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951.
Lépine F Milot S Déziel E He J Rahme LG 《Journal of the American Society for Mass Spectrometry》2004,15(6):862-869
The opportunistic pathogen Pseudomonas aeruginosa produces a large array of 4-hydroxy-2-alkylquinolines (HAQs). These compounds were analyzed by LC/MS, using positive electrospray ionization, in the culture supernatant of strain PA14. Fifty-six HAQs and related compounds were detected and their [M + H](+) ions were further analyzed by collision induced dissociation (CID). These HAQs were grouped into five different series based on the presence of an hydrogen or hydroxyl group at the 3 position, an N-oxide group in place of the quinoline nitrogen, and an unsaturation on their alkyl side chain. Two new analogs of 3,4-dihydroxy-2 heptylquinoline, the Pseudomonas quinolone signal (PQS), were found with an alkyl chain longer by one and two methylene groups. Moreover, two additional series of compounds were identified in which a saturated or unsaturated alkyl side chain is located at the 3 position along with an hydroxyl group at the 3 position and a ketone at the 2 position. No HAQ N-oxides, nor any compounds from the latter two series, were detected in a pqsL mutant derivative of PA14, indicating that this gene is involved in the biosynthesis of these compounds. This work demonstrates the large repertoire of HAQ and HAQ-related compounds produced by P. aeruginosa, and provides insight into N-oxides biosynthesis and confirm the hypothesis that N-oxides are the precursors of compounds from Series 6 and 7. 相似文献
952.
The extended Koopmans’ theorem is related to Fukui function, which measures the change in electron density that accompanies
electron attachment and removal. Two approaches are used, one based on the extended Koopmans’ theorem differential equation
and the other based directly on the expression of the ionized wave function from the extended Koopmans’ theorem. It is observed
that the Fukui function for electron removal can be modeled as the square of the first Dyson orbital, plus corrections. The
possibility of useful generalizations to the extended Koopmans’ theorem is considered; some of these extensions give approximations,
or even exact expressions, for the Fukui function for electron attachment. 相似文献
953.
Shigeru Arimoto 《Journal of mathematical chemistry》2007,41(3):231-269
The present article is the first part of a series devoted to extending the Repeat Space Theory (RST) to apply to carbon nanotubes
and related molecular networks. Four key problems are formulated whose affirmative solutions imply the formation of the initial
investigative bridge between the research field of nanotubes and that of the additivity and other network problems studied
and solved by using the RST. All of these four problems are solved affirmatively by using tools from the RST. The Piecewise
Monotone Lemmas (PMLs) are cornerstones of the proof of the Fukui conjecture concerning the additivity problems of hydrocarbons.
The solution of the fourth problem gives a generalized analytical formula of the pi-electron energy band curves of nanotube
(a, b), with two new complex parameters c and d. These two parameters bring forth a broad class of analytic curves to which the PMLs and associated theoretical devices apply.
Based on the above affirmative solutions of the problems, a central theorem in the RST, called the asymptotic linearity theorem
(ALT) has been applied to nanotubes and monocyclic polyenes. Analytical formulae derived in this application of the ALT illuminate
in a new global context (i) the conductivity of nanotubes and (ii) the aromaticity of monocyclic polyenes; moreover an analytical
formula obtained by using the ALT provides a fresh insight into Hückel’s (4n+2) rule. The present article forms a foundation of the forthcoming articles in this series.
The present series of articles is closely associated with the series of articles entitled ‘Proof of the Fukui conjecture via
resolution of singularities and related methods’ published in the JOMC. 相似文献
954.
We describe the properties of a series of oligomeric polyfluorophores assembled on the DNA backbone. The 11 oligomers (oligodeoxyfluorosides, ODFs), 4-7 monomers in length, were composed of only two fluorescent monomers and a spacer in varied sequences, and were designed to test how fluorescent nucleobases can interact electronically to yield complexity in fluorescence emission. The monomer fluorophores were deoxyribosides of pyrene and perylene, which emit light in violet and blue wavelengths, respectively. The experiments show that simple variation in sequence and spacing can dramatically change fluorescence, yielding emission maxima ranging from 380 to 557 nm and visible colors from violet to orange-red. Fluorescence lifetime data, excitation spectra, and absorption data point to a number of multi-fluorophore electronic interactions, including pyrene-pyrene and perylene-perylene excimers, pyrene-perylene exciplexes, as well as monomer dye emissions, contributing to the final spectral outcomes. Thus, two simple fluorophores can be readily combined to give emissions over much of the visible spectrum, all requiring only a single excitation. The results demonstrate that fluorescent nucleobases in oligomeric form can act cooperatively as electronic units, and that fluorophore sequence in such oligomers is as important as fluorophore composition in determining fluorescence properties. 相似文献
955.
