WO3薄膜的电致变色特性研究

介绍了ＷＯ３电致变色薄膜的变色机理和制备工艺，对ＷＯ３薄膜的电阻率，结构，化学组玢，电化学特性和变性性能等特性进行了工艺，提出了ＷＯ３薄膜的一种新的锂化方法，这种方法对进一步研制全固态电致变色薄膜器件是十分关键的。     

米散射激光雷达测量大气水平能见度

激光雷达作为一种新型的大气观测工具，可以通过直接探测激光与大气相互作用的光辐射信号来定量地反演大气水平能见度，从而成为测量大气水平能见度的主要手段．正在研制的一台基于532nm波长的车载式米散射激光雷达，用于大气能见度的测量；简单介绍了正在研制的激光雷达的技术参数，给出了测量数据的处理方法；利用雷达的技术参数进行了模拟计算，显示了该激光雷达探测大气水平能见度的可靠性，计算误差显示在大气能见度为10km时该激光雷达的测量误差小于16％．     

钨铈杂多酸及其盐的研究(Ⅰ)——离子交换法制备钨铈杂多酸

用离子交换法制备了三种迄今未见报导的钨铈杂多酸溶液。其阴离子组成分别为[CeW₈O₂₈]^4-、[CeW₁₀O₃₅]^6-和[CeW₁₂WO₄₂]^8-。其中12-钨铈杂多酸制得了稳定的固体,从而揭示了钨饰杂多化合物中一个新的系列--Ce-12W系列。对该固体酸进行了元素分析、红外光谱、电位滴定、X光衍射和差热、热重分析,并对其结构进行了初步探讨。     

光学衍射变换对及其在衍射相位元件设计上的应用

本文提出并证明了瑞利－索末菲衍射积分反演公式，得出一种新的变换对－光学衍射变换对，据此对ＧＳ和ＳＴ算法进行了修正，利用修正算法了设计了衍射相位元件，结果令人满意。     

双视场米散射激光雷达探测对流层气溶胶

介绍了自行研制的用来探测对流层大气气溶胶消光特性的双视场米散射激光雷达.该激光雷达采用两个具有独立接收视场的探测通道分别接收高低层532 nm的大气回波信号,可以兼顾低层大视场角低探测盲区和高层小视场角高探测高度的要求.叙述了该雷达系统的总体结构和技术参量以及数据处理方法,给出了合肥地区(东经117.16°,北纬31.90°)大气气溶胶消光系数廓线和对流层光学厚度的探测结果.测量结果表明,该雷达具备昼夜连续观测对流层大气气溶胶的能力,可以很好地反映气溶胶粒子的时间和空间分布特征.     

Design and Exploration of –SO<Subscript>3</Subscript>H Group Functionalized Brønsted Acidic Ionic Liquids (BAILs) as Task-Specific Catalytic Systems for Organic Reactions: A Review of Literature

For several decades various chemical industries are involved in environment pollution by using hazardous chemicals or excessive use of solvents or catalysts to get maximum amount of desired product. In this case acidic ionic liquids may act as safer substitute of volatile organic solvents/or traditional Brønsted or Lewis acid catalysts with their unique dual task-specific solvent-catalyst properties. Recent surge in the literature review clearly describes the importance, properties and applications of acidic ionic liquids as solvent and efficient reusable catalyst in organic reactions. This review presents an account of some recent reports indicating the synthesis and uses of –SO₃H functionalized ionic liquids(SFILs) as catalyst in organic synthesis.     

2‐Methyl‐1,3‐disulfoimidazolium polyoxometalate hybrid catalytic systems as equivalent safer alternatives to concentrated sulfuric acid in nitration of aromatic compounds

Ionic liquid‐derived polyoxometalate salts [mdsim]₃[PM₁₂O₄₀] (where M = W and Mo) of two heteropolyacids H₃PW₁₂O₄₀.nH₂O and H₃PMo₁₂O₄₀.nH₂O were synthesized using 2‐methyl‐1,3‐disulfoimidazolium chloride ([mdsim][Cl]) ionic liquid and the corresponding heteropolyacids. Three equivalents of [mdsim][Cl] were treated with the respective Keggin‐structured heteropolyacids (one equivalent) in aqueous medium at room temperature to afford the water‐stable ionic polyoxometalates as acidic solids. They were completely characterized using spectroscopic and other analytical techniques including thermal analysis and Hammett acidity studies. The inherent Brønsted acidic properties of ─SO₃H group of these polyoxometalate salts were studied for the nitration of aromatic compounds with 69% HNO₃ at normal temperature and 80°C without use of any external concentrated sulfuric acid. These strongly acidic polyoxometalates display good recyclability and efficient reusability.     

衍射光学元件热稳定性的分析

本文对折射元件和衍射元件的温度特性进行了分析,建立了透镜焦距和衍射效率随环境温度的变化关系,通过施密特红外望远镜系统的设计,比较了折射非球面与衍射光学校正板的温度特性对系统光学传递函数的影响,结果表明衍射光学元件具有较好的热稳定性.     

Orthogonally Complemented Subspaces in Banach Spaces

In this paper, we extend the Moreau (Riesz) decomposition theorem from Hilbert spaces to Banach spaces. Criteria for a closed subspace to be (strongly) orthogonally complemented in a Banach space are given. We prove that every closed subspace of a Banach space X with dim X ≥ 3 (dim X ≤ 2) is strongly orthognally complemented if and only if the Banach space X is isometric to a Hilbert space (resp. strictly convex), which is complementary to the well-known result saying that every closed subspace of a Banach space X is topologically complemented if and only if the Banach space X is isomorphic to a Hilbert space.