催化动力学荧光法测定中草药对羟基自由基的清除率

苯甲酸具有很弱的荧光,在Co2+的催化下,过氧化氢能氧化苯甲酸发出强的荧光。中草药提取物可以清除溶液中的·OH, 使产物的生成量减少, 从而使溶液的荧光增加程度降低。据此原理建立了一种测定中草药对羟基自由基清除率的催化动力学荧光新体系。当中草药的浓度为4.0 mg(干重)·mL-1时,测得紫花地丁、苍术和赤芍对羟基自由基的清除率分别为60.8%,40.1%和94.3%。该方法与分光光度法测定结果相比无显著性差异。     

一种高分辨率的光纤光栅传感解调技术

报道了一种基于光纤激光器波长扫描寻址的高分辨率的光纤光栅传感解调方案。光纤激光器的扫描寻址过程由微机来控制。微机控制光纤激光器波长扫描的同时,同步采集、处理传感信号,并通过曲线拟合给出传感光栅的中心反射波长值。本解调方案的波长移动分辨率为０．１ｐｍ,可以实现高分辨率的温度及应变测量。     

纳米ZnO的表面化学修饰及其分析表征

采用水溶性羟丙基甲基纤维素HPMC对无机纳米ZnO粒子进行物理吸附处理 ,获得了核为无机纳米ZnO ,外壳为水溶性高分子HPMC的粒子。然后在其上进行了甲基丙烯酸甲酯的接枝聚合。采用红外光谱、差热分析的方法对复合粒子进行了表征 ,并采用透射电镜观察了粒子的形貌。红外光谱表明在纳米ZnO的表面吸附了HPMC并接枝了PMMA ,差热分析表明HPMC ,HPMC g PMMA和ZnO/HPMC g PMMA的热稳定性逐渐提高 ,透射电镜观察表明 ,在纳米ZnO的表面粘附了一层聚合物 ,成功地实现了纳米粒子的表面修饰。     

免受温度影响的光纤光栅位移传感器

将一定长度、均匀周期的光纤光栅沿轴向刚性粘贴于厚度呈阶跃分布的等腰三角状悬臂梁界线附近的表面上 ,通过观测该光栅反射谱中两个峰值的间距来监测梁自由端在垂直于表面方向上的位移。实验表明该无源温漂位移线性传感装置的传感灵敏度达 9.2 4× 10 -2 nm/ mm,与理论值 9.4× 10 -2 nm/ mm非常接近。     

基于自适应准则的闪光照相图像重建

 针对闪光照相图像低信噪比的特点,提出了一种自适应的图像重建算法。该算法以代数法(ART)迭代重建为基础,在迭代重建过程中引入了两个权重矩阵,其中一个矩阵用来控制重建过程中的高频分量以保持重建结果的边界;另一个矩阵控制重建结果的平坦区域以提高重建结果的信噪比。通过在迭代过程中更新这两个矩阵来实现图像的自适应重建。数值模拟结果表明,相对于传统的单准则ART重建算法,该方法具有更好的抗噪能力和边界保持能力。     

实现20Gbit/s的OTDM孤子信号56km色散位移光纤的传输

在国内最先采用孤子的方式将8×2.5Gb/s的OTDM信号在色散位移光纤中传输了56.1km,对8×2.5Gb/s的OTDM进行解复用后进行了误码测量,系统功率代价为2.9dB.系统采用增益开关半导体激光器作光孤子源,高Q电滤波方式提取时钟,非线性光学环路镜解复用。孤子脉冲最大半宽度为20ps,传输光纤平均色散1.2ps/nm/km。     

牛顿环实验测量结果的不确定度评定及其表示

讨论了不等精度测量牛顿环曲率半径及牛顿环直径不确定度的评定及表示     

X射线荧光光谱(XRF)法测定绿泥石中镁、铝、硅、磷、钾、钙、钛、铁元素含量

建立了X射线荧光光谱法测定绿泥石中镁、铝、硅、磷、钾、钙、钛、铁元素含量的快速分析方法。以标准物质及标准物质与基准试剂氧化镁、氧化钙人工混合配制标样的方法建立标准工作曲线,重点讨论了熔剂和脱模剂的选取。最佳熔样条件：采用8.0g四硼酸锂和偏硼酸锂混合熔剂(质量比67: 33)+0.8g样品并添加溴化锂作为脱模剂,熔样温度1100℃,熔样时间10min。该方法相对标准偏差(n=12)均小于5.57%,绿泥石样品测定结果与化学法一致,硅酸盐标准物质测定结果均满足不确定度要求。     

Non-covalent reconfigurable microgel colloidosomes with a well-defined bilayer shell

Microgels are extremely interfacially active and are widely used to stabilize emulsions. However, they are commonly used to stabilize oil-in-water emulsions due to their intrinsic hydrophilicity and initially dispersed in water. In addition, there have been no attempts to control microgel structural layers that are formed at the interface and as a result it limits applications of microgel in advanced materials. Here, we show that by introducing octanol into poly(N-isopropylacrylamide-co-methacrylic acid) (PNIPAM-co-MAA) microgels, octanol-swollen microgels can rapidly diffuse from the initially dispersed oil phase onto the water droplet surface. This facilitates the formation of microgel-laden interfacial layers with strong elastic responses and also generates stable inverse water-in-oil Pickering emulsions. These emulsions can be used as templates to produce microgel colloidosomes, herein termed ‘microgelsomes’, with shells that can be fine-tuned from a particle monolayer to a well-defined bilayer. The microgelsomes can then be used to encapsulate and/or anchor nanoparticles, proteins, vitamin C, bio-based nanocrystals or enzymes. Moreover, the programmed release of these substances can be achieved by using ethanol as a trigger to mediate shell permeability. Thus, these reconfigurable microgelsomes with a microgel-bilayer shell can respond to external stimuli and demonstrate tailored properties, which offers novel insights into microgels and promise wider application of Pickering emulsions stabilized by soft colloids.

Inverse W/O Pickering emulsions and reconfigurable microgelsomes with a well-defined bilayer structure are prepared from octanol-swollen PNIPAM-co-MAA microgels and the combination of binary microgels, which promise wider application of soft colloids.