催化膜和催化膜反应器:整合的高效和环保催化过程

 The design of new heterogeneous photooxygenation systems able to employ visible light, oxygen, mild temperatures, and solvent with a low environmental impact has been investigated. In particular, the heterogenization of decatungstate (W10O4-32), a polyoxometalate with photocatalytic activity in oxidation reactions, has been carried out in polymeric membranes of polyvinylidenefluoride. The polymeric catalytic membranes prepared by phase inversion technique have been successfully applied in the aerobic mineralization of phenol in water, which was used as an example of organic pollutant. In order to evaluate the effect of the polymeric environment on the overall catalyst behavior, we have also heterogenized the decatungstate (opportunely functionalized) in perfluorinated membrane made of Hyflon. The photocatalytic composite membranes are characterized by different and tuneable properties depending on the nature of the polymeric micro-environment, in which the catalyst is confined. Moreover, the selective separation function of the membrane results in enhanced performance in comparison with homogeneous reactions.     

Noise Reduction in Spur Gear Systems

This article lists some tips for reducing gear case noise. With this aim, a static analysis was carried out in order to describe how stresses resulting from meshing gears affect the acoustic emissions. Different parameters were taken into account, such as the friction, material, and lubrication, in order to validate ideas from the literature and to make several comparisons. Furthermore, a coupled Eulerian–Lagrangian (CEL) analysis was performed, which was an innovative way of evaluating the sound pressure level of the aforementioned gears. Different parameters were considered again, such as the friction, lubrication, material, and rotational speed, in order to make different research comparisons. The analytical results agreed with those in the literature, both for the static analysis and CEL analysis—for example, it was shown that changing the material from steel to ductile iron improved the gear noise, while increasing the rotational speed or the friction increased the acoustic emissions. Regarding the CEL analysis, air was considered a perfect gas, but its viscosity or another state equation could have also been taken into account. Therefore, the above allowed us to state that research into these scientific fields will bring about reliable results.     

Securitizing and tranching longevity exposures

We consider the problem of optimally designing longevity risk transfers under asymmetric information. We focus on holders of longevity exposures that have superior knowledge of the underlying demographic risks, but are willing to take them off their balance sheets because of capital requirements. In equilibrium, they transfer longevity risk to uninformed agents at a cost, where the cost is represented by retention of part of the exposure and/or by a risk premium. We use a signalling model to quantify the effects of asymmetric information and emphasize how they compound with parameter uncertainty. We show how the cost of private information can be minimized by suitably tranching securitized cashflows, or, equivalently, by securitizing the exposure in exchange for an option on mortality rates. We also investigate the benefits of pooling several longevity exposures and the impact on tranching levels.     

An identity for T-ordered exponentials with applications to quantum mechanics

The solution of the Cauchy problem for Liouville's equation φ_xy = e^φ is shown to be equivalent to the calculation of a T-ordered exponential of a two-dimensional variable matrix. This gives rise to an identity for the T-ordered exponential involving two arbitrary functions. The formalism is applied to the time evolution of a magnetic dipole in a time dependent magnetic field and to the one-dimensional Dirac equation with external potential $\text{V(x) = (n +}\text{1}\text{2}\text{)λ}$ tanh λx which is relevant for field theoretic applications. A generalization to n-dimensional matrices is also given.     

Equazioni quasi ellittiche e spaziL p, θ (ω, δ) (I)

Summary Regularity theorems inL ^{2, θ} (ω, δ) spaces are proved for weak solutions of quasielliptic differential equations. In particular, regularization results are obtained in the class of holder continuous functions (with respect to a suitable metric related to the operator). As a consequence, we obtain results and estimates in L^p andL ^{p, θ} spaces for the solution of the Dirichlet problem.

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Lavoro eseguito nell’ambito del Gruppo di Ricerca n^o 46 del Comitato per la Matematica del C N.R.     

Time irregularity of generalized Ornstein–Uhlenbeck processes

This Note is concerned with the properties of solutions to a linear evolution equation perturbed by a cylindrical Lévy process. It turns out that solutions, under rather weak requirements, do not have a càdlàg modification. Some natural open questions are also stated.     

Singularity Formation in Fractional Burgers’ Equations

The formation of singularities in finite time in nonlocal Burgers’ equations, with time-fractional derivative, is studied in detail. The occurrence of finite-time singularity is proved, revealing the underlying mechanism, and precise estimates on the blowup time are provided. The employment of the present equation to model a problem arising in job market is also analyzed.