Russell SC Czerwieniec G Lebrilla C Tobias H Fergenson DP Steele P Pitesky M Horn J Srivastava A Frank M Gard EE 《Journal of the American Society for Mass Spectrometry》2004,15(6):900-909
The appearance of informative signals in the mass spectra of laser-ablated bio-aerosol particles depends on the effective ionization probabilities (EIP) of individual components during the laser ionization process. This study investigates how bio-aerosol chemical composition governs the EIP values of specific components and the overall features of the spectra from the bio-aerosol mass spectrometry (BAMS). EIP values were determined for a series of amino acid, dipicolinic acid, and peptide aerosol particles to determine what chemical features aid in ionization. The spectra of individual amino acids and dipicolinic acid, as well as mixtures, were examined for extent of fragmentation and the presence of molecular ion dimers, which are indicative of ionization conditions. Standard mixtures yielded information with respect to the significance of secondary ion plume reactions on observed spectra. A greater understanding of how these parameters affect EIP and spectra characteristics of bio-aerosols will aid in the intelligent selection of viable future biomarkers for the identification of bio-terrorism agents. 相似文献
956.
A simple and very sensitive spectrophotometric method for the direct determination of copper ions 总被引:1,自引:0,他引:1
A sensitive spectrophotometric method for the direct determination of copper in aqueous samples without a preconcentration step has been developed. It is based on the formation of a yellow complex with the chromogenic reagent di-2-pyridyl ketone benzoylhydrazone (dPKBH) in an alkaline medium. The complex stoichiometry was 1:2 (Cu:dPKBH) and presents maximum absorbance at 370 nm. The influence of chemical variables affecting the behaviour of the system such as pH, concentration of dPKBH, buffer solution and ethanol, order of addition of the reagents and stability of the complex, were evaluated. The molar absorptivity (epsilon) was 3.92x10(4) L mol(-1) cm(-1), and Beer's law was obeyed up to 3 mg L(-1) of copper. The relative standard deviation was 0.46% (n=11) for a sample containing 1 mg L(-1) Cu(II). The limit of detection was 2.5 micro g L(-1) and was therefore more sensitive than the direct methods reported previously. Finally, the method was successfully validated by analysing several real samples with different matrices, such as tap water, natural water or copper alloys, with an average relative error of 2.46%. 相似文献
957.
The preparation of pure Y3Al5O12 (YAG) and 50 vol% Al2O3–YAG
composite powders by a wet chemical route is presented. The role of the synthesis
temperature during reverse-strike precipitation has been investigated, showing
its relevant effect on the purity and homogeneity of YAG powder.
The
composite material was prepared by comparing two different synthesis routes.
A composite powder was synthesized via reverse-strike temperature-controlled
co-precipitation. In the latter case, a pure-alumina precursor was firstly
reverse-strike precipitated and then doped with an yttrium salt solution.
For both syntheses, the role of thermal and mechanical pre-treatments on the
phase development was demonstrated. 相似文献
958.
Reza Behjatmanesh-Ardakani 《Theoretical chemistry accounts》2007,118(4):799-805
In some works on the lattice Monte Carlo simulation of amphiphilic systems additional peaks in the cluster size distribution
has been interpreted as a clue for the phase or shape transition of micellar aggregates. On the other hand, some other works
showed that the additional peaks are a result of finite size of the lattice box. In this paper using calculating energy-auto-correlation
function and statistical error in correlated data, it is shown that how these apparently contradictory results are the same.
To do this, we have simulated a pure system containing amphiphile and water molecules. A simple model of potential containing
the main feature for these systems (the hydrophobicity of surfactant molecules) that cause the aggregates to be formed is
considered to avoid any synthetic results due to additional non-real parameters. To relax the initial configuration faster,
configurational bias Monte Carlo move is used in addition to reptation move. Periodic boundary condition and self-avoiding
walks are used as former published works in this field. It is shown that the additional peaks is a result of the statistical
errors for averaged cluster size distribution and can not be interpreted as a clue for shape or phase transition. 相似文献
959.
N. A. Mohamed Farook 《Journal of solution chemistry》2007,36(3):345-356
The oxidation kinetics of substituted and unsubstituted 4-oxoacids (S) by N-chlorosaccharin (NCSA) have been studied in aqueous acetic acid media. The reaction follows first-order kinetics in each
of the 4-oxoacids, NCSA and H+. The effect of changes in the electronic nature of the substrate reveals that positive charge develops in the transition
state. Based on the kinetic results and product analysis, a suitable mechanism has been proposed for the reaction of NCSA
with 4-oxoacids. 相似文献
960.
Electroactive conducting copolymers of aniline (ANI) and o-aminophenol (OAP) and two-layered poly(o-aminophenol) (POAP)/polyaniline (PANI) composites were prepared in aqueous acidic solution by electrode potential cycling.
Copolymerization was carried out at different feed concentrations of OAP and ANI on a gold electrode. A strong inhibition
of electropolymerization was found at a high molar fraction of OAP in the feed. The copolymers showed good adherence on the
electrode surface and gave a redox response up to pH=10.0. Two transitions were observed in the in situ conductivities of
the copolymers (as with PANI), but the conductivities were lower by 2.5–3 orders of magnitude as compared to PANI. Electrosynthesis
of PANI on POAP modified electrodes showed copolymer formation after reaction initiation and finally formation of a PANI layer
at the copolymer/solution interface. The ‘memory effect’ of the bilayer structures of both polymers was discussed in terms
of protonation/deprotonation and anion consumption taking place during redox processes of both polymers. 相似文献