7‐Chloro‐3,6‐di­methyl‐1H‐indene‐2‐carb­aldehyde

In the crystal structure of C₁₂H₁₁ClO, the (planar) mol­ecules give rise to a parallel packing. A model crystal obtained by semi‐empirical and packing‐energy calculations is consistent with the observed structure.     

Hexayne Amphiphiles and Bolaamphiphiles

Oligoynes with two or more conjugated carbon–carbon triple bonds are useful precursors for carbon-rich nanomaterials. However, their range of applications has so far been severely limited by the challenging syntheses, particularly in the case of oligoynes with functional groups. Here, we report a universal synthetic approach towards both symmetric and unsymmetric, functionalized hexaynes through the use of a modified Eglinton–Galbraith coupling and a sacrificial building block. We demonstrate the versatility of this approach by preparing hexaynes functionalized with phosphonic acid, carboxylic acid, ammonium, or thiol head groups, which serve as neutral, cationogenic, or anionogenic interfacially active groups. We show that these hexaynes are carbon-rich amphiphiles or bolaamphiphiles that self-assemble at liquid–liquid interfaces, on solid surfaces, as well as in aqueous media.     

SAXS study of the structure of amorphous Fe75TM5B20 (TM  Ti,V, Cr,Mn, Fe,Co, Ni)

A SAXS study was undertaken on Fe₇₅TM₅B₂₀ amorphous alloys (TM  Ti, V, Cr, Mn, Fe, Co, Ni) to prove the effects of the substituting metals on structural homogeneity of the systems. A density-density correlation extending up to 20 Å belongs to Fe-, Ni- and Co-containing alloys whereas the absence of a medium-range order characterizes the texture of the remaining alloys. A net correspondence was found between these structural conditions and the isothermal behavior of the resistivity.     

Quantum gravity,random geometry and critical phenomena

We discuss the theory of non-critical strings with extrinsic curvature embedded in a target space dimensiond greater than one. We emphasize the analogy between 2d gravity coupled to matter and non self-avoiding liquid-like membranes with bending rigidity. We first outline the exact solution for strings in dimensionsd<1 via the double scaling limit of matrix models and then discuss the difficulties of an extension tod>1. Evidence from recent and ongoing numerical simulations of dynamically triangulated random surfaces indicate that there is a non-trivial crossover from a crumpled to an extended surface as the bending rigidity is increased. If the cross-over is a true second order phase transition corresponding to a critical point there is the exciting possibility of obtaining a well defined continuum string theory ford>1. This essay received the third award from the Gravity Research Foundation, 1992-Ed.     

A class of strongly nonlinear functional differential equations

Let H be a real Hilbert space, :H [0, + ] a proper l.s.c., convex function with L_k:={u H; u² + (u) k} compact for every k > 0, let > 0 be a given constant and . We prove an existence result for strong solutions to a class of functional differential equations of the form

Alcune probabilità geometriche di reticoli nel piano

We consider, on the euclidean planeE ₂, a lattice of fundamental regions that are regular polygons, triangles or parallelograms. We determin the probabilityp in order that a vertex of the latticeR belongs to a circle of the random center and any radius.     

Metallacycles of porphyrins as building blocks in the construction of higher order assemblies through axial coordination of bridging ligands: solution- and solid-state characterization of molecular sandwiches and molecular wires

Treatment of the octahedral Ru(II)-dimethyl sulfoxide complexes trans-RuCl(2)(dmso-S)(4) (1), trans-RuCl(2)(dmso-O)(2)(CO)(2) (2), and trans-RuCl(2)(dmso)(3)(CO) (3) with a stoichiometric amount of 5,10-bis(4'-pyridyl)-15,20-diphenylporphyrin (4'-cis-DPyP) yields, after chromatographic purification, the novel 2+2 molecular squares of formula [trans,cis,cis-RuCl(2)(dmso-S)(2)(4'-cis-DPyP)](2) (4), [trans,cis,cis-RuCl(2)(CO)(2)(4'-cis-DPyP)](2) (5), and [trans,cis,cis-RuCl(2)(dmso-S)(CO)(4'-cis-DPyP)](2) (6), respectively. Compound 6 exists as an equimolar mixture of the isomeric metallacycles 6a and 6b, depending on whether the 4'-N(py) rings of 4'-cis-DPyP's are trans to CO or to dmso-S. Compounds 4-6 were fully characterized by NMR and IR spectroscopy and by FAB mass spectrometry. Treatment of 5 with excess zinc acetate in chloroform/methanol mixtures led to the isolation of the corresponding zinc adduct [trans,cis,cis-RuCl(2)(CO)(2)(Zn x 4'-cis-DPyP)](2) (5Zn). Treatment of 5Zn with 1 equiv of a trans ditopic N-donor ligand L (L = 4,4'-bipy, 5,15-bis(4'-pyridyl)-2,8,12,18-tetra-n-propyl-3,7,13,17-tetramethylporphyrin (4'-trans-DPyP-npm), or 5,15-bis(4'-pyridyl)-10,20-diphenylporphyrin (4'-trans-DPyP)) leads readily and selectively, according to (1)H NMR spectroscopy, to the quantitative assembling of 2:2 supramolecular adducts of stacked metallacycles of formula [(5Zn)(2)(mu-L)(2)] (7-9), which were thoroughly characterized in solution by NMR spectroscopy. NMR features indicate that, at ambient temperature, the equilibrium between 5Zn and L to yield [(5Zn)(2)(mu-L)(2)] has an intermediate to slow rate on the NMR time scale (relatively broad signals for L) and is totally shifted toward the 2:2 product (all or nothing process). Single-crystal X-ray investigations showed that, depending on the nature of the bridging ligand, in the solid state these sandwich structures can either be maintained or originate polymeric chains formulated as [(5Zn)(mu-L)](infinity). When L = 4'-trans-DPyP, both solution- and solid-state data indicate that [(5Zn)(2)(mu-4'-trans-DPyP)(2)] (9) is a discrete supramolecular assembly of two molecular squares of metalloporphyrins axially connected through other porphyrins. In this molecular box, the two bridging porphyrins are coplanar at a distance of about 11.4 A. When L = 4,4'-bipy, the corresponding adduct 7 has the anticipated sandwich-like discrete architecture [(5Zn)(2)(mu-4,4'-bipy)(2)] in solution, but it assumes a stair-like polymeric wire structure in the solid state. The polymer [(5Zn)(mu-4,4'-bipy)](infinity) is made by 5Zn squares bridged by 4,4'-bipy ligands which are axially coordinated alternatively on the two opposite sides of each square. Our work clearly established that relatively simple supramolecular adducts of porphyrins, such as molecular squares, are suitable building blocks for the construction of more elaborate assemblies of higher order by axial coordination of bridging ligands.     

Electron spin relaxation and frequency-dependent lineshape analysis of the 5′—ATP—Mn(II)—Trp system

A frequency-dependent lineshape analysis of the ESR spectra of ternary systems in solution has been carried out. The 5′-ATP—Mn(II)—Trp complex has been chosen as a model system. The analysis points out the presence of inverted spectra at both X- and Q-bands. The lineshape is described by a distribution of configurational sites, Y^l(ω) = Σ_kP_kY_k(H). The temperature dependence of the ESR linewidth has also been investigated and is discussed in terms of chemical equilibria and correlation times.