent molecules via hydrogen abstraction or proton transfer. The formation of several other cation fragments also requires hydrogen abstraction from its parent or an adjacent molecule. These fragmentations and reactions are likely to occur in a real biomedium during ionizing radiation treatment of tumors and thus bear significant radiobiological relevance. 相似文献
120.
Xavier Balandraud Emil Ernst Eugen Soós 《Zeitschrift für Angewandte Mathematik und Physik (ZAMP)》2005,56(2):304-356
To describe the behavior of Shape Memory Alloy we use a thermomechanical model, founded on a free energy which is a convex function with respect to the strain and to the martensitic volume fraction, and a concave one with respect to the temperature. The material parameters of the model are experimentally determined.Received: November 26, 2001; revised: March 20, 2002 相似文献